Solubility of Carbon Dioxide in Aqueous Solutions of 2-Amino-2-methyl-1-propanol andN-Methyldiethanolamine and Their Mixtures in the Temperature Range from 313 to 353 K and Pressures up to 2.7 MPa

1998 ◽  
Vol 37 (8) ◽  
pp. 3133-3141 ◽  
Author(s):  
Dirk Silkenbäumer ◽  
Bernd Rumpf ◽  
Rüdiger N. Lichtenthaler
Keyword(s):  
Carbon Dioxide ◽  
Aqueous Solutions ◽  
Temperature Range

scholarly journals AN INVESTIGATION OF THE EQUILIBRIA EXISTING IN GAS-WATER SYSTEMS FORMING ELECTROLYTES

1931 ◽  
Vol 5 (2) ◽  
pp. 162-199 ◽  
Author(s):  
O. M. Morgan ◽  
O. Maass
Keyword(s):  
Carbon Dioxide ◽  
Aqueous Solutions ◽  
Sulphur Dioxide ◽  
Carbonic Acid ◽  
Ammonium Hydroxide ◽  
Theoretical Treatment ◽  
Vapor Pressures ◽  
Temperature Range ◽  
Free Carbon Dioxide ◽  
Order Of Magnitude

The data and theoretical treatment contained in this paper are the continuation of a series of researches instituted to investigate the equilibria existing in certain gaseous-aqueous systems. In this work the vapor pressures and electrolytic conductivities of aqueous solutions of sulphur dioxide, carbon dioxide, and ammonia have been measured with greater precision than ever before over a temperature range from 0 to 25 °C. and over a concentration range where their respective vapor pressures do not exceed one atmosphere. From the data thus derived, equilibria relations have been calculated and certain changes have been made in the mode of theoretical procedure involved in this type of calculation.With regard to the equilibria existing in the three systems, the conclusions drawn may be summarized as follows: Practically all of the ammonia exists in the combined form and practically all the carbon dioxide exists as free carbon dioxide in the aqueous solutions in the temperature range investigated. The amounts of free and combined sulphur dioxide are of the same order of magnitude and the relative amount of combined and free sulphur dioxide can be calculated approximately, the latter increasing markedly with rising temperature. The true dissociation constant can therefore be found for ammonium hydroxide, can be estimated for sulphurous acid, but cannot be calculated for carbonic acid from the available data.

Thermal Conductivity and Prandtl Number of Carbon Dioxide and Carbon-Dioxide Air Mixtures at One Atmosphere

1961 ◽  
Vol 83 (2) ◽  
pp. 125-131 ◽  
Author(s):  
Jerome L. Novotny ◽  
Thomas F. Irvine
Keyword(s):  
Carbon Dioxide ◽  
Thermal Conductivity ◽  
Prandtl Number ◽  
Maximum Error ◽  
Intermolecular Force ◽  
Temperature Range ◽  
Average Temperature ◽  
Pure Carbon ◽  
Prandtl Numbers ◽  
Pure Carbon Dioxide

By measuring laminar recovery factors in a high velocity gas stream, experimental determinations were made of the Prandtl number of carbon dioxide over a temperature range from 285 to 450 K and of carbon-dioxide air mixtures at an average temperature of 285 K with a predicted maximum error of 1.5 per cent. Thermal conductivity values were deduced from these Prandtl numbers and compared with literature values measured by other methods. Using intermolecular force constants determined from literature experimental data, viscosities, thermal conductivities, and Prandtl numbers were calculated for carbon-dioxide air mixtures over the temperature range 200 to 1500 deg for mixture ratios from pure air to pure carbon dioxide.

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