Square-planar copper(II) chelate complexes of the ONN,X type (X = monodentate ligand): kinetics of ligand substitution as studied in acetone and the effect of water

Juergen Roeper; Helmut Paulus; Horst Elias

doi:10.1021/ic00311a016

Square-planar copper(II) chelate complexes of the ONN,X type (X = monodentate ligand): kinetics of ligand substitution as studied in acetone and the effect of water

Inorganic Chemistry ◽

10.1021/ic00311a016 ◽

1989 ◽

Vol 28 (12) ◽

pp. 2323-2329 ◽

Cited By ~ 16

Author(s):

Juergen Roeper ◽

Helmut Paulus ◽

Horst Elias

Keyword(s):

Ligand Substitution ◽

Chelate Complexes ◽

Monodentate Ligand ◽

Effect Of Water ◽

Square Planar ◽

Kinetics Of

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ChemInform Abstract: Square-Planar Copper(II) Chelate Complexes of the ONN,X Type (X: Monodentate Ligand): Kinetics of Ligand Substitution As Studied in Acetone and the Effect of Water.

ChemInform ◽

10.1002/chin.198939271 ◽

1989 ◽

Vol 20 (39) ◽

Author(s):

J. R. ROEPER ◽

H. PAULUS ◽

H. ELIAS

Keyword(s):

Ligand Substitution ◽

Chelate Complexes ◽

Monodentate Ligand ◽

Effect Of Water ◽

Square Planar ◽

Kinetics Of

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The kinetics of ligand substitution in bis(N-alkylsalicylaldiminato)nickel(II) Complexes: a study on the reactivity of square-planar versus octahedral coordination

Inorganica Chimica Acta ◽

10.1016/s0020-1693(00)86078-8 ◽

1988 ◽

Vol 149 (2) ◽

pp. 259-264 ◽

Cited By ~ 7

Author(s):

P. Segla ◽

H. Elias

Keyword(s):

Ligand Substitution ◽

Octahedral Coordination ◽

Square Planar ◽

Kinetics Of

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ChemInform Abstract: The Kinetics of Ligand Substitution in Bis(N-alkylsalicylaldiminato)nickel(II) Complexes: A Study on the Reactivity of Square-Planar versus Octahedral Coordination.

ChemInform ◽

10.1002/chin.198852243 ◽

1988 ◽

Vol 19 (52) ◽

Author(s):

P. SEGLA ◽

H. ELIAS

Keyword(s):

Ligand Substitution ◽

Octahedral Coordination ◽

Square Planar ◽

Kinetics Of

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Kinetics of Multidentate Ligand Substitution Reaction. III. Substitution Reactions of BT with Cobalt(II) and Nickel(II) Chelates ofN-(2-Hydroxyethyl)-ethylenediamine-N,N′,N′-triacetic Acid and 2,2′-Ethylenedioxybis[ethyliminodi(acetic acid)]

Bulletin of the Chemical Society of Japan ◽

10.1246/bcsj.41.2033 ◽

1968 ◽

Vol 41 (9) ◽

pp. 2033-2040 ◽

Cited By ~ 10

Author(s):

Mutsuo Kodama ◽

Chifumi Sasaki ◽

Tomohiko Noda

Keyword(s):

Acetic Acid ◽

Substitution Reaction ◽

Ligand Substitution ◽

Substitution Reactions ◽

Multidentate Ligand ◽

Kinetics Of ◽

Ligand Substitution Reaction

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Thermal decomposition kinetics of square-planar d8 bis(N-monosubstituted-dithlocarbamato)metal(II) complexes

Thermochimica Acta ◽

10.1016/0040-6031(89)85293-1 ◽

1989 ◽

Vol 149 ◽

pp. 331-340 ◽

Cited By ~ 6

Author(s):

G.A. Katsoulos ◽

M. Lalia-Kantouri ◽

C.C. Hadjikostas ◽

P. Kokorotsikos

Keyword(s):

Thermal Decomposition ◽

Decomposition Kinetics ◽

Thermal Decomposition Kinetics ◽

Square Planar ◽

Kinetics Of

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Effect of water on the kinetics of fatigue failure in steel 00Kh12N3D

Soviet Materials Science ◽

10.1007/bf00718317 ◽

1979 ◽

Vol 15 (1) ◽

pp. 12-17

Author(s):

L. I. Domozhirov

Keyword(s):

Fatigue Failure ◽

Effect Of Water ◽

Kinetics Of ◽

Steel 00Kh12n3d

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Supplementary material to "Kinetics of the OH + NO<sub>2</sub> reaction: Effect of water vapour and new parameterisation for global modelling"

10.5194/acp-2019-1103-supplement ◽

2019 ◽

Author(s):

Damien Amedro ◽

Matias Berasategui ◽

Arne J. C. Bunkan ◽

Andrea Pozzer ◽

Jos Lelieveld ◽

...

Keyword(s):

Water Vapour ◽

Effect Of Water ◽

Supplementary Material ◽

Global Modelling ◽

Kinetics Of

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Ligand substitution kinetics of Mo(CO)(RC.tplbond.CR')(S2CNMe2)2 complexes

Organometallics ◽

10.1021/om50001a009 ◽

1983 ◽

Vol 2 (7) ◽

pp. 834-840 ◽

Cited By ~ 18

Author(s):

Richard S. Herrick ◽

D. Mark Leazer ◽

Joseph L. Templeton

Keyword(s):

Ligand Substitution ◽

Kinetics Of

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Kinetics and mechanisms of the ligand substitution of (η5-C9H7)M(CO)4, where M=Nb or Ta, and a reinvestigation of the kinetics of (η5-C5H5)M(CO)4. Molecular structure of (η5-C5H5)Nb(Co)3[P(C6H5)3]

Journal of Organometallic Chemistry ◽

10.1016/s0022-328x(00)00257-6 ◽

2000 ◽

Vol 605 (2) ◽

pp. 168-173 ◽

Cited By ~ 4

Author(s):

Thomas E. Bitterwolf ◽

Dinara Lukmanova ◽

Skip Gallagher ◽

Arnold L. Rheingold ◽

Ilia A. Guzei ◽

...

Keyword(s):

Molecular Structure ◽

Ligand Substitution ◽

Kinetics Of

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Binuclear metal chelate complexes of anthraquinones having a MO4 chromophore. Part 1. Quinizarin

Canadian Journal of Chemistry ◽

10.1139/v87-253 ◽

1987 ◽

Vol 65 (7) ◽

pp. 1485-1490 ◽

Cited By ~ 6

Author(s):

M. N. Bakola-Christianopoulou ◽

P. D. Akrivos ◽

M. Baumgarten

Keyword(s):

Metal Ions ◽

Magnetic Measurements ◽

Metal Chelate ◽

Transition Elements ◽

Chelate Complexes ◽

Cobalt Nickel ◽

Oxygen Donor ◽

Nickel Copper ◽

Square Planar ◽

Coordination Spheres

Homobinuclear metal chelate complexes having 1,4-dihydroxy-9,10-anthracenedione (quinizarin) as a bridging unit have been prepared with four bivalent first row transition elements, namely cobalt, nickel, copper, and zinc. The coordination spheres of the metal ions consist of two nearly equivalent six-membered rings with oxygen donor atoms derived from the quinizarin and the terminal ligands which are either β-diketones or salicylic aldehyde. TG, spectroscopic (ir, uv–vis, epr), and magnetic measurements have been applied to an investigation of the geometry adopted by the MO4 chromophores. The results are consistent with varying degrees of distortion from the ideal square planar toward a tetrahedral arrangement around the metal ions, closely related to the specific metal center involved.

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