EPR spectra and zero-field splitting of exchange-coupled copper(II)-manganese(II) pairs

1981 ◽  
Vol 20 (8) ◽  
pp. 2734-2735 ◽  
Author(s):  
L. Banci ◽  
A. Bencini ◽  
D. Gatteschi
Keyword(s):  
Epr Spectra ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting

Magnetic interactions and single-ion zero-field-splitting effects in the two-sublattice manganese chain MnMn(EDTA).cntdot.9H2O: magnetism and single-crystal EPR spectra

1991 ◽  
Vol 30 (5) ◽  
pp. 947-950 ◽  
Author(s):  
J. J. Borras-Almenar ◽  
R. Burriel ◽  
Eugenio. Coronado ◽  
D. Gatteschi ◽  
C. J. Gomez-Garcia ◽  
...  
Keyword(s):  
Single Crystal ◽  
Magnetic Interactions ◽  
Epr Spectra ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting

The Dimeric Structure of Bis(1,3-Dimethylcyclopentadienyl)titanium(III) Chloride

1996 ◽  
Vol 61 (9) ◽  
pp. 1285-1294 ◽  
Author(s):  
Karel Mach ◽  
Vojtech Varga ◽  
Günter Schmid ◽  
Jörg Hiller ◽  
Ulf Thewalt
Keyword(s):  
Crystal Structure ◽  
Triplet State ◽  
Structure Analysis ◽  
Crystal Structure Analysis ◽  
Epr Spectra ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
X Ray ◽  
Dimeric Structure

The X-ray crystal structure analysis of bis(1,3-dimethylcyclopentadienyl)titanium(III) chloride revealed that it is a centrosymmetric chlorine-bridged dimer [(η5-C5H3Me2)2Ti(μ-Cl)]2 (1) with the Ti-Ti distance of 3.9155(8) Å. Its skeleton is virtually identical with those of the [(η5-C5H5)2Ti(μ-Cl)]2 and [(η5-C5H4Me)2Ti(μ-Cl)]2 dimers. The solution EPR study proved that 1 remains a dimer in toluene whereas it dissociates in 2-methyltetrahydrofuran (MTHF) to give (η5-C5H3Me2)2TiCl . MTHF. The EPR spectra of frozen toluene solutions proved that 1 forms the triplet state whose g-tensor and zero-field splitting D are virtually the same as those of [(η5-C5H5)2Ti(μ-Cl)]2.

Importance of Fourth-Order Zero-Field Splitting Terms in Random-Orientation EPR Spectra of Eu(II)-Doped Strontium Aluminate

2003 ◽  
Vol 107 (51) ◽  
pp. 11539-11546 ◽  
Author(s):  
Hideto Matsuoka ◽  
Ko Furukawa ◽  
Kazunobu Sato ◽  
Daisuke Shiomi ◽  
Yoshitane Kojima ◽  
...  
Keyword(s):  
Fourth Order ◽  
Epr Spectra ◽  
Zero Field ◽  
Strontium Aluminate ◽  
Zero Field Splitting ◽  
Random Orientation ◽  
Order Zero ◽  
Field Splitting

scholarly journals Determination of ZFS parameters from the EPR spectra of mono-, di- and trinuclear MnIIcomplexes: impact of magnetic coupling

2017 ◽  
Vol 46 (8) ◽  
pp. 2699-2714 ◽  
Author(s):  
Luis Escriche-Tur ◽  
Mercè Font-Bardia ◽  
Belén Albela ◽  
Montserrat Corbella
Keyword(s):  
Excited States ◽  
Epr Spectroscopy ◽  
Magnetic Coupling ◽  
Epr Spectra ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
X Band

Versatility in the synthesis of MnIIcompounds. EPR spectroscopy, zero-field splitting determination, and importance of excited states. Distinction of the sign ofDMnwith the use of X-band EPR spectra.

Analysis of the EPR spectra of transferrin: the importance of a zero-field-splitting distribution and 4th-order terms

2019 ◽  
Vol 21 (31) ◽  
pp. 16937-16948 ◽  
Author(s):  
Mykhailo Azarkh ◽  
Peter Gast ◽  
Anne B. Mason ◽  
Edgar J. J. Groenen ◽  
Guinevere Mathies
Keyword(s):  
High Spin ◽  
Biological Systems ◽  
New Method ◽  
Epr Spectra ◽  
Zero Field ◽  
Zero Field Splitting ◽  
Field Splitting ◽  
Effective Use ◽  
High Spin Iron

A new method is implemented to extract the distribution of zero-field-splitting parameters from the EPR spectra of transferrin. This promotes the effective use of multi-frequency EPR to characterize high-spin iron sites in biological systems.

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