Octahedral metal carbonyls. XXXV. Mechanism of the reaction of 2,2'-dipyridyltetracarbonylchromium (0) with alkyl phosphites

1975 ◽  
Vol 14 (9) ◽  
pp. 2275-2276 ◽  
Author(s):  
Billy J. McKerley ◽  
Gary C. Faber ◽  
Gerard R. Dobson
1979 ◽  
Vol 44 (11) ◽  
pp. 3308-3320 ◽  
Author(s):  
Ladislav Kohout ◽  
Jan Fajkoš

Synthesis of 4β-methanesulphonyloxy-6β,7aβ-cyclo-B-homo-5α-cholestane is described. During its acetolysis a kind of conjugative stabilization of the carbocation formed was observed. The mechanism of the reaction is discussed.


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