One-Dimensional Manganese Coordination Polymers Composed of Polynuclear Cluster Blocks and Polypyridyl Linkers: Structures and Properties

2008 ◽  
Vol 47 (23) ◽  
pp. 11108-11119 ◽  
Author(s):  
Svetlana G. Baca ◽  
Iurii L. Malaestean ◽  
Tony D. Keene ◽  
Harry Adams ◽  
Michael D. Ward ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
One Dimensional ◽  
Structures And Properties ◽  
Polynuclear Cluster

Syntheses, crystal structures and properties of three cyano-bridged one-dimensional coordination polymers based on macrocyclic metallic tectons

RSC Advances ◽  
2015 ◽  
Vol 5 (25) ◽  
pp. 19034-19040 ◽  
Author(s):  
Xiang Jiang ◽  
Bo Tao ◽  
Xiaoli Yu ◽  
Yunhong Wang ◽  
Hua Xia
Keyword(s):  
Porous Structure ◽  
Pore Size ◽  
Crystal Structures ◽  
Coordination Polymers ◽  
One Dimensional ◽  
Structures And Properties ◽  
Adsorption Of Co

Three complexes based on macrocyclic metallic tectons and [Ni(CN)4]2− have been reported. Interestingly, complex 1 features an unexpected large porous structure with a pore size of 1 nm, which shows two-step adsorption of CO2 gas at 195 K.

Syntheses, structures and properties of two one-dimensional coordination polymers constructed by phenol-sulfonate ligands and rare earth metal ions

2020 ◽  
Vol 19 (3) ◽  
pp. 245-255
Author(s):  
Lei Guan ◽  
Hong-Zhe Jin ◽  
Ying Wang ◽  
Xue-Jia Xiong ◽  
Ya-Xu Chen ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Near Infrared ◽  
Earth Metal ◽  
Infrared Emission ◽  
Disodium Salt ◽  
X Ray Diffraction ◽  
One Dimensional ◽  
X Ray ◽  
Structures And Properties ◽  
Elemental Analyses

Two new isomorphic and heterogeneous coordination polymers (CPs), namely {[RE (L) (H2O) 2] · (Hbipy) · H2O} n (RE = Yb(1), Y(2), Na2H2L = 4,5-dihydroxy-1,3-benzenedisulfonic acid disodium salt, bipy = 2,2′-bipyridine) have been synthesized by hydrothermal methods and structurally characterized by elemental analyses, power X-ray diffraction (PXRD) and single crystal X-ray diffraction. Compounds 1 and 2 feature one-dimensional (1D) wavy ladder-like chain structures, which are further connected by hydrogen bonds from water molecules to result in two-dimensional (2D) layered structures. The 1H-protonated bipy molecules act as uncoordinated cations, leading to valences of zero in compounds 1 and 2. Compounds 1 and 2 emit luminescence at 382 nm and 372 nm in the ultraviolet regions, respectively. The luminescent emissions originate from the typical ligand-centered (n–π* and π–π*) transitions. In addition, compound 1 has characteristic near-infrared emission of ytterbium ion at 964 nm.

Anion and solvent controlled growth of crystalline and amorphous zinc(II) coordination polymers and a molecular complex

2021 ◽  
Author(s):  
Claire Deville ◽  
Henrik Særkjær Jeppesen ◽  
Vickie McKee ◽  
Nina Lock
Keyword(s):  
Coordination Polymers ◽  
Molecular Complex ◽  
Research Field ◽  
Metal Coordination ◽  
Controlled Growth ◽  
Bottom Up ◽  
One Dimensional

Controlled bottom-up synthesis of amorphous coordination polymers with tailored metal coordination is a research field in its infancy. In this study, synthesis control was achieved to selectively prepare one-dimensional (1D)...

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