Photoinduced effects on the magnetic properties of the (Fe0.2Cr0.8)1.5[Cr(CN)6] Prussian blue analogue

2019 ◽  
Vol 7 (8) ◽  
pp. 2305-2317
Author(s):  
Francisco Jesús Luque ◽  
Iwona Agnieszka Kowalik ◽  
Juan Pablo Prieto-Ruiz ◽  
Miguel Ángel Niño ◽  
Helena Prima-García ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Charge Transfer ◽  
Visible Light ◽  
Prussian Blue ◽  
Magnetic Moments ◽  
Lattice Misfit ◽  
Prussian Blue Analogue

Visible light absorbed by Fe cations in a Prussian blue analogue induces charge transfer, and reduces lattice misfit and magnetic moments.

scholarly journals First Principles Study on the Effect of Pressure on the Structure, Elasticity, and Magnetic Properties of Cubic GaFe(CN)6 Prussian Blue Analogue

2019 ◽  
Vol 9 (8) ◽  
pp. 1607 ◽  
Author(s):  
Chuankun Zhang ◽  
Haiming Huang ◽  
Shijun Luo
Keyword(s):  
Mechanical Properties ◽  
Magnetic Properties ◽  
Prussian Blue ◽  
First Principles ◽  
Magnetic Moments ◽  
External Pressure ◽  
Half Metallicity ◽  
Obvious Effect ◽  
Prussian Blue Analogue ◽  
Half Metallic

The structure, elasticity, and magnetic properties of Prussian blue analogue GaFe(CN)6 under external pressure ranges from 0 to 40 GPa were studied by first principles calculations. In the range of pressure from 0 to 35 GPa, GaFe(CN)6 not only has the half-metallic characteristics of 100% spin polarization, but also has stable mechanical properties. The external pressure has no obvious effect on the crystal structure and anisotropy of GaFe(CN)6, but when the pressure exceeds 35 GPa, the half-metallicity of GaFe(CN)6 disappears, the mechanical properties are no longer stable, and total magnetic moments per formula unit are no longer integer values.

Designing heterostructurated core@satellites Prussian Blue Analogue@Au-Ag nanoparticles: effect on the magnetic properties and catalytic activity

2021 ◽  
Author(s):  
Ekaterina Mamontova ◽  
María Rodríguez-Castillo ◽  
Erwan Oliviero ◽  
Yannick Guari ◽  
Joulia Larionova ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Catalytic Activity ◽  
Prussian Blue ◽  
Molecular Complex ◽  
Ag Nanoparticles ◽  
Prussian Blue Analogue

We report in this article new magneto-plasmonic core@satellites Prussian Blue Analogue (PBA)@Au-Ag nanoheterostructures obtained by using a post-synthetic impregnation of a bimetallic [AuI2AgI2(C6F5)4(OEt2)2]n molecular complex with the ferromagnetic K+/Ni2+/[Cr(CN)6]3− PBA...

scholarly journals Ab-Initio Study of the Electronic and Magnetic Properties of Boron- and Nitrogen-Doped Penta-Graphene

Nanomaterials ◽  
2020 ◽  
Vol 10 (4) ◽  
pp. 816 ◽  
Author(s):  
Chao Zhang ◽  
Yu Cao ◽  
Xing Dai ◽  
Xian-Yong Ding ◽  
Leilei Chen ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Charge Transfer ◽  
First Principles ◽  
Magnetic Moments ◽  
First Principles Calculations ◽  
Electronic Band ◽  
Magnetic Devices ◽  
Spin Polarized ◽  
Electronic Band Gap ◽  
Transfer Mechanisms

First-principles calculations were performed to investigate the effects of boron/nitrogen dopant on the geometry, electronic structure and magnetic properties of the penta-graphene system. It was found that the electronic band gap of penta-graphene could be tuned and varied between 1.88 and 2.12 eV depending on the type and location of the substitution. Moreover, the introduction of dopant could cause spin polarization and lead to the emergence of local magnetic moments. The main origin of the magnetic moment was analyzed and discussed by the examination of the spin-polarized charge density. Furthermore, the direction of charge transfer between the dopant and host atoms could be attributed to the competition between the charge polarization and the atomic electronegativity. Two charge-transfer mechanisms worked together to determine which atoms obtained electrons. These results provide the possibility of modifying penta-graphene by doping, making it suitable for future applications in the field of optoelectronic and magnetic devices.

Thickness Dependent Magnetic Properties of Thin Films of Prussian Blue Analogue Fe[sub 1.5][Cr(CN)[sub 6]]⋅7.5H[sub 2]O

2011 ◽  
Author(s):  
Pramod Bhatt ◽  
S. M. Yusuf ◽  
M. D. Mukadam ◽  
J. V. Yakhmi ◽  
Amitabha Ghoshray ◽  
...  
Keyword(s):  
Thin Films ◽  
Magnetic Properties ◽  
Prussian Blue ◽  
Prussian Blue Analogue

scholarly journals Charge transfer driven by ultrafast spin transition in a CoFe Prussian blue analogue

2020 ◽  
Vol 13 (1) ◽  
pp. 10-14
Author(s):  
Marco Cammarata ◽  
Serhane Zerdane ◽  
Lodovico Balducci ◽  
Giovanni Azzolina ◽  
Sandra Mazerat ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Prussian Blue ◽  
Spin Transition ◽  
Prussian Blue Analogue

Out-of-equilibrium lattice response to photo-induced charge-transfer in a MnFe Prussian blue Analogue

2021 ◽  
Author(s):  
Giovanni azzolina ◽  
Roman Bertoni ◽  
Celine Mariette ◽  
Marco Cammarata ◽  
Elzbieta Trzop ◽  
...  
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Energy Dissipation ◽  
Prussian Blue ◽  
Structural Dynamics ◽  
Lattice Dynamics ◽  
The Self ◽  
Prussian Blue Analogue ◽  
Induced Charge ◽  
Main Components

Photo-induced structural dynamics in molecular materials often involve two main components; local molecular distortions induced by the self-trapping of electronic excited state and incoherent lattice dynamics due to energy dissipation....

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