Syntheses, crystal structures and properties of three cyano-bridged one-dimensional coordination polymers based on macrocyclic metallic tectons

RSC Advances ◽  
2015 ◽  
Vol 5 (25) ◽  
pp. 19034-19040 ◽  
Author(s):  
Xiang Jiang ◽  
Bo Tao ◽  
Xiaoli Yu ◽  
Yunhong Wang ◽  
Hua Xia

Three complexes based on macrocyclic metallic tectons and [Ni(CN)4]2− have been reported. Interestingly, complex 1 features an unexpected large porous structure with a pore size of 1 nm, which shows two-step adsorption of CO2 gas at 195 K.

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