Radical cation salts of TTF(CH2OH)4 with cyanide anions: Synthesis, crystal structure and magnetic properties of [TTF(CH2OH)4][TCNQF4] and [TTF(CH2OH)4]3[18-crown-6⊂K][M(CN)6]·DMF (M=Fe, Co)

Polyhedron ◽  
2005 ◽  
Vol 24 (12) ◽  
pp. 1555-1564 ◽  
Author(s):  
Sandrine Perruchas ◽  
Kamal Boubekeur ◽  
Philippe Molinié
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Radical Cation ◽  
Radical Cation Salts

Radical-cation salts based on TTF(s)–DHTTF (dihydrotetrathiafulvalene) fused donors: electrical conductivities and crystal structure

1996 ◽  
pp. 2517-2518 ◽  
Author(s):  
Jun-ichi Yamada ◽  
Sachinori Mishima ◽  
Hiroyuki Anzai ◽  
Masafumi Tamura ◽  
Yutaka Nishio ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Radical Cation ◽  
Electrical Conductivities ◽  
Radical Cation Salts

The radical cation iodide of the new electron donor tetraiodotetrathiafulvalene: Magnetic properties and crystal structure

1995 ◽  
Vol 7 (1) ◽  
pp. 41-43 ◽  
Author(s):  
Rudolf Gompper ◽  
Joachim Hock ◽  
Kurt Polborn ◽  
Elmar Dormann ◽  
Hubert Winter
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Radical Cation ◽  
Electron Donor

scholarly journals First Molecular Superconductor with the Tris(Oxalato)Aluminate Anion, β″-(BEDT-TTF)4(H3O)Al(C2O4)3·C6H5Br, and Isostructural Tris(Oxalato)Cobaltate and Tris(Oxalato)Ruthenate Radical Cation Salts

2021 ◽  
Vol 7 (7) ◽  
pp. 90
Author(s):  
Toby James Blundell ◽  
Michael Brannan ◽  
Joey Mburu-Newman ◽  
Hiroki Akutsu ◽  
Yasuhiro Nakazawa ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Metal Ions ◽  
Radical Cation ◽  
Research Group ◽  
Subsequent Research ◽  
Β Phase ◽  
Structures And Properties ◽  
Paramagnetic Metal ◽  
Radical Cation Salts ◽  
Superconducting Tc

Peter Day’s research group reported the first molecular superconductor containing paramagnetic metal ions in 1995, β″-(BEDT-TTF)4(H3O)Fe(C2O4)3·C6H5CN. Subsequent research has produced a multitude of BEDT-TTF-tris(oxalato)metallate salts with a variety of structures and properties, including 32 superconductors to date. We present here the synthesis, crystal structure, and conducting properties of the newest additions to the Day series including the first superconductor incorporating the diamagnetic tris(oxalato)aluminate anion, β″-(BEDT-TTF)4(H3O)Al(C2O4)3·C6H5Br, which has a superconducting Tc of ~2.5 K. β″-(BEDT-TTF)4(H3O)Co(C2O4)3·C6H5Br represents the first example of a β″ phase for the tris(oxalato)cobaltate anion, but this salt does not show superconductivity.

Crystal Structure and Magnetic Properties of Organic Radical Cation Salt, α-(Benzo[1,2-d:4,5-d′]bis[1,3,2]dithiazole)2ReBr6

2010 ◽  
Vol 39 (10) ◽  
pp. 1096-1098 ◽  
Author(s):  
Ken-ichi Suzuki ◽  
Takeshi Kodama ◽  
Koichi Kikuchi ◽  
Wataru Fujita
Keyword(s):  
Crystal Structure ◽  
Magnetic Properties ◽  
Radical Cation ◽  
Organic Radical ◽  
Radical Cation Salt
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