Impulsive Energy Transfer during Unimolecular Reaction via Reactive Cylinders in Phase Space

1995 ◽  
Vol 99 (40) ◽  
pp. 14707-14718 ◽  
Author(s):  
Joanna R. Fair ◽  
Karin R. Wright ◽  
John S. Hutchinson
Keyword(s):  
Energy Transfer ◽  
Phase Space ◽  
Unimolecular Reaction

Studies in energy transfer II. The isomerization of cyclo propane—a quasi-unimolecular reaction

1953 ◽  
Vol 217 (1131) ◽  
pp. 563-571 ◽  
Keyword(s):  
Energy Transfer ◽  
Rate Constant ◽  
Reaction System ◽  
Thermal Isomerization ◽  
Unimolecular Reaction ◽  
Unimolecular Reactions

The thermal isomerization of cy clopropane to propylene is a homogeneous unimolecular reaction at 490° C and at pressures down of 0·007 cm. The rate constant of the unimolecular reaction falls off by a factor of ten as the pressure in the reaction system is decreased from 8·4 to 0·007 cm. The results are compared with various theories of quasi-unimolecular reactions. The addition of a non-reacting gas to the system counteracts the falling off. The relative efficiencies of a number of gases for maintaining the unimolecular rate constant have been measured.

Collisional energy transfer in the two-channel thermal unimolecular reaction of chloroethane-1,1,2-d3

1994 ◽  
Vol 98 (4) ◽  
pp. 1139-1144 ◽  
Author(s):  
Chang Ju Choi ◽  
Bum Wook Lee ◽  
Kyung Hoon Jung ◽  
E. Tschuikow-Roux
Keyword(s):  
Energy Transfer ◽  
Unimolecular Reaction ◽  
Collisional Energy ◽  
Collisional Energy Transfer

Collisional energy transfer in the two-channel thermal unimolecular reaction of bromoethane-2-d

1987 ◽  
Vol 91 (9) ◽  
pp. 2354-2358 ◽  
Author(s):  
Kyung Hoon. Jung ◽  
Sung Hoon. Kang ◽  
Chul Un. Ro ◽  
E. Tschuikow-Roux
Keyword(s):  
Energy Transfer ◽  
Unimolecular Reaction ◽  
Collisional Energy ◽  
Collisional Energy Transfer

A one-dimensional self-gravitating stellar gas

1966 ◽  
Vol 25 ◽  
pp. 46-48 ◽  
Author(s):  
M. Lecar
Keyword(s):  
Gravitational Field ◽  
Phase Space ◽  
Motion Picture ◽  
Space Distribution ◽  
Two Dimensional ◽  
One Dimensional ◽  
Phase Space Distribution ◽  
Dimensional Phase Space ◽  
The Mean

“Dynamical mixing”, i.e. relaxation of a stellar phase space distribution through interaction with the mean gravitational field, is numerically investigated for a one-dimensional self-gravitating stellar gas. Qualitative results are presented in the form of a motion picture of the flow of phase points (representing homogeneous slabs of stars) in two-dimensional phase space.

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