Rational Design of Porous Coordination Polymers Based on Bis(phosphine)MCl2 Complexes That Exhibit High-Temperature H2 Sorption and Chemical Reactivity

2013 ◽  
Vol 135 (43) ◽  
pp. 16038-16041 ◽  
Author(s):  
Alisha M. Bohnsack ◽  
Ilich A. Ibarra ◽  
Vladimir I. Bakhmutov ◽  
Vincent M. Lynch ◽  
Simon M. Humphrey
Keyword(s):  
High Temperature ◽  
Coordination Polymers ◽  
Rational Design ◽  
Chemical Reactivity ◽  
Porous Coordination Polymers

Modular, Homochiral, Porous Coordination Polymers: Rational Design, Enantioselective Guest Exchange Sorption and Ab Initio Calculations of Host-Guest Interactions

2010 ◽  
Vol 16 (34) ◽  
pp. 10348-10356 ◽  
Author(s):  
Danil N. Dybtsev ◽  
Maxim P. Yutkin ◽  
Denis G. Samsonenko ◽  
Vladimir P. Fedin ◽  
Alexey L. Nuzhdin ◽  
...  
Keyword(s):  
Ab Initio Calculations ◽  
Ab Initio ◽  
Coordination Polymers ◽  
Rational Design ◽  
Porous Coordination Polymers

Porous coordination polymers constructed from anisotropic metal–carboxylate–pyridyl clusters

2012 ◽  
Vol 85 (2) ◽  
pp. 405-416 ◽  
Author(s):  
Yue-Biao Zhang ◽  
Jie-Peng Zhang
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
Rational Design ◽  
Building Blocks ◽  
Metal Carboxylate ◽  
Porous Coordination Polymers ◽  
Isotropic Metal ◽  
And Control ◽  
Anisotropic Metal

While isotropic metal–carboxylate clusters as secondary building blocks have enabled the rational design of porous coordination polymers (PCPs) with predictable topologies, augmented metal–carboxylate–pyridyl clusters can be used as anisotropic secondary building blocks to facilitate the construction of higher-connectivity frameworks and control over structural directionality in self-assembly.

The Influence of Diamagnetic Substrates Absorption on Magnetic Properties of Porous Coordination Polymers

2013 ◽  
Vol 3 (2) ◽  
pp. 144-160 ◽  
Author(s):  
Sergey Kolotilov ◽  
Mikhail Kiskin ◽  
Igor Eremenko ◽  
Vladimir Novotortsev
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymers ◽  
Porous Coordination Polymers

Photochromism and photomagnetism in three cyano-bridged 3d-4f heterobimetallic viologen frameworks

2021 ◽  
Author(s):  
Meng-Hua Li ◽  
Ming-Hua You ◽  
Mei-Jin Lin
Keyword(s):  
Electrical Conductivity ◽  
Coordination Polymers ◽  
Porous Coordination Polymers

The incorporation of photochromic moieties into porous coordination polymers is of particular interest due to it can endow them various switchable functions in the electrical conductivity, luminescence, and magnetism. In...

Host–Guest Interaction Modulation in Porous Coordination Polymers for Inverse Selective CO 2 /C 2 H 2 Separation

2021 ◽  
Author(s):  
Yifan Gu ◽  
Jia‐Jia Zheng ◽  
Ken‐ichi Otake ◽  
Mohana Shivanna ◽  
Shigeyoshi Sakaki ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Porous Coordination Polymers

scholarly journals Rational Design of Copper(II)–Uracil Nanoprocessed Coordination Polymers to Improve Their Cytotoxic Activity in Biological Media

2021 ◽  
Author(s):  
Verónica G. Vegas ◽  
Ana Latorre ◽  
María Luisa Marcos ◽  
Carlos J. Gómez-García ◽  
Óscar Castillo ◽  
...  
Keyword(s):  
Cytotoxic Activity ◽  
Coordination Polymers ◽  
Rational Design ◽  
Biological Media

The Synthesis and Catalytic Application of a New Class of Imprinted Silica

2003 ◽  
Vol 787 ◽  
Author(s):  
John D. Bass ◽  
Sandra L. Anderson ◽  
Alexander Katz
Keyword(s):  
Rational Design ◽  
Chemical Reactivity ◽  
Phenylboronic Acid ◽  
Coupling Reaction ◽  
Suzuki Coupling ◽  
Outer Sphere ◽  
Suzuki Coupling Reaction ◽  
New Class ◽  
Catalytic Application ◽  
Rate Acceleration

AbstractThe effect of chemical environment surrounding a synthetic heterogeneous catalyst active site is investigated using the hydrophilic imprinting of silica. Two model reaction systems have been used for this study: (i) Knoevenagel condensation of 3-nitrobenzaldehyde and malononitrile and (ii) Suzuki coupling of bromobenzene and phenylboronic acid. Using a catalyst in which isolated imprinted amines are surrounded by an acidic silanol-rich environment led to rate accelerations of over 120-fold relative to catalysts in which the amines are surrounded by a hydrophobic environment consisting of trimethylsilyl functional groups for system (i). This result parallels our previous study on the effect of the outer sphere composition on rate acceleration of Knoevenagel reactions using isophthalaldehyde as the aldehyde reactant. We also extended our method for the hydrophilic imprinting of bulk silica to organometallic systems, by successfully synthesizing a tethered palladium complex within the imprinted pocket. This material was used as an active catalyst for (ii). Our results show that a hydrophobic framework environment results in higher initial turnover frequencies than an acidic silanol-rich framework for the Suzuki coupling reaction of bromobenzene and phenylboronic acid, albeit with a lower overall effect than observed in the Knoevenagel system (i). Altogether, these results demonstrate the control of chemical reactivity via the rational design of the outer sphere using an imprinting approach.

scholarly journals The High-Temperature Chemical Reactivity of Li2O

2010 ◽  
Vol 171 (1) ◽  
pp. 108-122 ◽  
Author(s):  
G. F. Kessinger ◽  
A. R. Jurgensen ◽  
D. M. Missimer ◽  
J. S. Morrell
Keyword(s):  
High Temperature ◽  
Chemical Reactivity

The chemistry and applications of flexible porous coordination polymers

EnergyChem ◽  
2021 ◽  
pp. 100067
Author(s):  
Nibedita Behera ◽  
Jingui Duan ◽  
Wanqin Jin ◽  
Susumu Kitagawa
Keyword(s):  
Coordination Polymers ◽  
Porous Coordination Polymers
Sign in / Sign up

Export Citation Format

Share Document