Graphical Differentiation in Ammonia Synthesis Kinetics

1960 ◽  
Vol 52 (1) ◽  
pp. 89-91 ◽  
Author(s):  
Robert Anderson
Keyword(s):  
Ammonia Synthesis ◽  
Graphical Differentiation

Electron Donation by Low-Crystalline Ba-La-Ce Oxygen-Deficient Composite Oxide Accumulating on Ru Nanoparticles for Ammonia Synthesis under Mild Conditions

2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Bond Cleavage ◽  
Synthesis Process ◽  
Strong Electron ◽  
Mild Conditions ◽  
Ru Nanoparticles ◽  
Rate Determining Step ◽  
Highly Active ◽  
Composite Oxides ◽  
Low Crystalline

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>

Electron Donation by Low-Crystalline Ba-La-Ce Oxygen-Deficient Composite Oxide Accumulating on Ru Nanoparticles for Ammonia Synthesis under Mild Conditions

2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Bond Cleavage ◽  
Synthesis Process ◽  
Strong Electron ◽  
Mild Conditions ◽  
Ru Nanoparticles ◽  
Rate Determining Step ◽  
Highly Active ◽  
Composite Oxides ◽  
Low Crystalline

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>

Boosting Nitrogen Activation via Bimetallic Organic Frameworks for Photocatalytic Ammonia Synthesis

ACS Catalysis ◽  
2021 ◽  
pp. 9986-9995
Author(s):  
Zhanfeng Zhao ◽  
Hanjie Ren ◽  
Dong Yang ◽  
You Han ◽  
Jiafu Shi ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Nitrogen Activation

An intelligent quantitative risk assessment method for ammonia synthesis process

2021 ◽  
Vol 420 ◽  
pp. 129893
Author(s):  
Zijian Liu ◽  
Wende Tian ◽  
Zhe Cui ◽  
Honglong Wei ◽  
Chuankun Li
Keyword(s):  
Risk Assessment ◽  
Ammonia Synthesis ◽  
Assessment Method ◽  
Quantitative Risk Assessment ◽  
Synthesis Process ◽  
Risk Assessment Method
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