Nickel–iridium carbonyl clusters. Synthesis and solid-state structure of the trianion [Ir3Ni6(µ-CO)6(µ3-CO)2(CO)9]3–. The first example of a mixed iridium–nickel carbonyl cluster

1988 ◽  
pp. 201-205 ◽  
Author(s):  
Roberto Della Pergola ◽  
Luigi Garlaschelli ◽  
Francesco Demartin ◽  
Mario Manassero ◽  
Norberto Masciocchi ◽  
...  
Keyword(s):  
Solid State ◽  
Carbonyl Cluster ◽  
State Structure ◽  
Carbonyl Clusters ◽  
Nickel Carbonyl ◽  
Solid State Structure ◽  
Iridium Carbonyl Clusters

Synthesis, Solid-State Structure and Multinuclear NMR Studies of the New Polyhydrido Iridium Carbonyl Cluster Ir4H4(μ-H)4(CO)4(PPh3)4

2003 ◽  
Vol 2003 (11) ◽  
pp. 2108-2112 ◽  
Author(s):  
Luigi Garlaschelli ◽  
Francesco Greco ◽  
Giulia Peli ◽  
Mario Manassero ◽  
Mirella Sansoni ◽  
...  
Keyword(s):  
Solid State ◽  
Carbonyl Cluster ◽  
State Structure ◽  
Nmr Studies ◽  
Solid State Structure ◽  
Multinuclear Nmr

Chemistry of iridium carbonyl cluster complexes. Synthesis, characterization and solid state structure of the phosphido carbonyl cluster [Ir6(CO)12(μ-CO)2(μ-PPh2)−

1994 ◽  
Vol 5 (2) ◽  
pp. 363-371 ◽  
Author(s):  
Roberto Della Pergola ◽  
Elisa Brivio ◽  
Luigi Garlaschelli ◽  
Norberto Masciocchi ◽  
Mario Manassero
Keyword(s):  
Solid State ◽  
Carbonyl Cluster ◽  
State Structure ◽  
Solid State Structure ◽  
Cluster Complexes

Au-Ir and Hg-Ir Mixed-Metal Carbonyl Clusters. Synthesis, Characterization, and Solid State Structure of [Ir6(CO)15(AuPPh3)2] and [Ir6(CO)14(HgCl)2]2-

1995 ◽  
Vol 14 (1) ◽  
pp. 186-193 ◽  
Author(s):  
Alessandro Ceriotti ◽  
Roberto Della Pergola ◽  
Luigi Garlaschelli ◽  
Mario Manassero ◽  
Norberto Masciocchi
Keyword(s):  
Solid State ◽  
Metal Carbonyl ◽  
State Structure ◽  
Carbonyl Clusters ◽  
Solid State Structure ◽  
Mixed Metal ◽  
Metal Carbonyl Clusters

The structure of [Cu(bipy)3][Cu(bipy)(ala)(ClO4)2]ClO4 � a Compound with Two Different Coordination Modes in the same Complex

2008 ◽  
Vol 59 (11) ◽  
Author(s):  
Mircea Braban ◽  
Ionel Haiduc
Keyword(s):  
Solid State ◽  
Chelate Ring ◽  
Octahedral Complex ◽  
State Structure ◽  
Complex Species ◽  
Solid State Structure ◽  
Coordination Modes ◽  
Coordination Center ◽  
Self Assembled ◽  
Chelate Rings

The paper describes the solid state structure of a compound of composition [Cu(bipy)3][Cu(bipy)(ala) (ClO4)2]ClO4, in which both the cation and anion are octahedral complex species with copper(II) as coordination center. The cation contains three chelate rings formed by bipy; the anion contains in the quatorial plane a CuONC2 chelate ring formed by the alaninato ligand and a CuN2C2 chelate ring formed by bipy, with two monodentate perchorato ligands in axial positions completing the six-coordination. In the crystal p-p stackings lead to a supramolecular self-assembled structure.

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