Five-coordination. VIII. Low-spin transition metal complexes with an open-chain tetradentate phosphorus-sulfur ligand

1969 ◽  
Vol 8 (1) ◽  
pp. 146-150 ◽  
Author(s):  
Thomas D. DuBois ◽  
Devon W. Meek
1999 ◽  
Vol 103 (1-3) ◽  
pp. 2675-2678 ◽  
Author(s):  
H. Ushijima ◽  
T. Kawasaki ◽  
T. Kodzasa ◽  
M. Kanakubo ◽  
H. Matsuda ◽  
...  

1992 ◽  
Vol 47 (1) ◽  
pp. 74-78 ◽  
Author(s):  
Dieter Sellmann ◽  
Michael Geck ◽  
Matthias Moll

In order to investigate the potential conversion of coordinated NO into N2 ligands at Ru sulfur centers, the cationic Ru nitrosyl complex meso-[Ru(NO)('S5')]Br (1)** was synthesized by template alkylation of [NBu4][Ru(NO)('S2')2]** with (BrC2H4)2S. 1 is reactive towards nucleophiles. Reaction with azide yields N2O, N2 and [Ru('S5')]2 (2), reaction with LiNH2, NH3 and NEt3 leads to C-S bond cleavage in the 'S5' ligand of 1 and to the formation of a Ru nitrosyl vinylthioetherthiolate complex.


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