A novel bonding scheme of an allene system in a transition metal cluster complex. Molecular structure of .mu.3-.eta.-(1-methyl-3-ethyl-3-allenyl)-.mu.-hydrido-triangulo-tris(tricarbonylruthenium)(3Ru-Ru)

1976 ◽  
Vol 15 (5) ◽  
pp. 1221-1224 ◽  
Author(s):  
Giuliana. Gervasio ◽  
Domenico. Osella ◽  
Mario. Valle
Keyword(s):  
Molecular Structure ◽  
Transition Metal ◽  
Metal Cluster ◽  
Cluster Complex ◽  
Transition Metal Cluster ◽  
Allene System ◽  
Bonding Scheme

scholarly journals Synthesis and Crystal Structure of a Novel Octahedral Fe4Cr2 Transition Metal Cluster Complex Cp2Cr2Fe4(CO)12(μ6-O)

1999 ◽  
Vol 23 (6) ◽  
pp. 388-389
Author(s):  
Li-Cheng Song ◽  
Wen-Qi Gao ◽  
Xiao-Ying Huang
Keyword(s):  
Crystal Structure ◽  
Transition Metal ◽  
Diffraction Analysis ◽  
Metal Cluster ◽  
Cluster Complex ◽  
X Ray Diffraction ◽  
Synthesis And Crystal Structure ◽  
X Ray ◽  
Transition Metal Cluster

Reaction of Cp(OC)2Cr=S = Cr(CO)2Cp with Fe3(CO)12 affords an encapsulated μ6-O octahedral Fe4Cr2 cluster complex Cp2Cr2Fe4(CO)12(μ6-O), whose crystal structure is determined by X-ray diffraction analysis.

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