α- to β-(dmes)BiI5(dmes = Dimethyl(2-ethylammonium)sulfonium Dication): Umbrella Reversal of Sulfonium in the Solid State and Short I···I Interchain ContactsCrystal Structures, Optical Properties, and Theoretical Investigations of 1D Iodobismuthates

2009 ◽  
Vol 48 (3) ◽  
pp. 879-888 ◽  
Author(s):  
Nicolas Louvain ◽  
Nicolas Mercier ◽  
Florent Boucher
Keyword(s):  
Optical Properties ◽  
Solid State ◽  
Crystal Structures ◽  
Theoretical Investigations

Solid-State Optical Properties and Crystal Structures of 1,4-Dipropoxy-9,10-anthraquinone Polymorphs

2015 ◽  
Vol 88 (5) ◽  
pp. 713-715 ◽  
Author(s):  
Chitoshi Kitamura ◽  
Sining Li ◽  
Munenori Takehara ◽  
Yoshinori Inoue ◽  
Katsuhiko Ono ◽  
...  
Keyword(s):  
Optical Properties ◽  
Solid State ◽  
Crystal Structures

Synthesis, crystal structures, and solid state quadratic nonlinear optical properties of a series of stilbazolium cations combined with gold cyanide counter-ion

2011 ◽  
Vol 21 (40) ◽  
pp. 15940 ◽  
Author(s):  
Pascal G. Lacroix ◽  
M. Carmen Munoz ◽  
Ana Belén Gaspar ◽  
José Antonio Real ◽  
Sébastien Bonhommeau ◽  
...  
Keyword(s):  
Optical Properties ◽  
Solid State ◽  
Crystal Structures ◽  
Nonlinear Optical ◽  
Nonlinear Optical Properties ◽  
Gold Cyanide ◽  
Counter Ion

Distibylation of Acetylenes with Ph2Sb–SbPh2: Synthesis, Crystal Structures and Phosphorescence Properties of Bis(diphenylstibyl)ethenes

2014 ◽  
Vol 69 (11-12) ◽  
pp. 1181-1187
Author(s):  
Joji Ohshita ◽  
Toshiyuki Tsuchida ◽  
Kazuya Murakami ◽  
Yousuke Ooyama ◽  
Takayuki Nakanishi ◽  
...  
Keyword(s):  
Optical Properties ◽  
Solid State ◽  
Low Temperature ◽  
Crystal Structures ◽  
Uv Absorption ◽  
Similar Reaction ◽  
Photoluminescence Spectra ◽  
X Ray Diffraction ◽  
X Ray

Abstract Treatment of tetraphenyldistibine (1) with terminal arylacetylenes, XC6H5C≡CH (2a-c, X=H, F, OMe), gave the corresponding anti-addition products (E)-aryl-1,2-bis(diphenylstibyl)ethenes 3a-c in 11 - 17% yields. A similar reaction of 1 with 1,4-diphenylbutadiyne provided (E)-1,4-diphenyl- 1,2-bis(diphenylstibyl)but-1-en-3-yne (3d) in 28% yield. X-Ray diffraction studies on crystals of 3a, 3b and 3d revealed a congested configuration around the ethylene core. The optical properties of the adducts 3a-d were examined by measuring UV absorption and photoluminescence spectra. Interestingly, 3d showed phosphorescence in the solid state, which was enhanced at low temperature.

Quantum optics with nitrogen-vacancy centres in diamond

2017 ◽  
Author(s):  
Yiwen Chu ◽  
Mikhail D. Lukin
Keyword(s):  
Optical Properties ◽  
Quantum Information ◽  
Solid State ◽  
Quantum Optics ◽  
Quantum States ◽  
Nitrogen Vacancy ◽  
Common Theme ◽  
External Effects ◽  
Promising Candidate ◽  
Optical Photons

A common theme in the implementation of quantum technologies involves addressing the seemingly contradictory needs for controllability and isolation from external effects. Undesirable effects of the environment must be minimized, while at the same time techniques and tools must be developed that enable interaction with the system in a controllable and well-defined manner. This chapter addresses several aspects of this theme with regard to a particularly promising candidate for developing applications in both metrology and quantum information, namely the nitrogen-vacancy (NV) centre in diamond. The chapter describes how the quantum states of NV centres can be manipulated, probed, and efficiently coupled with optical photons. It also discusses ways of tackling the challenges of controlling the optical properties of these emitters inside a complex solid state environment.

scholarly journals Functionalised Terpyridines and Their Metal Complexes—Solid-State Interactions

Chemistry ◽  
2021 ◽  
Vol 3 (1) ◽  
pp. 199-227
Author(s):  
Young Hoon Lee ◽  
Jee Young Kim ◽  
Sotaro Kusumoto ◽  
Hitomi Ohmagari ◽  
Miki Hasegawa ◽  
...  
Keyword(s):  
Solid State ◽  
Metal Complexes ◽  
Crystal Structures ◽  
Weak Interactions ◽  
Dispersion Interactions ◽  
Derivatives Of

Analysis of the weak interactions within the crystal structures of 33 complexes of various 4′-aromatic derivatives of 2,2′:6′,2″-terpyridine (tpy) shows that interactions that exceed dispersion are dominated, as expected, by cation⋯anion contacts but are associated with both ligand–ligand and ligand–solvent contacts, sometimes multicentred, in generally complicated arrays, probably largely determined by dispersion interactions between stacked aromatic units. With V(V) as the coordinating cation, there is evidence that the polarisation of the ligand results in an interaction exceeding dispersion at a carbon bound to nitrogen with oxygen or fluorine, an interaction unseen in the structures of M(II) (M = Fe, Co, Ni, Cu, Zn, Ru and Cd) complexes, except when 1,2,3-trimethoxyphenyl substituents are present in the 4′-tpy.

Synthesis, structure and optical properties of europium doped calcium barium phosphate – a novel phosphor for solid-state lighting

2014 ◽  
Vol 2 (30) ◽  
pp. 6084 ◽  
Author(s):  
Naoyuki Komuro ◽  
Masayoshi Mikami ◽  
Yasuo Shimomura ◽  
Erica G. Bithell ◽  
Anthony K. Cheetham
Keyword(s):  
Optical Properties ◽  
Solid State ◽  
Solid State Lighting

Bis(1-phenyl-1-propyne) complexes of tungsten(II): crystal structures of [WI2(CO)(NCR)(η2-MeC2Ph)2] (R = Me, Et, or Ph)

2001 ◽  
Vol 79 (3) ◽  
pp. 263-271
Author(s):  
Paul K Baker ◽  
Michael GB Drew ◽  
Deborah S Evans
Keyword(s):  
Carbon Monoxide ◽  
Solid State ◽  
Crystal Structures ◽  
Octahedral Geometry ◽  
X Ray ◽  
X Ray Crystallography ◽  
Alkyne Complexes ◽  
First Time

Reaction of [WI2(CO)3(NCMe)2] with two equivalents of 1-phenyl-1-propyne (MeC2Ph) in CH2Cl2, and in the absence of light, gave the bis(1-phenyl-1-propyne) complex [WI2(CO)(NCMe)(η2-MeC2Ph)2] (1) in 77% yield. Treatment of equimolar quantities of 1 and NCR (R = Et, i-Pr, t-Bu, Ph) in CH2Cl2 afforded the nitrile-exchanged products, [WI2(CO)(NCR)(η2-MeC2Ph)2] (2-5) (R = Et (2), i-Pr (3), t-Bu (4), Ph (5)). Complexes 1, 2, and 5 were structurally characterized by X-ray crystallography. All three structures have the same pseudo-octahedral geometry, with the equatorial sites being occupied by cis and parallel alkyne groups, which are trans to the cis-iodo groups. The trans carbon monoxide and acetonitrile ligands occupy the axial sites. In structures 1 and 2, the methyl and phenyl substituents of the 1-phenyl-1-propyne ligands are cis to each other, whereas for the bulkier NCPh complex (5), the methyl and phenyl groups are trans to one another. This is the first time that this arrangement has been observed in the solid state in bis(alkyne) complexes of this type.Key words: bis(1-phenyl-1-propyne), carbonyl, nitrile, diiodo, tungsten(II), crystal structures.

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