Heterobimetallic Complexes with Phenylcyclopentadienyl Ligand:  Syntheses and Structures of Tricarbonylchromium−η6,η5-Phenylcyclopentadienyl−Transition Metal Complexes1

1997 ◽  
Vol 36 (7) ◽  
pp. 1286-1295 ◽  
Author(s):  
Changtao Qian ◽  
Jianhua Guo ◽  
Jie Sun ◽  
Jian Chen ◽  
Peiju Zheng
Keyword(s):  
Transition Metal ◽  
Heterobimetallic Complexes

Highly versatile heteroditopic ligand scaffolds for accommodating group 8, 9 & 11 heterobimetallic complexes

2017 ◽  
Vol 46 (41) ◽  
pp. 14406-14419 ◽  
Author(s):  
Mark R. D. Gatus ◽  
Mohan Bhadbhade ◽  
Barbara A. Messerle
Keyword(s):  
Transition Metal ◽  
Metal Ions ◽  
Transition Metal Ions ◽  
Heterobimetallic Complexes ◽  
Ligand Scaffolds

Two highly versatile xanthene scaffolds containing pairs of heteroditopic ligands were found to be capable of accommodating a range of transition metal ions, including Au(i), Ir(i), Ir(iii), Rh(i), and Ru(ii) to generate an array of heterobimetallic complexes.

scholarly journals Orbital energy mismatch engenders high-spin ground states in heterobimetallic complexes

2020 ◽  
Vol 11 (36) ◽  
pp. 9971-9977 ◽  
Author(s):  
Scott C. Coste ◽  
Tyler J. Pearson ◽  
Alison B. Altman ◽  
Ryan A. Klein ◽  
Brian A. Finney ◽  
...  
Keyword(s):  
Transition Metal ◽  
High Spin ◽  
Ground States ◽  
Orbital Energy ◽  
Bimetallic Complex ◽  
Spin Configuration ◽  
Heterobimetallic Complexes ◽  
Orbital Energies ◽  
Tin Complexes

We report a series of high spin bimetallic transition metal–tin complexes. The unusual high spin configuration in a bimetallic complex is enabled by an energetic mismatch in the orbital energies, leading to lanthanide-like nonbonding interactions.

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