Analysis of the EPR spectra of transferrin: the importance of a zero-field-splitting distribution and 4th-order terms

Mykhailo Azarkh; Peter Gast; Anne B. Mason; Edgar J. J. Groenen; Guinevere Mathies

doi:10.1039/c9cp02626f

Analysis of the EPR spectra of transferrin: the importance of a zero-field-splitting distribution and 4th-order terms

Physical Chemistry Chemical Physics ◽

10.1039/c9cp02626f ◽

2019 ◽

Vol 21 (31) ◽

pp. 16937-16948 ◽

Cited By ~ 1

Author(s):

Mykhailo Azarkh ◽

Peter Gast ◽

Anne B. Mason ◽

Edgar J. J. Groenen ◽

Guinevere Mathies

Keyword(s):

High Spin ◽

Biological Systems ◽

New Method ◽

Epr Spectra ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting ◽

Effective Use ◽

High Spin Iron

A new method is implemented to extract the distribution of zero-field-splitting parameters from the EPR spectra of transferrin. This promotes the effective use of multi-frequency EPR to characterize high-spin iron sites in biological systems.

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A low temperature magnetic suceptibility study of the zero field splitting in seven coordinate high-spin iron(III) complexes based on a pentadentate macrocyclic nitrogen ligand

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)82790-5 ◽

1983 ◽

Vol 70 ◽

pp. 127-131 ◽

Cited By ~ 5

Author(s):

Ann Nancy Scoville ◽

William Michael Reiff

Keyword(s):

Low Temperature ◽

High Spin ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting ◽

Nitrogen Ligand ◽

High Spin Iron

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Effect of axial interaction in high-spin iron(III) porphyrins. Paramagnetic anisotropy and zero-field splitting in (tetraphenylporphyrin)iron(III) thiocyanate and iodide

Inorganic Chemistry ◽

10.1021/ic50223a009 ◽

1981 ◽

Vol 20 (9) ◽

pp. 2786-2789 ◽

Cited By ~ 15

Author(s):

D. V. Behere ◽

Roshun. Birdy ◽

Samaresh. Mitra

Keyword(s):

High Spin ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting ◽

Paramagnetic Anisotropy ◽

Axial Interaction ◽

High Spin Iron

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Paramagnetic anisotropies and zero-field splitting of some high-spin iron(III) complexes

Journal of the Chemical Society A Inorganic Physical Theoretical ◽

10.1039/j19690001422 ◽

1969 ◽

pp. 1422 ◽

Cited By ~ 47

Author(s):

M. Gerloch ◽

J. Lewis ◽

R. C. Slade

Keyword(s):

High Spin ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting ◽

High Spin Iron

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ChemInform Abstract: EFFECT OF AXIAL INTERACTION IN HIGH-SPIN IRON(III) PORPHYRINS. PARAMAGNETIC ANISOTROPY AND ZERO-FIELD SPLITTING IN (TETRAPHENYLPORPHYRIN)IRON(III) THIOCYANATE AND IODIDE

Chemischer Informationsdienst ◽

10.1002/chin.198148058 ◽

1981 ◽

Vol 12 (48) ◽

Author(s):

D. V. BEHERE ◽

R. BIRDY ◽

S. MITRA

Keyword(s):

High Spin ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting ◽

Paramagnetic Anisotropy ◽

Axial Interaction ◽

High Spin Iron

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ChemInform Abstract: A LOW-TEMPERATURE MAGNETIC SUCEPTIBILITY STUDY OF THE ZERO FIELD SPLITTING IN SEVEN-COORDINATE HIGH-SPIN IRON(III) COMPLEXES BASED ON A PENTADENTATE MACROCYCLIC NITROGEN LIGAND

Chemischer Informationsdienst ◽

10.1002/chin.198324057 ◽

1983 ◽

Vol 14 (24) ◽

Author(s):

A. N. SCOVILLE ◽

W. M. REIFF

Keyword(s):

Low Temperature ◽

High Spin ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting ◽

Nitrogen Ligand ◽

High Spin Iron

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Calculation of EPR spectra of Fe3+ with high zero-field splitting in polycrystalline materials

physica status solidi (b) ◽

10.1002/pssb.2220670206 ◽

1975 ◽

Vol 67 (2) ◽

pp. 461-469 ◽

Cited By ~ 14

Author(s):

M. Ya. Shcherbakova ◽

V. E. Istomin

Keyword(s):

Epr Spectra ◽

Polycrystalline Materials ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting

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ChemInform Abstract: MAGNETIC PROPERTIES AND ZERO-FIELD SPLITTING IN HIGH-SPIN MANGANESE(III) COMPLEXES. 2. AXIALLY LIGATED MANGANESE(III) PORPHYRIN COMPLEXES

Chemischer Informationsdienst ◽

10.1002/chin.198538052 ◽

1985 ◽

Vol 16 (38) ◽

Author(s):

B. J. KENNEDY ◽

K. S. MURRAY

Keyword(s):

Magnetic Properties ◽

High Spin ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting

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ChemInform Abstract: Low-temperature Magnetic Susceptibility and Zero-field Splitting in Some High-spin Manganese(III) Compounds

Chemischer Informationsdienst ◽

10.1002/chin.198621046 ◽

1986 ◽

Vol 17 (21) ◽

Author(s):

M. L. COFIELD ◽

P. S. BRYAN

Keyword(s):

Magnetic Susceptibility ◽

Low Temperature ◽

High Spin ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting

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EPR spectroscopy of soybean lipoxygenase-1 Determination of the zero-field splitting constants of high-spin Fe(III) signals from temperature and microwave frequency dependence

Biochimica et Biophysica Acta (BBA) - Protein Structure ◽

10.1016/0005-2795(80)90222-6 ◽

1980 ◽

Vol 624 (1) ◽

pp. 30-39 ◽

Cited By ~ 30

Author(s):

Steven Slappendel ◽

Gerrit A. Veldink ◽

Johannes F.G. Vliegenthart ◽

Roland Aasa ◽

Bo G. Malmström

Keyword(s):

Frequency Dependence ◽

High Spin ◽

Epr Spectroscopy ◽

Microwave Frequency ◽

Soybean Lipoxygenase ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting

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Simulation of multi-frequency EPR spectra for a distribution of the zero-field splitting

Journal of Magnetic Resonance ◽

10.1016/j.jmr.2015.04.006 ◽

2015 ◽

Vol 255 ◽

pp. 106-113 ◽

Cited By ~ 4

Author(s):

Mykhailo Azarkh ◽

Edgar J.J. Groenen

Keyword(s):

Epr Spectra ◽

Zero Field ◽

Zero Field Splitting ◽

Field Splitting

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