Structural and Spectroscopic Properties of LaOF:Eu3+Nanocrystals Prepared by the Sol–Gel Pechini Method

2011 ◽  
Vol 50 (17) ◽  
pp. 8112-8120 ◽  
Author(s):  
Tomasz Grzyb ◽  
Stefan Lis
2015 ◽  
Vol 44 (9) ◽  
pp. 4063-4069 ◽  
Author(s):  
Tomasz Grzyb ◽  
Konrad Kubasiewicz ◽  
Agata Szczeszak ◽  
Stefan Lis

Gadolinium orthoborates doped with Yb3+ and Tb3+ ions, showing dual-mode luminescence (down- and up-conversion), were synthesised by the sol–gel Pechini method and analysed.


2014 ◽  
Vol 155 ◽  
pp. 374-383 ◽  
Author(s):  
Agata Szczeszak ◽  
Konrad Kubasiewicz ◽  
Tomasz Grzyb ◽  
Stefan Lis

Open Physics ◽  
2006 ◽  
Vol 4 (3) ◽  
Author(s):  
Abbas Al-Wattar ◽  
Baha Chiad ◽  
Wesam Twej ◽  
Sarmed Al-Awadi

AbstractThe solid host of a laser dye modifies its spectroscopic properties with respect to its liquid host. During the Sol-Gel process the dye molecules suffer from changing their environment. Two parameters affect this matter, the change in the concentration due to the evaporation of the solvent (drying) and the caging of dye molecules inside the pores or attachment to the silica network. Rhodamine 6G absorption and fluorescence spectra with different concentrations, during Sol-Gel time processing, have been studied. Both, absorption and fluorescence spectra of the dye in the solid host, for different concentrations, show a blue-shift relative to its liquid phase.


Author(s):  
Lam Thi Ngoc Tran ◽  
Damiano Massella ◽  
Lidia Zur ◽  
Alessandro Chiasera ◽  
Stefano Varas ◽  
...  

The development of efficient luminescent systems, such as microcavities, solid state lasers, integrated optical amplifiers, optical sensors is the main topic in glass photonics. The building blocks of these systems are glass-ceramics activated by rare earth ions because they exhibit specific morphologic, structural and spectroscopic properties. Among various materials that could be used as nanocrystals to be imbedded in silica matrix, tin dioxide presents some interesting peculiarities, e.g. the presence of tin dioxide nanocrystals allows increase in both solubility and emission of rare earth ions. Here, we focus our attention on Er3+ - doped silica – tin dioxide photonic glass-ceramics fabricated by sol-gel route. Although the SiO2-SnO2:Er3+ could be fabricated in different geometrical systems: thin films, monoliths and planar waveguides we herein limit ourselves to the monoliths. The effective role of tin dioxide as luminescence sensitizer for Er3+ ions is confirmed by spectroscopic measurements and detailed fabrication protocols are discussed.


2018 ◽  
Vol 20 (33) ◽  
pp. 21598-21606 ◽  
Author(s):  
K. Kniec ◽  
L. Marciniak

In this work we present the spectroscopic properties of LaGaO3:V,Nd3+ nanocrystals, which have been successfully obtained by the Pechini method.


2021 ◽  
Vol 0 (0) ◽  
Author(s):  
Anna Prnová ◽  
Jana Valúchová ◽  
Monika Michálková ◽  
Beáta Pecušová ◽  
Milan Parchovianský ◽  
...  

Abstract Glass microspheres with yttria-alumina eutectic composition (76.8 mol % Al2O3 and 23.2 mol % Y2O3) were prepared by sol-gel Pechini method and flame synthesis with or without subsequent milling. Prepared amorphous powders were studied by X-ray powder diffraction (XRD), particle size analysis (PSA), scanning electron microscopy (SEM) and differential thermal analysis (DTA). Hot pressing (HP), rapid hot pressing (RHP) and spark plasma sintering (SPS) were used to sinter amorphous precursor powders at 1600 °C without holding time (0 min). The preparation process including milling step resulted in amorphous powders with narrower particle size distribution and smaller particle size. All applied pressure assisted sintering techniques resulted in dense bulk samples with fine grained microstructure consisting of irregular α-Al2O3 and Y3Al5O12 (YAG) grains. Milling was beneficial in terms of final microstructure refinement and mechanical properties of sintered materials. A material with the Vickers hardness of HV = (17.1 ± 0.3) GPa and indentation fracture resistance of (4.2 ± 0.2) MPa.m1/2 was prepared from the powder milled for 12 h.


RSC Advances ◽  
2019 ◽  
Vol 9 (44) ◽  
pp. 25627-25637 ◽  
Author(s):  
Ma. Oumezzine ◽  
Herbet Bezerra Sales ◽  
Ahmed Selmi ◽  
E. K. Hlil

Bulk nanocrystalline samples of (La1−xPrx)0.67Ba0.33MnO3 (0.075 ≤ x ≤ 0.30) manganites with a fixed carrier concentration are prepared by the sol–gel based Pechini method.


2019 ◽  
Vol 43 (8) ◽  
pp. 3409-3418
Author(s):  
N. Górecka ◽  
K. Szczodrowski ◽  
A. Lazarowska ◽  
M. Grinberg

A series of luminescent materials based on a sodium calcium phosphate matrix doped with europium and different concentrations of silicon ions was synthesized using the Pechini method.


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