The Oxidative Dehydrogenation ofn-Butane in a Fixed-Bed Reactor and in an Inert Porous Membrane ReactorMaximizing the Production of Butenes and Butadiene

2006 ◽  
Vol 45 (8) ◽  
pp. 2661-2671 ◽  
Author(s):  
David Milne ◽  
David Glasser ◽  
Diane Hildebrandt ◽  
Brendon Hausberger
2015 ◽  
Vol 5 (5) ◽  
pp. 2807-2813 ◽  
Author(s):  
Bozhao Chu ◽  
Lara Truter ◽  
Tjeerd Alexander Nijhuis ◽  
Yi Cheng

Due to its excellent heat transfer ability, the micro-channel reactor with coated phase-pure M1 catalysts can achieve reactor productivity nearly 5 times higher than that of a traditional fixed-bed reactor under the same reaction conditions in oxidative dehydrogenation of ethane (ODHE).


2008 ◽  
Vol 145 (2) ◽  
pp. 308-315 ◽  
Author(s):  
Eduardo López ◽  
Eleni Heracleous ◽  
Angeliki A. Lemonidou ◽  
Daniel O. Borio

2007 ◽  
Vol 119 ◽  
pp. 251-254 ◽  
Author(s):  
Ji Chul Jung ◽  
Hee Soo Kim ◽  
Ahn Seop Choi ◽  
Young Min Chung ◽  
Tae Jin Kim ◽  
...  

α-Bi2Mo3O12 and γ-Bi2MoO6 catalysts were prepared by co-precipitation method, and they were applied to the oxidative dehydrogenation of n-butene into 1,3-butadiene in a continuous flow fixed-bed reactor. Formation of α-Bi2Mo3O12 and γ-Bi2MoO6 catalysts was well confirmed by XRD, Raman spectroscopy, and ICP-AES analyses. The γ-Bi2MoO6 catalyst exhibited a better catalytic performance than the α-Bi2Mo3O12 catalyst. Catalytic performance of γ-Bi2MoO6 strongly depended on the pH value used in the co-precipitation step. It was also revealed that a mixed catalyst comprising γ-Bi2MoO6 (90 wt%) and small amount of α-Bi2Mo3O12 (10 wt%) showed the best catalytic performance due to the synergy effect of two components. It is believed that the high catalytic performance of the mixed catalyst resulted from high diffusion coefficient of lattice oxygen in the γ-Bi2MoO6 and from abundant chemisorption sites for n-butene in the α-Bi2Mo3O12.


ChemistryOpen ◽  
2019 ◽  
Vol 8 (8) ◽  
pp. 1066-1075
Author(s):  
Anna Kulik ◽  
Katja Neubauer ◽  
Reinhard Eckelt ◽  
Stephan Bartling ◽  
Johannes Panten ◽  
...  

ChemistryOpen ◽  
2019 ◽  
Vol 8 (8) ◽  
pp. 1034-1034
Author(s):  
Anna Kulik ◽  
Katja Neubauer ◽  
Reinhard Eckelt ◽  
Stephan Bartling ◽  
Johannes Panten ◽  
...  

Sign in / Sign up

Export Citation Format

Share Document