Crystal Structure and Energy Transfer in Double-Complex Salts Composed of Tris(2,2‘-bipyridine)ruthenium(II) or Tris(2,2‘-bipyridine)osmium(II) and Hexacyanochromate(III)

Takuhiro Otsuka; Naoto Takahashi; Naoki Fujigasaki; Akiko Sekine; Yuji Ohashi; Youkoh Kaizu

doi:10.1021/ic9810541

Crystal Structure and Energy Transfer in Double-Complex Salts Composed of Tris(2,2‘-bipyridine)ruthenium(II) or Tris(2,2‘-bipyridine)osmium(II) and Hexacyanochromate(III)

Inorganic Chemistry ◽

10.1021/ic9810541 ◽

1999 ◽

Vol 38 (6) ◽

pp. 1340-1347 ◽

Cited By ~ 24

Author(s):

Takuhiro Otsuka ◽

Naoto Takahashi ◽

Naoki Fujigasaki ◽

Akiko Sekine ◽

Yuji Ohashi ◽

...

Keyword(s):

Crystal Structure ◽

Energy Transfer ◽

Double Complex ◽

Double Complex Salts ◽

Complex Salts

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Energy-Transfer Rate in Crystals of Double-Complex Salts Composed of [Ru(N-N)3]2+(N-N = 2,2‘-Bipyridine or 1,10-Phenanthroline) and [Cr(CN)6]3-: Effect of Relative Orientation between Donor and Acceptor

Inorganic Chemistry ◽

10.1021/ic0013936 ◽

2001 ◽

Vol 40 (14) ◽

pp. 3406-3412 ◽

Cited By ~ 21

Author(s):

Takuhiro Otsuka ◽

Akiko Sekine ◽

Naoki Fujigasaki ◽

Yuji Ohashi ◽

Youkoh Kaizu

Keyword(s):

Energy Transfer ◽

Transfer Rate ◽

Relative Orientation ◽

Energy Transfer Rate ◽

Double Complex ◽

Double Complex Salts ◽

Donor And Acceptor ◽

Complex Salts

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Double complex salts with [Ru(NH3)5Cl]2+ cation and [OsCl6]2− anion: Synthesis and properties. Crystal structure of [Ru(NH3)5Cl]2[OsCl6]Cl2

Russian Journal of Inorganic Chemistry ◽

10.1134/s0036023610090032 ◽

2010 ◽

Vol 55 (9) ◽

pp. 1347-1351

Author(s):

I. V. Korol’kov ◽

S. A. Martynova ◽

K. V. Yusenko ◽

S. V. Korenev

Keyword(s):

Crystal Structure ◽

Double Complex ◽

Double Complex Salts ◽

Complex Salts

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Energy-Transfer Process in Crystals of Chiral and Racemic Double Complex Salts of [Co(ethylenediamine)3][Tb(2,6-pyridinedicarboxylate)3]

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.80.1140 ◽

2007 ◽

Vol 80 (6) ◽

pp. 1140-1147 ◽

Cited By ~ 7

Author(s):

Munetaka Iwamura ◽

Toshiaki Tsukuda ◽

Makoto Morita

Keyword(s):

Energy Transfer ◽

Transfer Process ◽

Energy Transfer Process ◽

Double Complex ◽

Double Complex Salts ◽

Complex Salts

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Isostructuralism in double complex salts series: [M(H2O)x(NH3)6−x] [M′(CN)6] and [M(H2O)x(NH3)6−x] [CuCl5] (M, M′ = Co(III), Cr(III); x = 0, 1, 2). Crystal structure of [Cr(H2O)(NH3)5] [CuCl5]

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)82040-x ◽

1990 ◽

Vol 169 (1) ◽

pp. 91-95 ◽

Cited By ~ 7

Author(s):

J. Pons ◽

A. Solans ◽

J.C. Bayon ◽

E. Molins ◽

J. Casabo ◽

...

Keyword(s):

Crystal Structure ◽

Double Complex ◽

Double Complex Salts ◽

Complex Salts

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Zn-containing double complex salts formed by Keggin type polyoxotungstates: Synthesis and crystal structure

Russian Journal of Coordination Chemistry ◽

10.1134/s1070328417050086 ◽

2017 ◽

Vol 43 (6) ◽

pp. 368-372

Author(s):

L. I. Udalova ◽

S. A. Adonin ◽

P. A. Abramov ◽

I. V. Korolkov ◽

M. N. Sokolov

Keyword(s):

Crystal Structure ◽

Double Complex ◽

Synthesis And Crystal Structure ◽

Double Complex Salts ◽

Keggin Type ◽

Complex Salts

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Double Complex Salts [Ln(C6H5NO2)3(H2O)2][Cr(NCS)6] · 2H2O (Ln = Lu, Ce, Y): Synthesis and Crystal Structure

Russian Journal of Inorganic Chemistry ◽

10.1134/s0036023619030070 ◽

2019 ◽

Vol 64 (3) ◽

pp. 329-334

Author(s):

E. V. Cherkasova ◽

N. V. Pervukhina ◽

N. V. Kuratieva ◽

T. G. Cherkasova

Keyword(s):

Crystal Structure ◽

Double Complex ◽

Synthesis And Crystal Structure ◽

Double Complex Salts ◽

Complex Salts

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Energy transfer between transition‐metal complexes in double complex salts

The Journal of Chemical Physics ◽

10.1063/1.1680422 ◽

1973 ◽

Vol 59 (6) ◽

pp. 2902-2908 ◽

Cited By ~ 26

Author(s):

Ichiro Fujita ◽

Hiroshi Kobayashi

Keyword(s):

Energy Transfer ◽

Transition Metal ◽

Metal Complexes ◽

Transition Metal Complexes ◽

Double Complex ◽

Double Complex Salts ◽

Complex Salts

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Double complex salts with [Ru(NH3)5Cl]2+cation and [OsCl6]2−anion: synthesis and properties. Crystal structure of the [Ru(NH3)5Cl]2[OsCl6]Cl2

Acta Crystallographica Section A Foundations of Crystallography ◽

10.1107/s0108767309093982 ◽

2009 ◽

Vol 65 (a1) ◽

pp. s284-s285

Author(s):

Ilya Korolkov ◽

Svetlana Martynova ◽

Kirill Yusenko ◽

Sergey Korenev

Keyword(s):

Crystal Structure ◽

Double Complex ◽

Double Complex Salts ◽

Complex Salts

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ChemInform Abstract: Isostructuralism in Double Complex Salts Series: (M(H2O)x(NH3)6-x) (M′(CN)6) and (M(H2O)x(NH3)6-x) (CuCl5) (M,M′: Co(III), Cr(III); x = 0, 1, 2). Crystal Structure of (Cr(H2O)(NH3)5) (CuCl5).

ChemInform ◽

10.1002/chin.199029003 ◽

1990 ◽

Vol 21 (29) ◽

Author(s):

J. PONS ◽

A. SOLANS ◽

J. C. BAYON ◽

E. MOLINS ◽

J. CASABO ◽

...

Keyword(s):

Crystal Structure ◽

Double Complex ◽

Double Complex Salts ◽

Complex Salts

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Cobaloxime-Based Double Complex Salts as Efficient and Versatile Catalysts for the Light-Driven Hydrogen Evolution Reaction

10.26434/chemrxiv.11537661 ◽

2020 ◽

Author(s):

Elisabeth Hofmeister ◽

Jisoo Woo ◽

Tobias Ullrich ◽

Lydia Petermann ◽

Kevin Hanus ◽

...

Keyword(s):

Hydrogen Evolution ◽

Hydrogen Evolution Reaction ◽

Systematic Study ◽

Cobalt Complexes ◽

Spectroscopic Studies ◽

Double Complex ◽

Double Complex Salts ◽

Noble Metal Catalysts ◽

Reduction Potentials ◽

Complex Salts

Cobaloximes and their BF2-bridged analogues have emerged as promising non-noble metal catalysts for the photocatalytic hydrogen evolution reaction (HER). Herein we report the serendipitous discovery that double complex salts such as [Co(dmgh)2py2]+[Co(dmgBPh2)2Cl2]- can be obtained in good yields by treatment of commercially available [Co(dmgh)2pyCl] with triarylboranes. A systematic study on the use of such double complex salts and their single salts with simple counterions as photocatalysts revealed HER activities comparable or superior to existing cobaloxime catalysts and suggests ample opportunities for this compound class in catalyst/photosensitizer dyads and immobilized architectures. Preliminary electrochemical and spectroscopic studies indicate that one key advantage of these charged cobalt complexes is that the reduction potentials as well as the electrostatic interaction with charged photosensitizers can be tuned.

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