Stereochemical nonrigidity in nine-vertex polyhedral boranes: dimethyl sulfide derivatives of nonahydrononaborate(2-)

1982 ◽  
Vol 21 (11) ◽  
pp. 4022-4026 ◽  
Author(s):  
Edward H. Wong ◽  
Michael G. Gatter ◽  
Raifah M. Kabbani
Keyword(s):  
Dimethyl Sulfide ◽  
Stereochemical Nonrigidity ◽  
Derivatives Of

Heterocyclic derivatives of dimethyl sulfide

1966 ◽  
Vol 1 (5) ◽  
pp. 537-538
Author(s):  
M. V. Mukhina ◽  
I. Ya. Postovskii
Keyword(s):  
Dimethyl Sulfide ◽  
Heterocyclic Derivatives ◽  
Derivatives Of

Aminkomplexe des Goldes, Teil 10: Gold(I)-thiocyanat-Komplexe mit Tetrahydrothiophen, Dimethylsulfid, Ammoniak, Aminen und Azaaromatena

2018 ◽  
Vol 73 (2) ◽  
pp. 125-147 ◽  
Author(s):  
Mark Strey ◽  
Cindy Döring ◽  
Peter G. Jones
Keyword(s):  
Dimethyl Sulfide ◽  
Crystal Packing ◽  
Molecular Structures ◽  
Secondary Amines ◽  
X Ray ◽  
Anions And Cations ◽  
Derivatives Of ◽  
Aurophilic Interactions ◽  
Ray Methods ◽  
Alternating Chain

AbstractThe reaction of (tht)AuCl (tht=tetrahydrothiophene) with KSCN leads to a mixture of gold(I) thiocyanate AuSCN and [(tht)2Au]+ [Au(SCN)2]−1. The compounds were separated and the X-ray structure of 1 confirmed as an alternating chain of anions and cations linked by aurophilic contacts. Either pure AuSCN or the mixture was used to synthesize further derivatives of AuSCN, all of which were investigated by X-ray methods. Most products were of limited stability when removed from their mother liquor. The dimethyl sulfide derivative 2 is molecular, (Me2S)AuSCN; the ammonia derivative 3 is ionic, [(NH3)2Au]+ [Au(SCN)2]−. The reaction with 2,2-bipyridyl leads (presumably by involvement of the solvent or of atmospheric moisture) to [bipy-H]+ [Au(SCN)2]−13. All other products involve amines or azaaromatics as ligands L. The primary amine tert-butylamine forms an ionic product [L2Au]+ (SCN)−4. The secondary amines piperidine and dibenzylamine lead to molecular structures LAuSCN (5 and 6), whereas pyridine-based azaaromatics lead to ionic products [L2Au]+ [Au(SCN)2]− with L=2-, 3- or 4-picoline (7–9), 2,4-, 3,4- or 3,5-lutidine (10–12). The 3,4-lutidine derivative 11 forms two polymorphs that tend to form mixed crystals. The dominant features of the crystal packing for 7–12 are short aurophilic interactions.

ChemInform Abstract: Reaction of Dimethyl Sulfide Ditriflate with Alkenes. Synthesis of Sulfur Derivatives of Nortricyclane.

ChemInform ◽  
2010 ◽  
Vol 28 (44) ◽  
pp. no-no
Author(s):  
V. G. NENAJDENKO ◽  
P. V. VERTELEZKIJ ◽  
I. D. GRIDNEV ◽  
N. E. SHEVCHENKO ◽  
E. S. BALENKOVA
Keyword(s):  
Dimethyl Sulfide ◽  
Derivatives Of

Synthesis, Characterization, and Chemistry of Dimethyl Sulfide Derivatives of closo-B10H102-

2002 ◽  
Vol 67 (7) ◽  
pp. 1007-1024 ◽  
Author(s):  
Heather D. Hall ◽  
Bradley D. Ulrich ◽  
Roman G. Kultyshev ◽  
Jianping Liu ◽  
Shengming Liu ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Single Crystal ◽  
Diffraction Analysis ◽  
Liquid Ammonia ◽  
Dimethyl Sulfide ◽  
X Ray Diffraction ◽  
Chiral Column ◽  
X Ray ◽  
Derivatives Of

The reaction of Cs2[B10H10] with DMSO in acid produces the disubstituted 1,10-, 1,6-, and 2,7(8)-isomers of (Me2S)2B10H8 as well as the monosubstituted [(Me2S)B10H9]- anion. Through a modified procedure, the trisubstituted compound 1,10-(Me2S)2-2-(MeS)B10H7 was prepared and characterized. The 1,10-(Me2S)2B10H8 isomer was converted to the enantiomers 2,7-(Me2S)2B10H8 and 2,8-(Me2S)2B10H8 which were separated on a chiral column. The 1,6-(Me2S)2B10H8 isomer was converted to a mixture of 1,10-(Me2S)2B10H8 and 2,3-(Me2S)2B10H8. These polyhedral rearrangements are believed to occur through the diamond-square-diamond mechanism. The 1,6- and 1,10-(Me2S)2B10H8 isomers were reduced with alkali metal in liquid ammonia to produce the dianions [1,6-(MeS)2B10H8]2- and [1,10-(MeS)2B10H8]2-, respectively. Sodium ethanethiolate was used for the reduction of [1-(Me2S)B10H9]- and 1,10-(Me2S)2B10H8 to form [1-(MeS)B10H9]2- and [1-(MeS)-10-(Me2S)B10H8]-, respectively. The structures of 1,10-(Me2S)2B10H8, 1,6-(Me2S)2B10H8, 2,8-(Me2S)2B10H8, 2,3-(Me2S)2B10H8, 1,10-(Me2S)2-2-(MeS)B10H7, [1-(MeS)-10-(Me2S)B10H8]-, and [1,6-(MeS)2B10H8]2- were determined by single-crystal X-ray diffraction analysis.

Reaction of dimethyl sulfide ditriflate with alkenes. Synthesis of sulfur derivatives of nortricyclane

Tetrahedron ◽  
1997 ◽  
Vol 53 (24) ◽  
pp. 8173-8180 ◽  
Author(s):  
Valentine G. Nenajdenko ◽  
Pavel V. Vertelezkij ◽  
Ilya D. Gridnev ◽  
Nikolai E. Shevchenko ◽  
Elizabeth S. Balenkova
Keyword(s):  
Dimethyl Sulfide ◽  
Derivatives Of

Physical Properties of TCNQ Salts with N-Methyl Derivatives of Pyridine

1982 ◽  
Vol 85 (1) ◽  
pp. 257-263 ◽  
Author(s):  
A. Graja ◽  
M. Przybylski ◽  
B. Butka ◽  
R. Swietlik
Keyword(s):  
Physical Properties ◽  
Methyl Derivatives ◽  
Derivatives Of
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