Correlation and predication of physical properties of hydrocarbons with the modified Peng-Robinson equation of state. 2. Representation of the vapor pressures and of the molar volumes

1990 ◽  
Vol 29 (4) ◽  
pp. 659-666 ◽  
Author(s):  
Marek Rogalski ◽  
Bruno Carrier ◽  
Roland Solimando ◽  
Andre Peneloux
2002 ◽  
Vol 198 (2) ◽  
pp. 195-228 ◽  
Author(s):  
Otilio Hernández-Garduza ◽  
Fernando Garcı́a-Sánchez ◽  
David Ápam-Martı́nez ◽  
Richart Vázquez-Román

Fuel ◽  
2021 ◽  
Vol 293 ◽  
pp. 120254
Author(s):  
Gutierri Salgueiro ◽  
Marcellus de Moraes ◽  
Fernando Pessoa ◽  
Raquel Cavalcante ◽  
André Young

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Ilyas Al-Kindi ◽  
Tayfun Babadagli

AbstractThe thermodynamics of fluids in confined (capillary) media is different from the bulk conditions due to the effects of the surface tension, wettability, and pore radius as described by the classical Kelvin equation. This study provides experimental data showing the deviation of propane vapour pressures in capillary media from the bulk conditions. Comparisons were also made with the vapour pressures calculated by the Peng–Robinson equation-of-state (PR-EOS). While the propane vapour pressures measured using synthetic capillary medium models (Hele–Shaw cells and microfluidic chips) were comparable with those measured at bulk conditions, the measured vapour pressures in the rock samples (sandstone, limestone, tight sandstone, and shale) were 15% (on average) less than those modelled by PR-EOS.


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