High-Nuclearity Ce/Mn and Th/Mn Cluster Chemistry:  Preparation of Complexes with [Ce4Mn10O10(OMe)6]18+and [Th6Mn10O22(OH)2]18+Cores

2007 ◽  
Vol 46 (8) ◽  
pp. 3105-3115 ◽  
Author(s):  
Abhudaya Mishra ◽  
Anastasios J. Tasiopoulos ◽  
Wolfgang Wernsdorfer ◽  
Khalil A. Abboud ◽  
George Christou
Keyword(s):  
Cluster Chemistry ◽  
Mn Cluster

“Depolymerization” Approach in Mn Cluster Chemistry: Controlled Cleavage of a 1D Coordination Polymer Consisting of Mn8Units in Its Constituent, Discrete Mn8Complex

2010 ◽  
Vol 49 (2) ◽  
pp. 359-361 ◽  
Author(s):  
Constantinos C. Stoumpos ◽  
Olivier Roubeau ◽  
Guillem Aromí ◽  
Anastasios J. Tasiopoulos ◽  
Vassilios Nastopoulos ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Cluster Chemistry ◽  
1D Coordination Polymer ◽  
Mn Cluster

Manganese (III) fluoride as a new synthon in Mn cluster chemistry

Polyhedron ◽  
2005 ◽  
Vol 24 (16-17) ◽  
pp. 2443-2449 ◽  
Author(s):  
Leigh F. Jones ◽  
Jim Raftery ◽  
Simon J. Teat ◽  
David Collison ◽  
Euan K. Brechin
Keyword(s):  
Cluster Chemistry ◽  
Mn Cluster

New structural motifs in Mn cluster chemistry from the ketone/gem-diol and bis(gem-diol) forms of 2,6-di-(2-pyridylcarbonyl)pyridine: {MnII4MnIII2} and {MnII4MnIII6} complexes

RSC Advances ◽  
2016 ◽  
Vol 6 (107) ◽  
pp. 105969-105979 ◽  
Author(s):  
Dimosthenis P. Giannopoulos ◽  
Luís Cunha-Silva ◽  
Rafael Ballesteros-Garrido ◽  
Rafael Ballesteros ◽  
Belén Abarca ◽  
...  
Keyword(s):  
Structural Motifs ◽  
Cluster Chemistry ◽  
Mn Cluster

The ketone/gem-diol (L1H2) and bis(gem-diol) (L2H4) forms of the ligand 2,6-di-(2-pyridylcarbonyl)pyridine in Mn cluster chemistry have afforded the new complexes [MnII4MnIII2(N3)6Cl4(L1)2(DMF)4] and [MnII4MnIII6O2(N3)12(L1)2(L2H)2(DMF)6].

Macropolyhedral Boron-Containing Cluster Chemistry. A Metallathiaborane from S2B17H17: Isolation and Characterisation of [(PMe2Ph)2PtS2B16H16]; A neo-arachno Ten-Vertex Cluster Shape, and the Constitution of the [arachno-B10H15]- Anion

2005 ◽  
Vol 70 (4) ◽  
pp. 430-440 ◽  
Author(s):  
Michael J. Carr ◽  
Michael G. S. Londesborough ◽  
Jonathan Bould ◽  
Ivana Císařová ◽  
Bohumil Štíbr ◽  
...  
Keyword(s):  
Dft Calculations ◽  
Sodium Hydride ◽  
Hydrogen Atoms ◽  
Subsequent Reaction ◽  
Cluster Chemistry ◽  
Cluster Shape ◽  
Open Face

The deprotonation of S2B17H17 with sodium hydride and subsequent reaction with [PtCl2(PMe2Ph)2] gives the new macropolyhedral metallathiaborane [(PMe2Ph)2PtS2B16H16], of which the cluster consists of a conventional eleven-vertex nido {SB10} unit, fused, with two boron atoms in common, with a {PtSB8} unit of unique ten-vertex neo-arachno constitution and geometry. The latter geometry suggests a configuration for the previously structurally uncharacterised [B10H15]- anion; starting from this configuration, DFT calculations of structure and thence of boron nuclear shieldings, which are found very closely to mimic those found experimentally, thence support a fluxional structure for [B10H15]- with three {BHB(bridging)} and two {BH(endo)} hydrogen atoms around a six-membered open face.

A novel 2-D Mn selenidostannate(iv) incorporating high-nuclear Mn clusters with spin canting behavior

2017 ◽  
Vol 46 (46) ◽  
pp. 16009-16013 ◽  
Author(s):  
Jian Zhou ◽  
Hong Xiao ◽  
Hua-Hong Zou ◽  
Xing Liu
Keyword(s):  
Spin Canting ◽  
Mn Cluster

The incorporation of a hepta-nuclear Mn cluster [Mn7(ea)6]8+ into a selenidostannate(iv) framework leads to a novel 2-D Mn selenidostannate(iv) with spin canting behavior.

The heteronuclear cluster chemistry of the Group IB metals

1988 ◽  
Vol 344 (3) ◽  
pp. 411-417 ◽  
Author(s):  
Paul J. McCarthy ◽  
Ian D. Salter ◽  
Vladimir Šik
Keyword(s):  
Cluster Chemistry ◽  
Heteronuclear Cluster

Cluster chemistry

1994 ◽  
Vol 469 (1) ◽  
pp. 89-97 ◽  
Author(s):  
Michael I. Bruce ◽  
Jonathan R. Hinchliffe ◽  
Richard Surynt ◽  
Brian W. Skelton ◽  
Allan H. White
Keyword(s):  
Cluster Chemistry
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