Reduction of vanadium tetrachloride by tetrakis(dimethylamino)diborane(4). Preparation of bis(dimethylaminomethane)vanadium(III) chloride

1974 ◽  
Vol 13 (6) ◽  
pp. 1313-1316 ◽  
Author(s):  
R. F. Kiesel ◽  
E. P. Schram
Keyword(s):  
Vanadium Tetrachloride

scholarly journals Growth without Postannealing of Monoclinic VO2 Thin Film by Atomic Layer Deposition Using VCl4 as Precursor

Coatings ◽  
2018 ◽  
Vol 8 (12) ◽  
pp. 431 ◽  
Author(s):  
Wen-Jen Lee ◽  
Yong-Han Chang
Keyword(s):  
Vanadium Dioxide ◽  
Atomic Layer ◽  
Amorphous Structure ◽  
Temperature Dependent ◽  
Vanadium Compounds ◽  
Multifunctional Material ◽  
Layer Deposition ◽  
Vanadium Tetrachloride ◽  
First Time ◽  
Deposited Films

Vanadium dioxide (VO2) is a multifunctional material with semiconductor-to-metal transition (SMT) property. Organic vanadium compounds are usually employed as ALD precursors to grow VO2 films. However, the as-deposited films are reported to have amorphous structure with no significant SMT property, therefore a postannealing process is necessary for converting the amorphous VO2 to crystalline VO2. In this study, an inorganic vanadium tetrachloride (VCl4) is used as an ALD precursor for the first time to grow VO2 films. The VO2 film is directly crystallized and grown on the substrate without any postannealing process. The VO2 film displays significant SMT behavior, which is verified by temperature-dependent Raman spectrometer and four-point-probing system. The results demonstrate that the VCl4 is suitably employed as a new ALD precursor to grow crystallized VO2 films. It can be reasonably imagined that the VCl4 can also be used to grow various directly crystallized vanadium oxides by controlling the ALD-process parameters.

Amino Derivative of Vanadium Tetrachloride

1965 ◽  
Vol 337 (3-4) ◽  
pp. 221-224 ◽  
Author(s):  
Sarju Prasad ◽  
Ramesh Chandra Srivastava
Keyword(s):  
Amino Derivative ◽  
Vanadium Tetrachloride

Oxidative coupling of phenols using vanadium tetrachloride and vanadium oxytrichloride

1969 ◽  
Vol 34 (8) ◽  
pp. 2388-2392 ◽  
Author(s):  
Wayne L. Carrick ◽  
George L. Karapinka ◽  
George T. Kwiatkowski
Keyword(s):  
Oxidative Coupling ◽  
Vanadium Tetrachloride
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