Nitrosylated Iron−Thiolate−Sulfinate Complexes with {Fe(NO)}6/7Electronic Cores:  Relevance to the Transformation between the Active and Inactive NO-Bound Forms of Iron-Containing Nitrile Hydratases

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Chien-Hong Chen ◽  
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Gene-Hsiang Lee ◽  
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Caio Abércio da Silva ◽  
Rita de Kássia Silva dos Santos ◽  
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Marco Aurélio Callegari ◽  
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B. D. Sharma
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Vol 44 (42) ◽  
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Sodio C. N. Hsu

Ferrocene-based iron–thiolate complexes are reported, and the kinetic product transforms to its corresponding thermodynamic product by the chelating effect of Fc(NC)2.


2015 ◽  
Vol 22 (1) ◽  
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Deniz Akata ◽  
Mustafa Nasuh Ozmen ◽  
Musturay Karcaaltıncaba

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