“Depolymerization” Approach in Mn Cluster Chemistry: Controlled Cleavage of a 1D Coordination Polymer Consisting of Mn8Units in Its Constituent, Discrete Mn8Complex

2010 ◽  
Vol 49 (2) ◽  
pp. 359-361 ◽  
Author(s):  
Constantinos C. Stoumpos ◽  
Olivier Roubeau ◽  
Guillem Aromí ◽  
Anastasios J. Tasiopoulos ◽  
Vassilios Nastopoulos ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Cluster Chemistry ◽  
1D Coordination Polymer ◽  
Mn Cluster

scholarly journals Copper(II) 2,2-Bis(Hydroxymethyl)Propionate Coordination Compounds with Hexamethylenetetramine: From Mononuclear Complex to One-Dimensional Coordination Polymer

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3358
Author(s):  
Sadaf Rauf ◽  
Agata Trzesowska-Kruszynska ◽  
Tomasz Sierański ◽  
Marcin Świątkowski
Keyword(s):  
Coordination Polymer ◽  
Coordination Compounds ◽  
Structural Diversity ◽  
Structural Features ◽  
Mononuclear Complex ◽  
Molar Ratio ◽  
One Dimensional ◽  
1D Coordination Polymer ◽  
Copper Coordination ◽  
Stretching Vibrations

Three new copper coordination compounds derived from 2,2-bis(hydroxymethyl)propionic acid (dmpa) and hexamethylenetetramine (hmta) were obtained and their crystal structures were determined. The stoichiometry of the reagents applied in the syntheses reflects the metal to ligand molar ratio in the formed solid products. Due to the multiple coordination modes of the used ligands, wide structural diversity was achieved among synthesized compounds, i.e., mononuclear [Cu(dmp)2(hmta)2(H2O)] (1), dinuclear [Cu2(dmp)4(hmta)2] (2), and 1D coordination polymer [Cu2(dmp)4(hmta)]n (3). Their supramolecular structures are governed by O—H•••O and O—H•••N hydrogen bonds. The compounds were characterized in terms of absorption (UV-Vis and IR) and thermal properties. The relationships between structural features and properties were discussed in detail. Owing to discrepancies in the coordination mode of a dmp ligand, bidentate chelating in 1, and bidentate bridging in 2 and 3, there is a noticeable change in the position of the bands corresponding to the stretching vibrations of the carboxylate group in the IR spectra. The differences in the structures of the compounds are also reflected in the nature and position of the UV-Vis absorption maxima, which are located at lower wavelengths for 1.

Synthesis, structure, magnetic properties and EPR spectroscopy of a copper(ii) coordination polymer with a ditopic hydrazone ligand and acetate bridges

2015 ◽  
Vol 44 (4) ◽  
pp. 1782-1789 ◽  
Author(s):  
Rahman Bikas ◽  
Pavlo Aleshkevych ◽  
Hassan Hosseini-Monfared ◽  
Joaquín Sanchiz ◽  
Ritta Szymczak ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Coordination Polymer ◽  
Epr Spectroscopy ◽  
Hydrazone Ligand ◽  
1D Coordination Polymer

The synthesis, structure, EPR spectroscopy and magnetic properties of a 1D coordination polymer of Cu(ii) containing two kinds of acetate bridged dimers is reported.

Azide-bridged Cd(ii) 1D coordination polymer with Cd13nano-crown-like cluster

CrystEngComm ◽  
2013 ◽  
Vol 15 (4) ◽  
pp. 650-653 ◽  
Author(s):  
Shi-Qiang Bai ◽  
Chen-Jie Fang ◽  
Zheng He ◽  
En-Qing Gao ◽  
Chun-Hua Yan ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
1D Coordination Polymer

Copper(II)/di-2-pyridyl ketone chemistry: A triangular cluster displaying antisymmetric exchange versus an 1D coordination polymer

Polyhedron ◽  
2013 ◽  
Vol 64 ◽  
pp. 30-37 ◽  
Author(s):  
Constantinos G. Efthymiou ◽  
Catherine P. Raptopoulou ◽  
Vassilis Psycharis ◽  
Anastasios J. Tasiopoulos ◽  
Albert Escuer ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
1D Coordination Polymer

Ibuprofen as linker for calcium(II) in a 1D-coordination polymer: a solid state investigation complemented with solution studies

2021 ◽  
pp. 120319
Author(s):  
Juliana Morais Missina ◽  
Luca Conti ◽  
Patrizia Rossi ◽  
Andrea Ienco ◽  
Giovana Gioppo Nunes ◽  
...  
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
1D Coordination Polymer ◽  
Solution Studies
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