Electron-transfer bond-breaking processes: an example of nonlinear activation-driving force relationship in the reductive cleavage of the carbon-sulfur bond

1993 ◽  
Vol 97 (1) ◽  
pp. 150-157 ◽  
Author(s):  
Maria Gabriella Severin ◽  
Maria Carmen Arevalo ◽  
Flavio Maran ◽  
Elio Vianello
Keyword(s):  
Electron Transfer ◽  
Driving Force ◽  
Reductive Cleavage ◽  
Bond Breaking ◽  
Sulfur Bond ◽  
Force Relationship

scholarly journals Metal-Free Reductive Cleavage of CN and SN Bonds by Photoactivated Electron Transfer from a Neutral Organic Donor

2013 ◽  
Vol 126 (2) ◽  
pp. 484-488 ◽  
Author(s):  
Steven O'Sullivan ◽  
Eswararao Doni ◽  
Tell Tuttle ◽  
John A. Murphy
Keyword(s):  
Electron Transfer ◽  
Reductive Cleavage ◽  
Metal Free

Balancing electron transfer rate and driving force for efficient photocatalytic hydrogen production in CdSe/CdS nanorod–[NiFe] hydrogenase assemblies

2017 ◽  
Vol 10 (10) ◽  
pp. 2245-2255 ◽  
Author(s):  
Bryant Chica ◽  
Chang-Hao Wu ◽  
Yuhgene Liu ◽  
Michael W. W. Adams ◽  
Tianquan Lian ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Hydrogen Production ◽  
Driving Force ◽  
Transfer Rate ◽  
Pyrococcus Furiosus ◽  
Electron Transfer Rate ◽  
Photocatalytic Hydrogen Production ◽  
Photocatalytic System

We describe a hybrid photocatalytic system for hydrogen production consisting of nanocrystalline CdSe/CdS dot-in-rod (DIR) structures coupled to [NiFe] soluble hydrogenase I (SHI) fromPyrococcus furiosus.

Driving force effects in proton coupled electron transfer

2000 ◽  
Vol 300-302 ◽  
pp. 186-190 ◽  
Author(s):  
Mauro C.M. Laranjeira ◽  
Rosemary A. Marusak ◽  
A.Graham Lappin
Keyword(s):  
Electron Transfer ◽  
Driving Force ◽  
Proton Coupled Electron Transfer
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