Kinetic study of .beta.-hydride elimination of monoalkyl complexes of platinum(II): effects of varying the alkyl chain length or the cis group in the reaction of cis-bis(triethylphosphine)(alkyl)(halo or pseudohalo)platinum(II) complexes

1990 ◽  
Vol 29 (18) ◽  
pp. 3467-3472 ◽  
Author(s):  
Giuseppe Alibrandi ◽  
Luigi Monsu Scolaro ◽  
Domenico Minniti ◽  
Raffaello Romeo
Keyword(s):  
Kinetic Study ◽  
Chain Length ◽  
Alkyl Chain ◽  
Alkyl Chain Length ◽  
Beta Hydride Elimination ◽  
Hydride Elimination

scholarly journals Silver Nanoparticles Stabilized with Phosphorus-Containing Heterocyclic Surfactants: Synthesis, Physico-Chemical Properties, and Biological Activity Determination

Nanomaterials ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 1883
Author(s):  
Martin Pisárčik ◽  
Miloš Lukáč ◽  
Josef Jampílek ◽  
František Bilka ◽  
Andrea Bilková ◽  
...  
Keyword(s):  
Silver Nanoparticles ◽  
Biological Activity ◽  
Zeta Potential ◽  
Chain Length ◽  
Alkyl Chain ◽  
Chemical Properties ◽  
Alkyl Chain Length ◽  
Microbial Pathogens ◽  
Physico Chemical ◽  
Phosphorus Containing

Phosphorus-containing heterocyclic cationic surfactants alkyldimethylphenylphospholium bromides with the alkyl chain length 14 to 18 carbon atoms were used for the stabilization of silver nanodispersions. Zeta potential of silver nanodispersions ranges from +35 to +70 mV, which indicates the formation of stable silver nanoparticles (AgNPs). Long-chain heptadecyl and octadecyl homologs of the surfactants series provided the most intensive stabilizing effect to AgNPs, resulting in high positive zeta potential values and smaller diameter of AgNPs in the range 50–60 nm. A comparison with non-heterocyclic alkyltrimethylphosphonium surfactants of the same alkyl chain length showed better stability and more positive zeta potential values for silver nanodispersions stabilized with heterocyclic phospholium surfactants. Investigations of biological activity of phospholium-capped AgNPs are represented by the studies of antimicrobial activity and cytotoxicity. While cytotoxicity results revealed an increased level of HepG2 cell growth inhibition as compared with the cytotoxicity level of silver-free surfactant solutions, no enhanced antimicrobial action of phospholium-capped AgNPs against microbial pathogens was observed. The comparison of cytotoxicity of AgNPs stabilized with various non-heterocyclic ammonium and phosphonium surfactants shows that AgNPs capped with heterocyclic alkyldimethylphenylphospholium and non-heterocyclic triphenyl-substituted phosphonium surfactants have the highest cytotoxicity among silver nanodispersions stabilized by the series of ammonium and phosphonium surfactants.

scholarly journals Physico-chemical and gel properties of heat-induced pasteurized liquid egg white gel: effect of alkyl chain length of alcohol

2021 ◽  
Vol 24 (1) ◽  
pp. 1229-1243
Author(s):  
Danai Charoensuk ◽  
Robert G. Brannan ◽  
Wilailuk Chaiyasit ◽  
Wanlop Chanasattru
Keyword(s):  
Chain Length ◽  
Alkyl Chain ◽  
Egg White ◽  
Alkyl Chain Length ◽  
Gel Properties ◽  
Gel Effect ◽  
Physico Chemical

scholarly journals Responsive Polyesters with Alkene and Carboxylic Acid Side-Groups for Tissue Engineering Applications

Polymers ◽  
2021 ◽  
Vol 13 (10) ◽  
pp. 1636
Author(s):  
Stella Afroditi Mountaki ◽  
Maria Kaliva ◽  
Konstantinos Loukelis ◽  
Maria Chatzinikolaidou ◽  
Maria Vamvakaki
Keyword(s):  
Carboxylic Acid ◽  
Chain Length ◽  
Main Chain ◽  
Alkyl Chain ◽  
Click Reaction ◽  
Irradiation Time ◽  
Alkyl Chain Length ◽  
Polymer Chains ◽  
Condensation Polymerization ◽  
L929 Fibroblast

Main chain polyesters have been extensively used in the biomedical field. Despite their many advantages, including biocompatibility, biodegradability, and others, these materials are rather inert and lack specific functionalities which will endow them with additional biological and responsive properties. In this work, novel pH-responsive main chain polyesters have been prepared by a conventional condensation polymerization of a vinyl functionalized diol with a diacid chloride, followed by a photo-induced thiol-ene click reaction to attach functional carboxylic acid side-groups along the polymer chains. Two different mercaptocarboxylic acids were employed, allowing to vary the alkyl chain length of the polymer pendant groups. Moreover, the degree of modification, and as a result, the carboxylic acid content of the polymers, was easily tuned by varying the irradiation time during the click reaction. Both these parameters, were shown to strongly influence the responsive behavior of the polyesters, which presented adjustable pKα values and water solubilities. Finally, the difunctional polyesters bearing the alkene and carboxylic acid functionalities enabled the preparation of cross-linked polyester films by chemically linking the pendant vinyl bonds on the polymer side groups. The biocompatibility of the cross-linked polymers films was assessed in L929 fibroblast cultures and showed that the cell viability, proliferation, and attachment were greatly promoted on the polyester surface, bearing the shorter alkyl chain length side groups and the higher fraction of carboxylic acid functionalities.

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