Boosting Nitrogen Activation via Bimetallic Organic Frameworks for Photocatalytic Ammonia Synthesis

ACS Catalysis ◽  
2021 ◽  
pp. 9986-9995
Author(s):  
Zhanfeng Zhao ◽  
Hanjie Ren ◽  
Dong Yang ◽  
You Han ◽  
Jiafu Shi ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Nitrogen Activation

Cooperative Nitrogen Activation and Ammonia Synthesis on Densely Monodispersed Mo–N–C Sites

2020 ◽  
Vol 11 (10) ◽  
pp. 3962-3968 ◽  
Author(s):  
Ke Ye ◽  
Min Hu ◽  
Qin-Kun Li ◽  
Yulan Han ◽  
Yi Luo ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Nitrogen Activation

scholarly journals Nitrogen Activation in a Mars–van Krevelen Mechanism for Ammonia Synthesis on Co3Mo3N

2015 ◽  
Vol 119 (51) ◽  
pp. 28368-28376 ◽  
Author(s):  
Constantinos D. Zeinalipour-Yazdi ◽  
Justin S. J. Hargreaves ◽  
C. Richard A. Catlow
Keyword(s):  
Ammonia Synthesis ◽  
Nitrogen Activation

Electron Donation by Low-Crystalline Ba-La-Ce Oxygen-Deficient Composite Oxide Accumulating on Ru Nanoparticles for Ammonia Synthesis under Mild Conditions

2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Bond Cleavage ◽  
Synthesis Process ◽  
Strong Electron ◽  
Mild Conditions ◽  
Ru Nanoparticles ◽  
Rate Determining Step ◽  
Highly Active ◽  
Composite Oxides ◽  
Low Crystalline

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>

Electron Donation by Low-Crystalline Ba-La-Ce Oxygen-Deficient Composite Oxide Accumulating on Ru Nanoparticles for Ammonia Synthesis under Mild Conditions

2019 ◽  
Author(s):  
Katsutoshi Sato ◽  
Shin-ichiro Miyahara ◽  
Yuta Ogura ◽  
Kotoko Tsujimaru ◽  
Yuichiro Wada ◽  
...  
Keyword(s):  
Ammonia Synthesis ◽  
Bond Cleavage ◽  
Synthesis Process ◽  
Strong Electron ◽  
Mild Conditions ◽  
Ru Nanoparticles ◽  
Rate Determining Step ◽  
Highly Active ◽  
Composite Oxides ◽  
Low Crystalline

<p>To mitigate global problems related to energy and global warming, it is helpful to develop an ammonia synthesis process using catalysts that are highly active under mild conditions. Here we show that the ammonia synthesis activity of Ru/Ba/LaCeO<i><sub>x</sub></i> pre-reduced at 700 °C is the highest reported among oxide-supported Ru catalysts. Our results indicate that low crystalline oxygen-deficient composite oxides, which include Ba<sup>2+</sup>, Ce<sup>3+</sup> and La<sup>3+</sup>, with strong electron-donating ability, accumulate on Ru particles and thus promote N≡N bond cleavage, which is the rate determining step for ammonia synthesis.</p>

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