Stimulated emission pumping studies of energy transfer in highly vibrationally excited molecules

1993 ◽  
Vol 97 (16) ◽  
pp. 3944-3955 ◽  
Author(s):  
X. Yang ◽  
J. M. Price ◽  
J. A. Mack ◽  
C. G. Morgan ◽  
C. A. Rogaski ◽  
...  
2005 ◽  
Vol 123 (13) ◽  
pp. 131102 ◽  
Author(s):  
Chen-Lin Liu ◽  
Hsu Chen Hsu ◽  
Jia-Jia Lyu ◽  
Chi-Kung Ni

The absolute efficiencies for the vibrational excitation of molecules which quench singlet molecular oxygen have been determined from measurements of their infrared chemiluminescence and kinetics of relaxation. The systems studied were NO and CO with O 2 ( 1 ∆ g ) and NO, CO, HCl, DCl, H 2 O, D 2 O, CO 2 , N 2 O, NH 3 and C 2 H 2 with O 2 ( 1 ∑ + g ). Rate coefficients for the vibrational relaxation of a number of these molecules by molecular oxygen were also determined.


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