Lower oxidation states of tellurium. Tetratellurium(2+) in molten salt solutions

Niels Bjerrum

doi:10.1021/ic50091a001

Lower oxidation states of tellurium. Tetratellurium(2+) in molten salt solutions

Inorganic Chemistry ◽

10.1021/ic50091a001 ◽

1970 ◽

Vol 9 (9) ◽

pp. 1965-1969 ◽

Cited By ~ 11

Author(s):

Niels Bjerrum

Keyword(s):

Molten Salt ◽

Oxidation States ◽

Salt Solutions ◽

Lower Oxidation

Download Full-text

Lower oxidation states of bismuth. Bi+ and [Bi5]3+ in molten salt solutions

Inorganic Chemistry ◽

10.1021/ic50052a022 ◽

1967 ◽

Vol 6 (6) ◽

pp. 1162-1172 ◽

Cited By ~ 87

Author(s):

Niels J. Bjerrum ◽

Charles R. Boston ◽

George Pedro Smith

Keyword(s):

Molten Salt ◽

Oxidation States ◽

Salt Solutions ◽

Lower Oxidation

Download Full-text

Lower oxidation states in gallium halides

10.31274/rtd-180813-15014 ◽

1956 ◽

Author(s):

Richard K. McMullan

Keyword(s):

Oxidation States ◽

Lower Oxidation

Download Full-text

ChemInform Abstract: LOWER OXIDATION STATES OF SULFUR. 1. SPECTROPHOTOMETRIC STUDY OF THE SULFUR-CHLORINE SYSTEM IN MOLTEN SODIUM CHLORIDE-ALUMINUM CHLORIDE (37-63 MOL *) AT 150°C

Chemischer Informationsdienst ◽

10.1002/chin.197831011 ◽

1978 ◽

Vol 9 (31) ◽

Author(s):

R. FEHRMANN ◽

N. J. BJERRUM ◽

F. W. POULSEN

Keyword(s):

Sodium Chloride ◽

Aluminum Chloride ◽

Spectrophotometric Study ◽

Oxidation States ◽

Molten Sodium ◽

Lower Oxidation

Download Full-text

ChemInform Abstract: LOWER OXIDATION STATES OF SELENIUM PART 1, SPECTROPHOTOMETRIC STUDY OF THE SELENIUM-SELENIUM TETRACHLORIDE SYSTEM IN A MOLTEN NACL-ALCL3 EUTECTIC MIXTURE AT 150 DEGREES

Chemischer Informationsdienst ◽

10.1002/chin.197546004 ◽

1975 ◽

Vol 6 (46) ◽

pp. no-no

Author(s):

R. FEHRMANN ◽

N. J. BJERRUM ◽

H. A. ANDREASEN

Keyword(s):

Eutectic Mixture ◽

Spectrophotometric Study ◽

Oxidation States ◽

Lower Oxidation

Download Full-text

Longitudinal collective models in metal-molten salt solutions

Journal of Physics C Solid State Physics ◽

10.1088/0022-3719/19/23/008 ◽

1986 ◽

Vol 19 (23) ◽

pp. 4443-4461 ◽

Cited By ~ 7

Author(s):

G Chabrier ◽

J P Hansen ◽

J F Joanny

Keyword(s):

Molten Salt ◽

Salt Solutions ◽

Collective Models

Download Full-text

Lower oxidation states of bismuth. Bi82+ formed in aluminum chloride-sodium chloride melts

Inorganic Chemistry ◽

10.1021/ic50057a005 ◽

1967 ◽

Vol 6 (11) ◽

pp. 1968-1972 ◽

Cited By ~ 45

Author(s):

Niels J. Bjerrum ◽

George Pedro Smith

Keyword(s):

Sodium Chloride ◽

Aluminum Chloride ◽

Oxidation States ◽

Chloride Melts ◽

Lower Oxidation

Download Full-text

The prediction of metal-to-metal bonding in transition metal binary and related compounds

Australian Journal of Chemistry ◽

10.1071/ch9641191 ◽

1964 ◽

Vol 17 (11) ◽

pp. 1191 ◽

Cited By ~ 11

Author(s):

JC Sheldon

Keyword(s):

Transition Metal ◽

Metal Oxides ◽

Transition Metal Oxides ◽

Valence State ◽

Oxidation States ◽

Metal Bonding ◽

Binary Oxides ◽

Lower Oxidation ◽

D Orbitals ◽

Related Compounds

The evidence for, and the factors determining, the formation of metal-to-metal (m-m) bonds in transition metal oxides, sulphides, halides, and related complexes are discussed. It is proposed that when metals of high preferred valence state are constrained to low formal oxidation states, m-m bonds will form to allow the metal to exercise a higher valency. It is assumed that (n-l)d orbitals are used for such bonds and predictions of the feasibility of m-m bonding are possible by the comparison of the size of such orbitals with the expected inter-metal distances in polymeric metal oxides and halides. It is concluded that binary oxides and halides (excepting fluorides) of the lower oxidation states of Zr, Hf, Nb, Ta, Mo, W, and Re and of a few neighbouring elements will display m-m bonds.

Download Full-text