Oxidation States, Geometries, and Electronic Structures of Plutonium Tetroxide PuO4 Isomers: Is Octavalent Pu Viable?

2013 ◽  
Vol 52 (24) ◽  
pp. 14237-14245 ◽  
Author(s):  
Wei Huang ◽  
Wen-Hua Xu ◽  
Jing Su ◽  
W. H. E. Schwarz ◽  
Jun Li
Keyword(s):  
Electronic Structures ◽  
Oxidation States

Si2p Core Level Absorption and Photoemission Spectra of Porous Si

1992 ◽  
Vol 283 ◽  
Author(s):  
Hisao Nakashima ◽  
Koichi Inoue ◽  
Kenzo Maehashi
Keyword(s):  
Synchrotron Radiation ◽  
Electronic Structures ◽  
Energy Shift ◽  
Blue Shift ◽  
Photo Luminescence ◽  
High Energy ◽  
Core Level ◽  
Oxidation States ◽  
Porous Si ◽  
The Core

ABSTRACTSi2p core level absorption and photoemission spectra are taken for different porous Si layers using synchrotron radiation, toknow the electronic structures of porous Si. The core level absorption spectra show the high energy shift of the conduction band which correlates with the photo-luminescence blue shift. The oxidation states of porous Si are clarified from the photoemission spectra.

Spectral and energy transfer in Bi3+–Ren+ (n = 2, 3, 4) co-doped phosphors: extended optical applications

2018 ◽  
Vol 20 (17) ◽  
pp. 11516-11541 ◽  
Author(s):  
Junpeng Xue ◽  
Xiangfu Wang ◽  
Jung Hyun Jeong ◽  
Xiaohong Yan
Keyword(s):  
Energy Transfer ◽  
Electronic Structures ◽  
Electronic Configuration ◽  
Oxidation States ◽  
Optical Applications ◽  
Co Doped

Bismuth with [Xe]4f145d106s26p3 electronic configuration is considered as ‘a wonder metal’ due to its diverse oxidation states and multi-type electronic structures.

ReducedN-Alkyl Substituted Bis(imino)pyridine Cobalt Complexes: Molecular and Electronic Structures for Compounds Varying by Three Oxidation States

2010 ◽  
Vol 49 (13) ◽  
pp. 6110-6123 ◽  
Author(s):  
Amanda C. Bowman ◽  
Carsten Milsmann ◽  
Eckhard Bill ◽  
Emil Lobkovsky ◽  
Thomas Weyhermüller ◽  
...  
Keyword(s):  
Electronic Structures ◽  
Cobalt Complexes ◽  
Oxidation States

Theoretical studies on the oxidation states and electronic structures of actinide-borides: AnB12 (An = Th–Cm) clusters

2018 ◽  
Vol 20 (37) ◽  
pp. 23856-23863 ◽  
Author(s):  
Shu-Xian Hu ◽  
Mingyang Chen ◽  
Bingyun Ao
Keyword(s):  
Density Functional Theory ◽  
Oxidation State ◽  
Electronic Structures ◽  
Density Functional ◽  
Oxidation States ◽  
Theoretical Studies ◽  
Functional Theory ◽  
Actinide Series ◽  
Metal Doped ◽  
Half Sandwich

The electronic structures of actinide metal doped half sandwich AnB12 (An = Th to Cm) clusters are explored and characterized using relativistic density functional theory. The trend of oxidation state across the actinide series in AnB12 exhibits two turning points, +V in Pa and +II in Am.

Syntheses and electronic structures of μ-nitrido bridged pyridine, diimine iridium complexes

2014 ◽  
Vol 50 (63) ◽  
pp. 8735-8738 ◽  
Author(s):  
Friedrich Angersbach-Bludau ◽  
Christopher Schulz ◽  
Julia Schöffel ◽  
Peter Burger
Keyword(s):  
Transition Metal ◽  
Electronic Structures ◽  
Oxidation States ◽  
Late Transition Metal ◽  
Iridium Complexes ◽  
Nitrido Complexes ◽  
Late Transition

Oxidation states in late transition metal nitrido complexes.

Mechanisms of neptunium redox reactions in nitric acid solutions

2017 ◽  
Vol 4 (4) ◽  
pp. 581-594 ◽  
Author(s):  
Sayandev Chatterjee ◽  
Samuel A. Bryan ◽  
Amanda J. Casella ◽  
James M. Peterson ◽  
Tatiana G. Levitskaia
Keyword(s):  
Nitric Acid ◽  
Electronic Structures ◽  
Redox Reactions ◽  
Oxidation States ◽  
Acid Solutions ◽  
Nitric Acid Solutions

This work explores the mechanisms of inter-conversions among the various oxidation states of neptunium in aqueous HNO3, and the effect of HNO3 on their electronic structures.

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