Structure and Magnetic Properties of the Two-Dimensional Ferrimagnet (NEt4)[{Mn(salen)}2Fe(CN)6]:  Investigation of Magnetic Anisotropy on a Single Crystal

2003 ◽  
Vol 42 (11) ◽  
pp. 3509-3515 ◽  
Author(s):  
Hitoshi Miyasaka ◽  
Hidenori Ieda ◽  
Naohide Matsumoto ◽  
Ken-ichi Sugiura ◽  
Masahiro Yamashita
Keyword(s):  
Magnetic Properties ◽  
Magnetic Anisotropy ◽  
Single Crystal ◽  
Two Dimensional

A tetragonal phase Mn2B2 sheet: a stable room temperature ferromagnet with sizable magnetic anisotropy

2020 ◽  
Vol 22 (19) ◽  
pp. 10893-10899 ◽  
Author(s):  
Yusuf Zuntu Abdullahi ◽  
Zeynep Demir Vatansever ◽  
Ethem Aktürk ◽  
Ümit Akıncı ◽  
Olcay Üzengi Aktürk
Keyword(s):  
Magnetic Properties ◽  
Magnetic Anisotropy ◽  
Tetragonal Phase ◽  
Room Temperature ◽  
Electronic Devices ◽  
Two Dimensional ◽  
Metal Boride

Exploring the magnetic properties of two-dimensional (2D) metal boride (MBene) sheets for spin-based electronics is gaining importance for developing electronic devices.

Syntheses, structures and magnetic properties of two CoII/NiII isostructural coordination polymers based on an asymmetric semirigid tricarboxylate ligand

2022 ◽  
Vol 78 (1) ◽  
Author(s):  
Shao-Dong Li ◽  
Feng Su ◽  
Cheng-Yong Zhou ◽  
Qi-Long Hu ◽  
Ya-Qi Li ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Ir Spectroscopy ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Two Dimensional ◽  
X Ray Diffraction ◽  
Magnetic Studies ◽  
Thermogravimetric Analyses ◽  
X Ray ◽  
Elemental Analyses

Two new isostructural complexes, namely, poly[aqua[μ3-2-(4-carboxyphenoxy)terephthalato-κ3 O 1:O 4:O 4′](1,10-phenanthroline-κ2 N,N′)cobalt(II)], [Co(C15H8O7)(C12H8N2)(H2O)] n or [Co(μ3-Hcpota)(phen)(H2O)] n , I, and poly[aqua[μ3-2-(4-carboxyphenoxy)terephthalato-κ3 O 1:O 4:O 4′](1,10-phenanthroline-κ2 N,N′)nickel(II)], [Ni(C15H8O7)(C12H8N2)(H2O)] n or [Ni(μ3-Hcpota)(phen)(H2O)] n , II, have been synthesized by solvothermal reactions. Complexes I and II were fully characterized by IR spectroscopy, elemental analyses, thermogravimetric analyses, and powder and single-crystal X-ray diffraction. They both present two-dimensional structures based on [M 2(μ-COO)2]2+ (M = CoII or NiII) dinuclear metal units with a fes topology and a vertex symbol (4·82). Interestingly, the positions of the two dimeric metal motifs and the two partially deprotonated Hcpota2− ligands reproduce regular flying butterfly arrangements flipped upside down and sharing wings in the ab plane. Magnetic studies indicate antiferromagnetic interactions (J = −5.21 cm−1 for I and −11.53 cm−1 for II) in the dimeric units, with Co...Co and Ni...Ni distances of 4.397 (1) and 4.358 (1) Å, respectively, that are related to double syn–anti carboxylate bridges.

Magnetic Susceptibility and Structure of Some Transition Metal (II) Complexes with 1,2,4-Triazole

1977 ◽  
Vol 32 (7) ◽  
pp. 783-784 ◽  
Author(s):  
D. W. Engelfriet ◽  
J. G. Haasnoot ◽  
W. L. Groeneveld
Keyword(s):  
Magnetic Properties ◽  
Magnetic Susceptibility ◽  
Transition Metal ◽  
Metal Ions ◽  
Single Crystal ◽  
Two Dimensional ◽  
Single Crystal Diffraction ◽  
Magnetic Susceptibilities ◽  
X Ray

Abstract The magnetic susceptibilities of some transition metal (II) complexes with 1,2,4-triazole (trz) have been measured in the range 2-300 K. Ni (trz)2 (NO3)2 (H2O) 8/3, Ni (trz)2 SO4 (H2O)5 and α-Ni (trz)2 (NCS)2 are found to be linear antiferromagnetic trimers. For β- Ni (trz)2 (NCS)2 and similar compounds with Mn (II), Fe (II), Co (II) and Cu(II), totally different magnetic properties were observed, suggesting the presence of two-dimensional networks of metal ions bridged by 1,2,4-triazole molecules. For Co (trz) 2 (NCS) 2 this was confirmed by X-ray single crystal diffraction.

Magnetic properties and magnetic anisotropy of two-dimensional organometallic framework

2019 ◽  
Vol 290 ◽  
pp. 22-26 ◽  
Author(s):  
Xu Li ◽  
Xia Long ◽  
Tian Liu ◽  
Guojun Zhu ◽  
Juexian Cao
Keyword(s):  
Magnetic Properties ◽  
Magnetic Anisotropy ◽  
Two Dimensional

Two-Dimensional AC Magnetic Properties of Electrical Steel Sheet with Two-Dimensional DC-Biased Magnetization

2021 ◽  
Vol 1034 ◽  
pp. 141-149
Author(s):  
Hideaki Miyahara ◽  
Kyyoul Yun
Keyword(s):  
Magnetic Properties ◽  
Magnetic Anisotropy ◽  
Electrical Steel ◽  
Iron Loss ◽  
Low Grade ◽  
High Grade ◽  
Two Dimensional ◽  
Steel Sheets ◽  
Increase Rate ◽  
Electrical Steel Sheets

To estimate the magnetic properties with two-dimensional AC-magnetization with two-dimensional DC-biased magnetization, three different grades of non-oriented electrical steel sheets with two-dimensional DC-biased magnetization were prepared. As a result, in the high grade specimen, the difference in the magnetic properties depending on the excitation direction (AC excitation direction is parallel to DC excitation direction) was larger than in the low grade specimen, and the magnetic properties were the best when the excitation direction was the rolling direction. Non-oriented electrical steel sheets have small magnetic anisotropy. High grade non-oriented electrical steel sheets have a large magnetic anisotropy to compare with low grade non-oriented electrical steel sheets. It is thought that magnetic anisotropy increased in the high grade non-oriented electrical steel sheets because the B-H loops under DC-biased magnetization were minor loops. In addition, the increase rate of the H widths and the increase rate of the iron losses depending on the excitation direction were relatively consistent. Since the iron loss is proportional to the area of the B-H loop, it is considered that the iron loss increased at the same rate as the H width of the B-H loop.

Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

2021 ◽  
Vol 9 (15) ◽  
pp. 5082-5087
Author(s):  
Yu Gong ◽  
Wang-Kang Han ◽  
Hui-Shu Lu ◽  
Qing-Tao Hu ◽  
Huan Tu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Single Crystal ◽  
Coordination Polymers ◽  
Ligand Exchange ◽  
Spin Crossover ◽  
Metal Organic Frameworks ◽  
Crystal Transformation ◽  
Metal Organic

New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.

scholarly journals Complex magnetism of the two-dimensional antiferromagnetic Ge2F: from a Néel spin-texture to a potential antiferromagnetic skyrmion

RSC Advances ◽  
2021 ◽  
Vol 11 (15) ◽  
pp. 8654-8663
Author(s):  
Fatima Zahra Ramadan ◽  
Flaviano José dos Santos ◽  
Lalla Btissam Drissi ◽  
Samir Lounis
Keyword(s):  
Density Functional Theory ◽  
Magnetic Properties ◽  
Density Functional ◽  
Low Energy ◽  
Two Dimensional ◽  
Functional Theory ◽  
2D Material ◽  
Energy Models ◽  
Spin Texture

Based on density functional theory combined with low-energy models, we explore the magnetic properties of a hybrid atomic-thick two-dimensional (2D) material made of germanene doped with fluorine atoms in a half-fluorinated configuration (Ge2F).

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