Chemistry and catalytic properties of ruthenium and osmium complexes. 3. Development of highly active systems for the homogeneous hydrogenation of aldehydes and ketones

1986 ◽  
Vol 25 (8) ◽  
pp. 1106-1111 ◽  
Author(s):  
Roberto A. Sanchez-Delgado ◽  
Norma Valencia ◽  
Rosalinda Marquez-Silva ◽  
Antida Andriollo ◽  
Miriam Medina
Keyword(s):  
Catalytic Properties ◽  
Homogeneous Hydrogenation ◽  
Active Systems ◽  
Highly Active ◽  
Aldehydes And Ketones ◽  
Osmium Complexes

The chemistry and catalytic properties of ruthenium and osmium complexes

1986 ◽  
Vol 36 (3) ◽  
pp. 283-291 ◽  
Author(s):  
Roberto A. Sanchez-Delgado ◽  
B.Alexis Oramas
Keyword(s):  
Catalytic Properties ◽  
Osmium Complexes

scholarly journals PdCu alloy nanodendrites with tunable composition as highly active electrocatalysts for methanol oxidation

RSC Advances ◽  
2017 ◽  
Vol 7 (10) ◽  
pp. 5800-5806 ◽  
Author(s):  
Yaling Xiong ◽  
Wenying Ye ◽  
Wenlong Chen ◽  
Yiwen Wu ◽  
Qingfeng Xu ◽  
...  
Keyword(s):  
Methanol Oxidation ◽  
Catalytic Properties ◽  
Highly Active

PdCu alloy nanodendrites were prepared and exhibited enhanced catalytic properties towards methanol oxidation relative to commercial Pd/C.

Hydrothermal Fabrication and Catalytic Properties of La1-xSrxM1-yFeyO3(M = Mn, Co) That Are Highly Active for the Removal of Toluene

2010 ◽  
Vol 44 (7) ◽  
pp. 2618-2623 ◽  
Author(s):  
Jiguang Deng ◽  
Hongxing Dai ◽  
Haiyan Jiang ◽  
Lei Zhang ◽  
Guozhi Wang ◽  
...  
Keyword(s):  
Catalytic Properties ◽  
Highly Active

scholarly journals Bi- and trinuclear copper(I) complexes of 1,2,3-triazole-tethered NHC ligands: synthesis, structure, and catalytic properties

2016 ◽  
Vol 12 ◽  
pp. 863-873 ◽  
Author(s):  
Shaojin Gu ◽  
Jiehao Du ◽  
Jingjing Huang ◽  
Huan Xia ◽  
Ling Yang ◽  
...  
Keyword(s):  
Room Temperature ◽  
Copper Complexes ◽  
Catalytic Properties ◽  
Polynuclear Complexes ◽  
Carbene Ligands ◽  
Efficient Catalyst ◽  
X Ray ◽  
X Ray Crystallography ◽  
Air Atmosphere ◽  
Highly Active

A series of copper complexes (3–6) stabilized by 1,2,3-triazole-tethered N-heterocyclic carbene ligands have been prepared via simple reaction of imidazolium salts with copper powder in good yields. The structures of bi- and trinuclear copper complexes were fully characterized by NMR, elemental analysis (EA), and X-ray crystallography. In particular, [Cu2(L2)2](PF6)2 (3) and [Cu2(L3)2](PF6)2 (4) were dinuclear copper complexes. Complexes [Cu3(L4)2](PF6)3 (5) and [Cu3(L5)2](PF6)3 (6) consist of a triangular Cu3 core. These structures vary depending on the imidazolium backbone and N substituents. The copper–NHC complexes tested are highly active for the Cu-catalyzed azide–alkyne cycloaddition (CuAAC) reaction in an air atmosphere at room temperature in a CH3CN solution. Complex 4 is the most efficient catalyst among these polynuclear complexes in an air atmosphere at room temperature.

Homogeneous hydrogenation of α,β-unsaturated aldehydes catalyzed by ruthenium and osmium complexes

1984 ◽  
Vol 24 (2) ◽  
pp. 217-220 ◽  
Author(s):  
Roberto A. Sánchez-Delgado ◽  
Antida Andriollo ◽  
Norma Valencia
Keyword(s):  
Homogeneous Hydrogenation ◽  
Unsaturated Aldehydes ◽  
Osmium Complexes
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