Defect Structure, Phase Separation, and Electrical Properties of Nonstoichiometric Tetragonal Tungsten Bronze Ba0.5–xTaO3–x

2013 ◽  
Vol 52 (22) ◽  
pp. 13244-13252 ◽  
Author(s):  
Xiaojun Kuang ◽  
Fengjuan Pan ◽  
Jiang Cao ◽  
Chaolun Liang ◽  
Matthew R. Suchomel ◽  
...  
Keyword(s):  
Phase Separation ◽  
Electrical Properties ◽  
Defect Structure ◽  
Tungsten Bronze ◽  
Tetragonal Tungsten Bronze ◽  
Structure Phase

Phase Separation and Phase Transitions in Multiferroic K0.58FeF3with the Tetragonal Tungsten Bronze Structure

2011 ◽  
Vol 23 (24) ◽  
pp. 5440-5445 ◽  
Author(s):  
Sandra A. Reisinger ◽  
Marc Leblanc ◽  
Anne-Marie Mercier ◽  
Chiu C. Tang ◽  
Julia E. Parker ◽  
...  
Keyword(s):  
Phase Transitions ◽  
Phase Separation ◽  
Tungsten Bronze ◽  
Tungsten Bronze Structure ◽  
Tetragonal Tungsten Bronze

Structure and electrical properties of tetragonal tungsten bronze Ba2CeFeNb4O15

RSC Advances ◽  
2015 ◽  
Vol 5 (94) ◽  
pp. 76957-76962 ◽  
Author(s):  
Hongqiang Ma ◽  
Kun Lin ◽  
Laijun Liu ◽  
Baoling Yang ◽  
Yangchun Rong ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Electrical Property ◽  
Electrical Properties ◽  
Impedance Spectroscopy ◽  
Electron Diffraction ◽  
Tungsten Bronze ◽  
Ac Impedance Spectroscopy ◽  
Tetragonal Tungsten Bronze ◽  
X Ray ◽  
Selected Area Electron Diffraction

The crystal structure and electrical property of a tetragonal tungsten bronze ceramic, BaCeFeNb4O15, were investigated by synchrotron X-ray powder diffraction, selected area electron diffraction, and AC impedance spectroscopy.

ChemInform Abstract: Structure and Electrical Properties of Tetragonal Tungsten Bronze Ba2CeFeNb4O15.

ChemInform ◽  
2015 ◽  
Vol 46 (48) ◽  
pp. no-no
Author(s):  
Hongqiang Ma ◽  
Kun Lin ◽  
Laijun Liu ◽  
Baoling Yang ◽  
Yangchun Rong ◽  
...  
Keyword(s):  
Electrical Properties ◽  
Tungsten Bronze ◽  
Tetragonal Tungsten Bronze ◽  
Abstract Structure

Irreversible anomalies in the electrical properties of oxides with the tetragonal tungsten bronze structure

2000 ◽  
Vol 36 (11) ◽  
pp. 1133-1136
Author(s):  
I. A. Gurnikovskii ◽  
A. G. Bermus ◽  
L. M. Rudkovskaya ◽  
O. A. Bunina
Keyword(s):  
Electrical Properties ◽  
Tungsten Bronze ◽  
Tungsten Bronze Structure ◽  
Tetragonal Tungsten Bronze

Epitaxial Growth of Sr0.3Ba0.7Nb2O6 Thin Films Prepared by Sol-Gel Process

1999 ◽  
Vol 606 ◽  
Author(s):  
Keishi Nishio ◽  
Jirawat Thongrueng ◽  
Yuichi Watanabe ◽  
Toshio Tsuchiya
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Epitaxial Growth ◽  
Raw Materials ◽  
Substrate Surface ◽  
Sol Gel ◽  
Tungsten Bronze ◽  
Monomethyl Ether ◽  
Tetragonal Tungsten Bronze ◽  
Sol Gel Process

AbstructWe succeeded in the preparation of strontium-barium niobate (Sr0.3Ba0.7Nb2O6 : SBN30)that have a tetragonal tungsten bronze type structure thin films on SrTiO3 (100), STO, or La doped SrTiO3 (100), LSTO, single crystal substrates by a spin coating process. LSTO substrate can be used for electrode. A homogeneous coating solution was prepared with Sr and Ba acetates and Nb(OEt)5 as raw materials, and acetic acid and diethylene glycol monomethyl ether as solvents. The coating thin films were sintered at temperature from 700 to 1000°C for 10 min in air. It was confirmed that the thin films on STO substrate sintered above 700°C were in the epitaxial growth because the 16 diffraction spots were observed on the pole figure using (121) reflection. The <130> and <310> direction of the thin film on STO were oriented with the c-axis in parallel to the substrate surface. However, the diffraction spots of thin film on LSTO substrate sintered at 700°C were corresponds to the expected pattern for (110).

Tetragonal Tungsten Bronze Type Sn(II)-Based Quaternary Oxides: A New Type of Visible-Light-Absorbing Semiconductors for Photoelectrochemical Water Oxidation

2021 ◽  
Author(s):  
Yalong Zou ◽  
Jiabo Le ◽  
Yufeng Cao ◽  
Na An ◽  
Yang Zhou ◽  
...  
Keyword(s):  
Visible Light ◽  
Water Oxidation ◽  
Tungsten Bronze ◽  
Complex Oxides ◽  
Tetragonal Tungsten Bronze ◽  
Visible Light Absorption ◽  
New Type ◽  
Hydrogen Fuels ◽  
Photoelectrochemical Water Oxidation ◽  
Pec Water Splitting

The attractive photoelectrochemical (PEC) water splitting for hydrogen fuels always desires new semiconductors which provide stronger visible light absorption with suitable band positions. Sn(II) complex oxides are expected to offer...

Intergrowth of niobium tungsten oxides of the tetragonal tungsten bronze type

2020 ◽  
Vol 75 (11) ◽  
pp. 913-919
Author(s):  
Frank Krumeich
Keyword(s):  
Electron Microscopy ◽  
Transmission Electron Microscopy ◽  
Tungsten Bronze ◽  
Structural Complexity ◽  
Dark Field ◽  
Tetragonal Tungsten Bronze ◽  
Tungsten Oxides ◽  
Transmission Electron ◽  
Scanning Transmission

AbstractSince the 1970s, high-resolution transmission electron microscopy (HRTEM) is well established as the most appropriate method to explore the structural complexity of niobium tungsten oxides. Today, scanning transmission electron microscopy (STEM) represents an important alternative for performing the structural characterization of such oxides. STEM images recorded with a high-angle annular dark field (HAADF) detector provide not only information about the cation positions but also about the distribution of niobium and tungsten as the intensity is directly correlated to the local scattering potential. The applicability of this method is demonstrated here for the characterization of the real structure of Nb7W10O47.5. This sample contains well-ordered domains of Nb8W9O47 and Nb4W7O31 besides little ordered areas according to HRTEM results. Structural models for Nb4W7O31 and twinning occurring in this phase have been derived from the interpretation of HAADF-STEM images. A remarkable grain boundary between well-ordered domains of Nb4W7O31 and Nb8W9O47 has been found that contains one-dimensionally periodic features. Furthermore, short-range order observed in less ordered areas could be attributed to an intimate intergrowth of small sections of different tetragonal tungsten bronze (TTB) based structures.

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