Kinetics of the metal-exchange reaction between N,N'-bis(2-picolyl)ethylenediaminenickel(II) and copper(II)

1974 ◽  
Vol 13 (12) ◽  
pp. 2922-2929 ◽  
Author(s):  
R. K. Steinhaus ◽  
C. L. Barsuhn
Keyword(s):  
Exchange Reaction ◽  
Metal Exchange ◽  
Metal Exchange Reaction ◽  
Kinetics Of

The Second Step of the Halogen/Metal Exchange Reaction

2003 ◽  
Vol 5 (3) ◽  
pp. 313-316 ◽  
Author(s):  
Reinhard W. Hoffmann ◽  
Mark Brönstrup ◽  
Michael Müller
Keyword(s):  
Exchange Reaction ◽  
Second Step ◽  
Metal Exchange ◽  
Metal Exchange Reaction

Thermochromism of Metal Exchange Reaction between Zinc(II) and Mercury(II) Porphyrins

1995 ◽  
Vol 50 (4) ◽  
pp. 545-550 ◽  
Author(s):  
Masaaki Tabata ◽  
Masahiro Ide ◽  
Kentaro Kaneko
Keyword(s):  
Aqueous Solution ◽  
Exchange Reaction ◽  
Thermodynamic Parameters ◽  
Distribution Curve ◽  
Equilibrium Constants ◽  
Metal Exchange ◽  
Free Base ◽  
Temperature Range ◽  
Base Form ◽  
Metal Exchange Reaction

Thermochromism was observed for an aqueous solution containing zinc(II) and mercury( II) cations and N-p-nitrobenzyl-5,10,15,20-tetrakis(4-sulfonatophenyl)porphyrin anion (NO2Bz(Htpps)4-) in the temperature range 10 to 70 °C. The equilibrium constants and the thermodynamic parameters of Zn(NO2Bztpps)3- and Hg(NO2Bztpps)3- have been determined spectrophotometrically to elucidate the thermochromism at 10, 15, 20, 25 and 30 °C in 0.1 mol dm-3 NaNO3. The protonation and metalation constants of NO2Bz(Htpps)4- are defined as K2 = [H2P][H+]-1[HP]-1, K3 = [H3P][H+]-1[H2P]-1 and KMP = [M P][H+][M2+]-1[HP]-1, where HP and MP denote the free base form of the prophyrin and the metalloporphyrins of zinc(II) and mercury(II), respectively. Charges of the prophyrin and metalloporphyrins are omitted for simplicity. The following values were found: logK2 = 7.75 ±0.02 (25 °C), ΔH°/kJmol-1 = -21.2±0.5 and ΔS°/Jmol-1K-1 = 77±1, logK3 = 2.55±0.02 (25 °C), ΔH°/kJmol-1 = -25±0.8 and ΔS°/Jmol-1K-1 = -35±3 and log KZnP = 0.63±0.03 (25 °C), ΔH°/kJmol-1 = 31.0±0.8 and ΔS°/Jmol-1K-1 = 116±3, logKHgP = 6.22±0.03 (25 °C), ΔH°/kJmol-1 = 4.5±0.7 and ΔS°/Jmol-1K-1 = 134±2. The distribution curve calculated from the thermodynamic parameters sufficiently agrees with the observed metal exchange reaction between the metalloporphyrins.

scholarly journals On the mechanism of rapid metal exchange between thiolate-protected gold and gold/silver clusters: a time-resolved in situ XAFS study

2018 ◽  
Vol 20 (7) ◽  
pp. 5312-5318 ◽  
Author(s):  
Bei Zhang ◽  
Olga V. Safonova ◽  
Stephan Pollitt ◽  
Giovanni Salassa ◽  
Annelies Sels ◽  
...  
Keyword(s):  
Exchange Reaction ◽  
Silver Clusters ◽  
Metal Exchange ◽  
Time Resolved ◽  
X Ray ◽  
Gold Silver ◽  
In Situ Xafs ◽  
Metal Exchange Reaction ◽  
X Ray Absorption

The fast metal exchange reaction between Au38 and AgxAu38−x nanoclusters has been studied by time resolved in situ X-ray absorption spectroscopy.

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