Oxygen Atom Transfer, Coupled Electron−Proton Transfer, and Correlated Electron−Nucleophile Transfer Reactions of Oxomolybdenum(IV) and Dioxomolybdenum(VI) Complexes

1996 ◽  
Vol 35 (4) ◽  
pp. 1050-1058 ◽  
Author(s):  
Les J. Laughlin ◽  
Charles G. Young
Keyword(s):  
Oxygen Atom ◽  
Proton Transfer ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Correlated Electron ◽  
Electron Proton Transfer

Nonclassical oxygen atom transfer reactions of an eight-coordinate dioxomolybdenum(vi) complex

2021 ◽  
Author(s):  
Leila G. Ranis ◽  
Jacqueline Gianino ◽  
Justin M. Hoffman ◽  
Seth N. Brown
Keyword(s):  
Oxygen Atom ◽  
Transfer Reaction ◽  
Transfer Reactions ◽  
Atom Transfer ◽  
Oxygen Atom Transfer ◽  
Oxygen Atom Transfer Reactions ◽  
Atom Transfer Reactions ◽  
Oxygen Atoms

Eight-coordinate MoO2(DOPOQ)2 can donate two oxygen atoms to substrates such as phosphines in a four-electron nonclassical oxygen atom transfer reaction.

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