Dioxygen Reactivity of Copper and Heme−Copper Complexes Possessing an Imidazole−Phenol Cross-Link

2005 ◽  
Vol 44 (5) ◽  
pp. 1238-1247 ◽  
Author(s):  
Eunsuk Kim ◽  
Kaliappan Kamaraj ◽  
Benedikt Galliker ◽  
Nick D. Rubie ◽  
Pierre Moënne-Loccoz ◽  
...  
Keyword(s):  
Copper Complexes ◽  
Cross Link ◽  
Dioxygen Reactivity

scholarly journals Dioxygen Reactivity of New Bispidine-Copper Complexes

2012 ◽  
Vol 51 (5) ◽  
pp. 2841-2851 ◽  
Author(s):  
Peter Comba ◽  
Christina Haaf ◽  
Stefan Helmle ◽  
Kenneth D. Karlin ◽  
Shanthi Pandian ◽  
...  
Keyword(s):  
Copper Complexes ◽  
Dioxygen Reactivity

Electrochemical behavior and dioxygen reactivity of tripodal dinuclear copper complexes linked by unsaturated rigid spacers

2013 ◽  
Vol 42 (6) ◽  
pp. 2238-2253 ◽  
Author(s):  
Antoine Gomila ◽  
Nicolas Le Poul ◽  
Jean-Michel Kerbaol ◽  
Nathalie Cosquer ◽  
Smaïl Triki ◽  
...  
Keyword(s):  
Electrochemical Behavior ◽  
Copper Complexes ◽  
Dinuclear Copper ◽  
Dioxygen Reactivity

scholarly journals Structure and Reactivity of Copper Complexes Supported by a Bulky Tripodal N4 Ligand: Copper(I)/Dioxygen Reactivity and Formation of a Hydroperoxide Copper(II) Complex

2018 ◽  
Vol 644 (14) ◽  
pp. 780-789 ◽  
Author(s):  
Sayantan Paria ◽  
Takehiro Ohta ◽  
Yuma Morimoto ◽  
Hideki Sugimoto ◽  
Takashi Ogura ◽  
...  
Keyword(s):  
Copper Complexes ◽  
Dioxygen Reactivity

Steric hindrance influence of a diazo link upon mesogenic properties of some ligands and related copper complexes

1997 ◽  
Vol 94 ◽  
pp. 1695-1714 ◽  
Author(s):  
P Lesot ◽  
F Perez ◽  
P Judeinstein ◽  
JP Bayle ◽  
H Allouchi ◽  
...  
Keyword(s):  
Steric Hindrance ◽  
Copper Complexes

Synthesis, characterization and biological activities of 1,3,4-oxadiazole derivatives of nalidixic acid and their copper complexes

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Nalidixic Acid ◽  
Copper Complexes ◽  
Biological Activities ◽  
Bidentate Coordination ◽  
Antibacterial And Antifungal Activities ◽  
Elemental Analyses ◽  
Oxadiazole Derivatives ◽  
Antibacterial And Antifungal ◽  
Derivatives Of ◽  
Substituted 1

A series of novel 1, 3, 4-oxadiazole analogues was synthesized from cyclization of hydrazones of substituted 1-ethyl-1,4-dihydro-7-methyl-4-oxo-1,8-naphthyridine-3-carbohydrazides were prepared from nalidixic acid. The structures of synthesized oxadiazole derivatives and their copper complexes were elucidated on the basis of FTIR, elemental analyses, 1H-NMR and atomic absorption spectral analysis. It was observed from spectral data that metal ligand ratio was 1:1 in all copper complexes and they were bidentate, coordination was found to be done through oxygen of 4-oxo group and nitrogen of oxadiazole ring. The synthesized compounds were further evaluated with biological activities and compared with parent hydrazones. Copper complexes possess antibacterial and antifungal activities better than the oxadiazoles while they have better antioxidant activity then copper complexes. Parent hydrazones were better in all biological activities than synthesized oxadiazoles.

Complexes of Cu (II) with a-Ketoglutaric Acid and 1- (o-tolyl) Biguanide Synthesis, characterization and biological Activity

2019 ◽  
Vol 70 (10) ◽  
pp. 3603-3610
Author(s):  
Madalina Mihalache ◽  
Cornelia Guran ◽  
Aurelia Meghea ◽  
Vasile Bercu ◽  
Ludmila Motelica ◽  
...  
Keyword(s):  
Staphylococcus Aureus ◽  
Pseudomonas Aeruginosa ◽  
Antimicrobial Activity ◽  
Antibacterial Activity ◽  
Biological Activity ◽  
Candida Albicans ◽  
Antifungal Activity ◽  
Copper Complexes ◽  
Substrate Adhesion ◽  
Inert Substrate

The three copper complexes having a-ketoglutaric acid (H2A) and 1- (o-tolyl) biguanide (TB) ligands have been synthesized and characterized. The proposed formulas for these complexes are: [Cu(TB)(HA)]Cl (C1), [Cu(TB)(HA)CH3COO]�H2O (C2) and [Cu(TB)(HA)](NO3) (C3) where HA represents deprotonated H2A. The complexes obtained were tested for antibacterial activity against Staphylococcus aureus ATCC 25923 and Pseudomonas aeruginosa ATCC 27853, antifungal activity on Candida albicans ATCC 10231 and antitumor activity on HeLa tumor cells. Due to the antitumor, antifungal, antimicrobial activity and inhibition of inert substrate adhesion, complexes synthesized could be used for potential therapeutic applications.

Sign in / Sign up

Export Citation Format

Share Document