ChemInform Abstract: Isostructuralism in Double Complex Salts Series: (M(H2O)x(NH3)6-x) (M′(CN)6) and (M(H2O)x(NH3)6-x) (CuCl5) (M,M′: Co(III), Cr(III); x = 0, 1, 2). Crystal Structure of (Cr(H2O)(NH3)5) (CuCl5).

ChemInform ◽  
1990 ◽  
Vol 21 (29) ◽  
Author(s):  
J. PONS ◽  
A. SOLANS ◽  
J. C. BAYON ◽  
E. MOLINS ◽  
J. CASABO ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Double Complex ◽  
Double Complex Salts ◽  
Complex Salts

Crystal Structure and Energy Transfer in Double-Complex Salts Composed of Tris(2,2‘-bipyridine)ruthenium(II) or Tris(2,2‘-bipyridine)osmium(II) and Hexacyanochromate(III)

1999 ◽  
Vol 38 (6) ◽  
pp. 1340-1347 ◽  
Author(s):  
Takuhiro Otsuka ◽  
Naoto Takahashi ◽  
Naoki Fujigasaki ◽  
Akiko Sekine ◽  
Yuji Ohashi ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Energy Transfer ◽  
Double Complex ◽  
Double Complex Salts ◽  
Complex Salts

Zn-containing double complex salts formed by Keggin type polyoxotungstates: Synthesis and crystal structure

2017 ◽  
Vol 43 (6) ◽  
pp. 368-372
Author(s):  
L. I. Udalova ◽  
S. A. Adonin ◽  
P. A. Abramov ◽  
I. V. Korolkov ◽  
M. N. Sokolov
Keyword(s):  
Crystal Structure ◽  
Double Complex ◽  
Synthesis And Crystal Structure ◽  
Double Complex Salts ◽  
Keggin Type ◽  
Complex Salts

Cobaloxime-Based Double Complex Salts as Efficient and Versatile Catalysts for the Light-Driven Hydrogen Evolution Reaction

2020 ◽  
Author(s):  
Elisabeth Hofmeister ◽  
Jisoo Woo ◽  
Tobias Ullrich ◽  
Lydia Petermann ◽  
Kevin Hanus ◽  
...  
Keyword(s):  
Hydrogen Evolution ◽  
Hydrogen Evolution Reaction ◽  
Systematic Study ◽  
Cobalt Complexes ◽  
Spectroscopic Studies ◽  
Double Complex ◽  
Double Complex Salts ◽  
Noble Metal Catalysts ◽  
Reduction Potentials ◽  
Complex Salts

Cobaloximes and their BF<sub>2</sub>-bridged analogues have emerged as promising non-noble metal catalysts for the photocatalytic hydrogen evolution reaction (HER). Herein we report the serendipitous discovery that double complex salts such as [Co(dmgh)<sub>2</sub>py<sub>2</sub>]<sup>+</sup>[Co(dmgBPh<sub>2</sub>)<sub>2</sub>Cl<sub>2</sub>]<sup>-</sup> can be obtained in good yields by treatment of commercially available [Co(dmgh)<sub>2</sub>pyCl] with triarylboranes. A systematic study on the use of such double complex salts and their single salts with simple counterions as photocatalysts revealed HER activities comparable or superior to existing cobaloxime catalysts and suggests ample opportunities for this compound class in catalyst/photosensitizer dyads and immobilized architectures. Preliminary electrochemical and spectroscopic studies indicate that one key advantage of these charged cobalt complexes is that the reduction potentials as well as the electrostatic interaction with charged photosensitizers can be tuned.

Synthesis of CuxNi1−x alloy nanoparticles from double complex salts and investigation of their magnetoimpedance effects

RSC Advances ◽  
2015 ◽  
Vol 5 (88) ◽  
pp. 71601-71607 ◽  
Author(s):  
Seyed Abolghasem Kahani ◽  
Mansoure Shahrokh
Keyword(s):  
Reduction Method ◽  
Chemical Reduction ◽  
Alloy Nanoparticles ◽  
Chemical Reduction Method ◽  
Double Complex ◽  
Double Complex Salts ◽  
Complex Salts

This work is a novel study of the synthesis of CuxNi1−x nanoalloy from double complex salts by chemical reduction method.

Sign in / Sign up

Export Citation Format

Share Document