Monomeric complexes of tungsten (0-VI) containing the ligand N,N',N"-trimethyl-1,4,7-triazacyclononane and their electrochemical properties. Preparation of [L2W2O5](PF6)2 and identification of its mixed-valence tungsten (VI)/tungsten(V) complex

1985 ◽  
Vol 24 (24) ◽  
pp. 4049-4054 ◽  
Author(s):  
Gabriele Backes-Dahmann ◽  
Karl Wieghardt
Keyword(s):  
Electrochemical Properties ◽  
Mixed Valence

Synthesis, luminescence and electrochemical properties of luminescent dinuclear mixed-valence gold complexes with alkynyl bridges

2015 ◽  
Vol 2 (5) ◽  
pp. 453-466 ◽  
Author(s):  
Ling-Ling Hung ◽  
Wai Han Lam ◽  
Keith Man-Chung Wong ◽  
Eddie Chung-Chin Cheng ◽  
Nianyong Zhu ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Photophysical Properties ◽  
Mixed Valence ◽  
Computational Studies ◽  
Gold Complexes

A series of luminescent dinuclear mixed-valence gold alkynyl complexes was synthesized. Their photophysical properties can be tuned by varying the nature of the alkynyl bridges, as supported by computational studies.

Electrochemical properties and structures of the mixed-valence lithium cuprates Li3Cu2O4 and Li2NaCu2O4

2001 ◽  
Vol 97-98 ◽  
pp. 465-468 ◽  
Author(s):  
E.A. Raekelboom ◽  
A.L. Hector ◽  
M.T. Weller ◽  
J.R. Owen
Keyword(s):  
Electrochemical Properties ◽  
Mixed Valence

Spectroscopic and electrochemical properties of ruthenium complexes with photochromic triarylamine–dithienylethene–acetylide ligands

2016 ◽  
Vol 3 (11) ◽  
pp. 1432-1443 ◽  
Author(s):  
Dao-Bin Zhang ◽  
Jin-Yun Wang ◽  
Denis Jacquemin ◽  
Zhong-Ning Chen
Keyword(s):  
Electrochemical Properties ◽  
Mixed Valence ◽  
Ruthenium Complexes ◽  
Progressive Increase ◽  
Charge Delocalization ◽  
System P ◽  
Molecular Backbone

The charge delocalization along the molecular backbone shows a progressive increase following stepwise photocyclization in the inorganic–organic mixed-valence system.

Hydrothermal Synthesis and Electrochemical Properties of Layered Vanadates

1998 ◽  
Vol 548 ◽  
Author(s):  
J. Livage ◽  
L. Boujhedja ◽  
S. Castro-Garcia ◽  
C. Julien
Keyword(s):  
Aqueous Solutions ◽  
Electrochemical Properties ◽  
Diffusion Processes ◽  
Mixed Valence ◽  
Layered Structures ◽  
Point Of Zero Charge ◽  
Organic Cations ◽  
Oh Groups ◽  
Molecular Precursors ◽  
Ph Range

ABSTRACTThe synthesis of vanadates from aqueous solutions leads to a large variety of crystalline materials. The nature of molecular precursors mainly depends on pH and three different pH ranges can be distinguished. Cationic precursors are formed at low pH. Precipitation is obtained via the addition of anions leading to materials in which [VO6] octahedra are linked through anions. V2O5,nH2O gels are formed around the Point of Zero Charge (pH=2). They are made of ribbon-like particles and exhibit interesting properties as cathodic materials. Electrochemical properties depend on the drying procedure. Moreover, intercalation reactions lead to a whole range of new inorganic and organic bronzes. Chain metavanadates are precipitated from anionic precursors in basic aqueous solutions. Vanadium coordination decreases and they are made of corner sharing [VO4] tetrahedra. Layered structures are formed in the pH range where negatively charged species such as [VO(OH)4(OH2)]− should behave as precursors. Condensation occurs via V-OH groups in the equatorial plane leading to layered structures in which cations are inserted between the vanadate planes. Some reduction occurs when organic cations such as tetramethyl ammonium [N(CH3)4]+ are used leading to mixed valence vanadates. Electron delocalization is observed in these compounds but Li insertion is hindered by large organic cations. Better electrochemical properties are observed with smaller inorganic cations. Fibrous crystals of NaV3O8,H2O are formed in the presence of NaOH whereas the mixed valence bronze α'-NaxV2O5 is obtained when both NaOH and TMAOH react with V2O5. This fibrous morphology appears to improve diffusion processes at the electrode-electrolyte interface.

Electrochemical Properties and ESR Characterization of Mixed Valence α-[XMo3-xVxW9O40]n-Heteropolyanions with X = PVand SiIV,x= 1, 2, or 3

1996 ◽  
Vol 35 (2) ◽  
pp. 282-288 ◽  
Author(s):  
Emmanuel Cadot ◽  
Michel Fournier ◽  
André Tézé ◽  
Gilbert Hervé
Keyword(s):  
Electrochemical Properties ◽  
Mixed Valence

Electrochemical properties and structures of the mixed-valence lithium cuprates Li3Cu2O4 and Li2NaCu2O4

Ionics ◽  
2000 ◽  
Vol 6 (5-6) ◽  
pp. 466-469
Author(s):  
E. A. Raekelboom ◽  
A. L. Hector ◽  
M. T. Weller ◽  
J. R. Owen
Keyword(s):  
Electrochemical Properties ◽  
Mixed Valence

Spectroscopic and electrochemical properties of mixed-valence RhI-RhIII complexes with a cyanide bridge

1996 ◽  
Vol 45 (3) ◽  
pp. 687-693
Author(s):  
T. V. Magdesieva ◽  
A. A. Bezrukova ◽  
S. I. Gorelsky ◽  
K. P. Butin ◽  
V. S. Khandkarova ◽  
...  
Keyword(s):  
Electrochemical Properties ◽  
Mixed Valence ◽  
Cyanide Bridge
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