4-(2-Tetrathiafulvalenyl-ethenyl)pyridine (TTF−CH═CH−Py) Radical Cation Salts Containing Poly(β-diketonate) Rare Earth Complexes: Synthesis, Crystal Structure, Photoluminescent and Magnetic Properties

2009 ◽  
Vol 48 (15) ◽  
pp. 7421-7429 ◽  
Author(s):  
Fabrice Pointillart ◽  
Olivier Maury ◽  
Yann Le Gal ◽  
Stéphane Golhen ◽  
Olivier Cador ◽  
...  
2021 ◽  
Author(s):  
Andreas Schnepf ◽  
Svetlana Klementyeva ◽  
Claudio Schrenk ◽  
Marat M Khusniyarov ◽  
Minghui Zhang

We report the synthesis, structure and magnetic properties of the first rare earth complexes of metalloid group 14 clusters [(thf)2Ln(Ge9Hyp3)2] (Ln = Eu, Sm, Hyp = Si(SiMe3)3). X-ray crystallographic analysis...


2008 ◽  
Vol 463 (1-2) ◽  
pp. 338-342 ◽  
Author(s):  
Na Zhao ◽  
Shu-Ping Wang ◽  
Rui-Xia Ma ◽  
Zhi-Hua Gao ◽  
Rui-Fen Wang ◽  
...  

2016 ◽  
Vol 848 ◽  
pp. 709-714 ◽  
Author(s):  
Gang Fu ◽  
Jiang Wang ◽  
Mao Hua Rong ◽  
Guang Hui Rao ◽  
Huai Ying Zhou

The rare-earth (RE) permanent magnets based on Nd2Fe14B with excellent magnetic properties have been widely used in industrial applications. In this work, the crystal structure, microstructure and magnetic properties of Nd2.28Fe13.58B1.14, Ce2.28Fe13.58B1.14 and Pr2.28Fe13.58B1.14 alloys prepared by arc-melting were investigated. The results show that all alloys are single phase with tetragonal Nd2Fe14B-type (space group P42/mnm). The Curie temperatures (Tc) of RE2.28Fe13.58B1.14 (RE=Nd, Ce, Pr) alloys are 583 K, 423 K and 557 K, respectively. On the other hand, the coercivities of Nd2.28Fe13.58B1.14 and Pr2.28Fe13.58B1.14 alloys are about 1.05 T and 1.23 T, respectively, while that of Ce2.28Fe13.58B1.14 alloy is only about 0.25 T due to the poor squareness of hysteresis loop. Meanwhile, the saturation magnetizations of Nd2.28Fe13.58B1.14 and Pr2.28Fe13.58B1.14 alloys are about 135 emu/g and 113 emu/g, respectively, while that of Ce2.28Fe13.58B1.14 alloy is about 97 emu/g. It was indicated that the Curie temperatures and magnetic properties of RE2.28Fe13.58B1.14 alloys with the same crystal structure are dependent on light rare earth elements.


1995 ◽  
Vol 30 (7) ◽  
pp. 985-989 ◽  
Author(s):  
L. N. Bozukov ◽  
M. M. Milanova ◽  
D. S. Todorovsky

2004 ◽  
Vol 61 (3) ◽  
pp. 405-410 ◽  
Author(s):  
Jianbin Tang ◽  
Liming Jiang ◽  
Weilin Sun ◽  
Zhiquan Shen

Polyhedron ◽  
2011 ◽  
Vol 30 (13) ◽  
pp. 2195-2202 ◽  
Author(s):  
Dipak K. Hazra ◽  
Rupam Sen ◽  
Subratanath Koner ◽  
Madeleine Helliwell ◽  
Monika Mukherjee

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