Rational Design of a Novel Intercalation System. Layer-Gap Control of Crystalline Coordination Polymers, {[Cu(CA)(H2O)m](G)}n(m= 2, G = 2,5-Dimethylpyrazine and Phenazine;m= 1, G = 1,2,3,4,6,7,8,9-Octahydrophenazine)

1996 ◽  
Vol 35 (15) ◽  
pp. 4449-4461 ◽  
Author(s):  
Satoshi Kawata ◽  
Susumu Kitagawa ◽  
Hitoshi Kumagai ◽  
Chihiro Kudo ◽  
Hiroe Kamesaki ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Rational Design ◽  
Gap Control

scholarly journals Rational Design of Copper(II)–Uracil Nanoprocessed Coordination Polymers to Improve Their Cytotoxic Activity in Biological Media

2021 ◽  
Author(s):  
Verónica G. Vegas ◽  
Ana Latorre ◽  
María Luisa Marcos ◽  
Carlos J. Gómez-García ◽  
Óscar Castillo ◽  
...  
Keyword(s):  
Cytotoxic Activity ◽  
Coordination Polymers ◽  
Rational Design ◽  
Biological Media

Syntheses, structures and characterization of isomorphous CoII and NiII coordination polymers based on 2-[(1H-imidazol-1-yl)methyl]-6-methyl-1H-benzimidazole and benzene-1,4-dicarboxylate

2017 ◽  
Vol 73 (8) ◽  
pp. 645-651 ◽  
Author(s):  
Qiu-Ying Huang ◽  
Yang Zhao ◽  
Xiang-Ru Meng
Keyword(s):  
Coordination Polymers ◽  
Rational Design ◽  
Three Dimensional ◽  
Spectroscopic Properties ◽  
Polymeric Chain ◽  
Design And Synthesis ◽  
Carboxylate Groups ◽  
Metal Organic ◽  
The One ◽  
Ir Spectroscopic

Careful choice of the organic ligands is one of the most important parameters in the rational design and synthesis of coordination polymers. Aromatic polycarboxylates have been widely used in the preparation of metal–organic polymers since they can utilize various coordination modes to form diverse structures and can act as hydrogen-bond acceptors and donors in the assembly of supramolecular structures. Nitrogen-heterocyclic organic compounds have also been used extensively as ligands for the construction of polymers with interesting structures. In the polymers catena-poly[[[diaquabis{2-[(1H-imidazol-1-yl)methyl]-6-methyl-1H-benzimidazole-κN 3}cobalt(II)]-μ2-benzene-1,4-dicarboxylato-κ2 O 1:O 4] dihydrate], {[Co(C8H4O4)(C12H11N4)2(H2O)2]·2H2O} n , (I), and catena-poly[[[diaquabis{2-[(1H-imidazol-1-yl)methyl]-6-methyl-1H-benzimidazole-κN 3}nickel(II)]-μ2-benzene-1,4-dicarboxylato-κ2 O 1:O 4] dihydrate], {[Ni(C8H4O4)(C12H11N4)2(H2O)2]·2H2O} n , (II), the CoII or NiII ion lies on an inversion centre and exhibits a slightly distorted octahedral coordination geometry, coordinated by two N atoms from two imidazole rings and four O atoms from two monodentate carboxylate groups and two water molecules. The dicarboxylate ligands bridge metal ions forming a polymeric chain. The 2-[(1H-imidazol-1-yl)methyl]-6-methyl-1H-benzimidazole ligands coordinate to the CoII or NiII centres in monodentate modes through an imidazole N atom and are pendant on opposite sides of the main chain. The two structures are isomorphous. In the crystal, the one-dimensional chains are further connected through O—H...O, O—H...N and N—H...O hydrogen bonds, leading to a three-dimensional supramolecular architecture. In addition, the IR spectroscopic properties, PXRD patterns, thermogravimetric behaviours and fluorescence properties of both polymers have been investigated.

Modular, Homochiral, Porous Coordination Polymers: Rational Design, Enantioselective Guest Exchange Sorption and Ab Initio Calculations of Host-Guest Interactions

2010 ◽  
Vol 16 (34) ◽  
pp. 10348-10356 ◽  
Author(s):  
Danil N. Dybtsev ◽  
Maxim P. Yutkin ◽  
Denis G. Samsonenko ◽  
Vladimir P. Fedin ◽  
Alexey L. Nuzhdin ◽  
...  
Keyword(s):  
Ab Initio Calculations ◽  
Ab Initio ◽  
Coordination Polymers ◽  
Rational Design ◽  
Porous Coordination Polymers

Rational Design of Porous Coordination Polymers Based on Bis(phosphine)MCl2 Complexes That Exhibit High-Temperature H2 Sorption and Chemical Reactivity

2013 ◽  
Vol 135 (43) ◽  
pp. 16038-16041 ◽  
Author(s):  
Alisha M. Bohnsack ◽  
Ilich A. Ibarra ◽  
Vladimir I. Bakhmutov ◽  
Vincent M. Lynch ◽  
Simon M. Humphrey
Keyword(s):  
High Temperature ◽  
Coordination Polymers ◽  
Rational Design ◽  
Chemical Reactivity ◽  
Porous Coordination Polymers

scholarly journals From a Well-Defined Organozinc Precursor to Diverse Luminescent Coordination Polymers Based on Zn(II)-Quinolinate Building Units Interconnected by Mixed Ligand Systems

Molecules ◽  
2021 ◽  
Vol 26 (23) ◽  
pp. 7402
Author(s):  
Katarzyna Sołtys-Brzostek ◽  
Kamil Sokołowski ◽  
Iwona Justyniak ◽  
Michał K. Leszczyński ◽  
Natalia Olejnik-Fehér ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Self Assembly ◽  
Rational Design ◽  
Building Blocks ◽  
Mixed Ligand ◽  
Direct Reaction ◽  
Synthetic Strategy ◽  
Secondary Building Units ◽  
Additional Base

Introduction of photoactive building blocks into mixed-ligand coordination polymers appears to be a promising way to produce new advanced luminescent materials. However, rational design and self-assembly of the multi-component supramolecular systems is challenging from both a conceptual and synthetic perspective. Here, we report exploratory studies that investigate the potential of [Zn(q)2]2[tBuZn(OH)]2 complex (q = deprotonated 8-hydroxyquinoline) as an organozinc precursor as well as a mixed-ligand synthetic strategy for the preparation of new luminescent coordination polymers (CPs). As a result we present three new 2D mixed-ligand Zn(II)-quinolinate coordination polymers which are based on various zinc quinolinate secondary building units interconnected by two different organic linker types, i.e., deprotonated 4,4′-oxybisbenzoic acid (H2obc) as a flexible dicarboxylate linker and/or selected bipyridines (bipy). Remarkably, using the title organozinc precursors in a combination with H2obc and 4,4′-bipyridine, a novel molecular zinc quinolinate building unit, [Zn4(q)6(bipy)2(obc)2], was obtained which self-assembled into a chain-type hydrogen-bonded network. The application of the organometallic precursor allowed for its direct reaction with the selected ligands at ambient temperature, avoiding the use of both solvothermal conditions and additional base reagents. In turn, the reaction involving Zn(NO3)2, as a classical inorganic precursor, in a combination with H2obc and bipy led to a novel 1D coordination polymer [Zn2(q)2(NO3)2(bipy)]. While the presence of H2obc was essential for the formation of this coordination polymer, this ditopic linker was not incorporated into the isolated product, which indicates its templating behavior. The reported compounds were characterized by single-crystal and powder X-ray diffraction, elemental analysis as well as UV-Vis and photoluminescence spectroscopy.

scholarly journals Rational Design of Coordination Polymers with Flexible Oxyethylene Side Chains

2012 ◽  
Vol 33 (4) ◽  
pp. 1264-1267 ◽  
Author(s):  
Eun-Young Choi ◽  
Chun-Ji Gao ◽  
Suck-Hyun Lee ◽  
O-Pil Kwon
Keyword(s):  
Coordination Polymers ◽  
Rational Design ◽  
Side Chains

scholarly journals Rational Design of Carborane-Based Cu2-paddle wheel Coordination Polymers for Increased Hydrolytic Stability

2022 ◽  
Author(s):  
Zhen Li ◽  
Duane Choquesillo-Lazarte ◽  
Julio Fraile ◽  
Clara Vinas ◽  
Francesc Teixidor ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Coordination Polymers ◽  
Rational Design ◽  
Hydrolytic Stability ◽  
Paddle Wheel

A new unsymmetric carborane based dicarboxylic linker provided a 1D Cu2-paddle wheel coordination polymer (2) with much higher hydrolytic stability than the corresponding 2D Cu2-paddle wheel polymer (1), obtained from...

scholarly journals Rational Design of Dual IR and Visible Highly Luminescent Light-Lanthanides-Based Coordination Polymers

2020 ◽  
Vol 59 (15) ◽  
pp. 10673-10687 ◽  
Author(s):  
Youenn Pointel ◽  
Yan Suffren ◽  
Carole Daiguebonne ◽  
François Le Natur ◽  
Stéphane Freslon ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Rational Design ◽  
Light Lanthanides

Molecular Paneling in the Rational Design of Calixarene Coordination Polymers

2013 ◽  
Vol 13 (7) ◽  
pp. 2703-2706 ◽  
Author(s):  
Piotr P. Cholewa ◽  
Christine M. Beavers ◽  
Simon J. Teat ◽  
Scott J. Dalgarno
Keyword(s):  
Coordination Polymers ◽  
Rational Design
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