Postsynthetic Modification of a Metal–Organic Framework for Stabilization of a Hemiaminal and Ammonia Uptake

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Sundaram Balasubramanian ◽  
Tapas Kumar Maji

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...  

A porphyrin-based metal–organic framework is shown to be structurally stable towards acid loading using either hydrochloric or formic acid.


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Mihaela Florea ◽  
Elena Ilyes ◽  
Florin Vasiliu ◽  
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Mian Li ◽  
Xue-Zhi Wang ◽  
Dong Luo ◽  
Yi-Fang Zhao ◽  
...  

In contrast to the regular postsynthetic modification (PSM) approach which is global and random in principle, a diffusion-controlled PSM strategy utilizing size mismatch between pores and reactants has been developed to target selective functionalization and fine-tuning of material performance.


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