Investigation on the Chain-to-Chain and Chain-to-Open-Framework Transformations of Two One-Dimensional Aluminophosphate Chains

2003 ◽  
Vol 42 (15) ◽  
pp. 4597-4602 ◽  
Author(s):  
Kaixue Wang ◽  
Jihong Yu ◽  
Caijin Li ◽  
Ruren Xu
Keyword(s):  
One Dimensional ◽  
Open Framework

In2Ge6O15(OH)2(H2dien): An Open-Framework Indate Germanate with One-Dimensional 12-Ring Channels

2007 ◽  
Vol 119 (16) ◽  
pp. 2885-2888 ◽  
Author(s):  
Guang-Zhen Liu ◽  
Shou-Tian Zheng ◽  
Guo-Yu Yang
Keyword(s):  
One Dimensional ◽  
Open Framework

Three-Dimensional Open-Framework Nickel Aluminophosphate [NiAlP2O8][C2N2H9]:  Assembly of One-Dimensional AlP2O83-Chains through [NiO5N] Octahedra

2000 ◽  
Vol 12 (8) ◽  
pp. 2065-2067 ◽  
Author(s):  
Bo Wei ◽  
Jihong Yu ◽  
Zhan Shi ◽  
Shilun Qiu ◽  
Wenfu Yan ◽  
...  
Keyword(s):  
Three Dimensional ◽  
One Dimensional ◽  
Open Framework

Synthesis, Structure and Characterization of a Novel 3D Zinc Organophosphonate

2014 ◽  
Vol 936 ◽  
pp. 915-918
Author(s):  
Hui Duan Li
Keyword(s):  
Powder Diffraction ◽  
Organic Ligand ◽  
Water Molecules ◽  
X Ray Diffraction ◽  
Triclinic Space Group ◽  
One Dimensional ◽  
X Ray ◽  
Open Framework ◽  
Solvothermal Conditions

A novel zinc organophosphonate was synthesized under solvothermal conditions by using [piperazine-1,4-diyldi (methylene)] bis (phosphonic acid) as a organic ligand. Single-crystal X-ray diffraction analysis reveals that compound 1 crystallized in the triclinic space group P-1 (No. 2). Compound 1 formulated as Zn (O3PCH2NHC4H8NHCH2PO3)·H2O. Compound 1 featured a 3D open-framework. Notably, the structure of compound 1 featured one-dimensional channel in the [00 direction. Water molecules were located in these channels. Further characterizations of compound 1 have been performed, including X-ray powder diffraction, IR, ICP and CHN analyses.

Open-framework transition metal fluorophosphates with one-dimensional antiferromagnetic chains

2021 ◽  
pp. 122526
Author(s):  
Yong Jin ◽  
Xinan Zhang ◽  
Tianyu Zhu ◽  
Haoming Yang ◽  
Olivier Mentré ◽  
...  
Keyword(s):  
Transition Metal ◽  
One Dimensional ◽  
Open Framework

Construction of a porous three dimensional rare earth metal–sulfur–ligand open framework

2015 ◽  
Vol 51 (87) ◽  
pp. 15819-15822 ◽  
Author(s):  
Jin Xu ◽  
Ting Liu ◽  
Xiaohui Han ◽  
Shanshan Wang ◽  
Dan Liu ◽  
...  
Keyword(s):  
Rare Earth ◽  
Rare Earth Metal ◽  
Three Dimensional ◽  
Earth Metal ◽  
One Dimensional ◽  
Open Framework ◽  
Sulfur Ligand ◽  
Organic Linker

By using piperazine-1,4-dicarbodithiolate (pipzdtc2−) as the organic linker and the Nd3+ cation as the inorganic motif, a 3D rare earth metal–sulfur–ligand MOF with one-dimensional channels was obtained.

In2Ge6O15(OH)2(H2dien): An Open-Framework Indate Germanate with One-Dimensional 12-Ring Channels

2007 ◽  
Vol 46 (16) ◽  
pp. 2827-2830 ◽  
Author(s):  
Guang-Zhen Liu ◽  
Shou-Tian Zheng ◽  
Guo-Yu Yang
Keyword(s):  
One Dimensional ◽  
Open Framework

Synthons and design in metal phosphates and oxalates with open architectures

2001 ◽  
Vol 57 (1) ◽  
pp. 1-12 ◽  
Author(s):  
C. N. R. Rao ◽  
Srinivasan Natarajan ◽  
Amitava Choudhury ◽  
S. Neeraj ◽  
R. Vaidhyanathan
Keyword(s):  
Linear Chain ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Ladder Structure ◽  
One Dimensional ◽  
Metal Phosphates ◽  
Open Framework ◽  
Framework Materials ◽  
Layer Structures ◽  
The One

We briefly describe the structures of open-framework metal phosphates with different dimensionalities, such as the one-dimensional linear-chain and ladder structures, two-dimensional layer structures and three-dimensional structures with channels. We demonstrate the role of the zero-dimensional four-membered ring monomer and of the one-dimensional ladder structure as the starting building units or synthons involved in the formation of the complex architectures. Thus, we show how the one-dimensional ladder structure transforms to two- and three-dimensional structures under mild conditions. The two-dimensional layer structures also transform to three-dimensional structures, while the zero-dimensional monomer transforms to layered and three-dimensional structures under ordinary reaction conditions. These transformations provide an insight into the possible pathways involved in the building up of the complex structures of metal phosphates. The isolation of amine phosphates during the hydrothermal synthesis of metal phosphates and also the facile reactions between amine phosphates and metal ions to yield a variety of open-framework materials have thrown light on the mechanism of formation and design of these structures. The existence of a hierarchy of open-framework metal oxalates and their ready formation by employing amine oxalates as intermediates provides additional support to the observations made earlier with regard to the phosphates.

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