Synthesis, Characterization, and Chemistry of Dimethyl Sulfide Derivatives of closo-B10H102-

2002 ◽  
Vol 67 (7) ◽  
pp. 1007-1024 ◽  
Author(s):  
Heather D. Hall ◽  
Bradley D. Ulrich ◽  
Roman G. Kultyshev ◽  
Jianping Liu ◽  
Shengming Liu ◽  
...  
Keyword(s):  
Alkali Metal ◽  
Single Crystal ◽  
Diffraction Analysis ◽  
Liquid Ammonia ◽  
Dimethyl Sulfide ◽  
X Ray Diffraction ◽  
Chiral Column ◽  
X Ray ◽  
Derivatives Of

The reaction of Cs2[B10H10] with DMSO in acid produces the disubstituted 1,10-, 1,6-, and 2,7(8)-isomers of (Me2S)2B10H8 as well as the monosubstituted [(Me2S)B10H9]- anion. Through a modified procedure, the trisubstituted compound 1,10-(Me2S)2-2-(MeS)B10H7 was prepared and characterized. The 1,10-(Me2S)2B10H8 isomer was converted to the enantiomers 2,7-(Me2S)2B10H8 and 2,8-(Me2S)2B10H8 which were separated on a chiral column. The 1,6-(Me2S)2B10H8 isomer was converted to a mixture of 1,10-(Me2S)2B10H8 and 2,3-(Me2S)2B10H8. These polyhedral rearrangements are believed to occur through the diamond-square-diamond mechanism. The 1,6- and 1,10-(Me2S)2B10H8 isomers were reduced with alkali metal in liquid ammonia to produce the dianions [1,6-(MeS)2B10H8]2- and [1,10-(MeS)2B10H8]2-, respectively. Sodium ethanethiolate was used for the reduction of [1-(Me2S)B10H9]- and 1,10-(Me2S)2B10H8 to form [1-(MeS)B10H9]2- and [1-(MeS)-10-(Me2S)B10H8]-, respectively. The structures of 1,10-(Me2S)2B10H8, 1,6-(Me2S)2B10H8, 2,8-(Me2S)2B10H8, 2,3-(Me2S)2B10H8, 1,10-(Me2S)2-2-(MeS)B10H7, [1-(MeS)-10-(Me2S)B10H8]-, and [1,6-(MeS)2B10H8]2- were determined by single-crystal X-ray diffraction analysis.

A study of composition effects on the bandgaps in a series of new alkali metal aluminum/gallium iodates

2020 ◽  
Vol 49 (7) ◽  
pp. 2337-2344 ◽  
Author(s):  
Jian-Han Zhang ◽  
Qi Wu ◽  
Wen-Zhong Lai
Keyword(s):  
Alkali Metal ◽  
Single Crystal ◽  
Diffraction Analysis ◽  
Hydrothermal Reaction ◽  
X Ray Diffraction ◽  
X Ray ◽  
Composition Effects ◽  
Metal Aluminum

Four new alkali metal aluminum/gallium iodates, namely A2M(IO3)4(H0.5IO3)2 (A = K, Rb and M = Al, Ga), have been successfully synthesized via a hydrothermal reaction and structurally characterized through single-crystal X-ray diffraction analysis.

Synthesis of 4-(3-coumarinyl)-3-benzyl-4-thiazolin-2-one 4-methylbenzylidenehydrazone and determination of the isomeric structure by X-ray analysis

2003 ◽  
Vol 218 (12) ◽  
Author(s):  
Süheyla Özbey ◽  
Nilgün Karalı ◽  
Aysel Gürsoy
Keyword(s):  
Single Crystal ◽  
Diffraction Analysis ◽  
Spectral Data ◽  
X Ray Diffraction ◽  
X Ray ◽  
Isomeric Structure ◽  
Elemental Analyses

AbstractIn this study 4-(3-coumarinyl)-3-benzyl-4-thi azolin-2-one 4-methylbenzylidenehydrazone 3 was synthesised. An independent proof of the thiazolylhydrazone structure of 3 was achieved by single crystal X-ray diffraction analysis. Elemental analyses and spectral data (IR,

Single-crystal X-ray diffraction analysis of nonplanar autoepitaxial silicon layers

2009 ◽  
Vol 45 (14) ◽  
pp. 1610-1613
Author(s):  
V. T. Bublik ◽  
L. V. Kozhitov ◽  
T. T. Kondratenko
Keyword(s):  
Single Crystal ◽  
Diffraction Analysis ◽  
X Ray Diffraction ◽  
X Ray

Functionalized triphenylphosphine oxide-based manganese(II) complexes for luminescent printing

2021 ◽  
Author(s):  
Xiaomeng Huang ◽  
Yanyan Qin ◽  
Pengfei She ◽  
Haixing Meng ◽  
Shu-Juan Liu ◽  
...  
Keyword(s):  
Single Crystal ◽  
Diffraction Analysis ◽  
Triphenylphosphine Oxide ◽  
X Ray Diffraction ◽  
X Ray

Three novel neutral manganese(II) complexes (TPhPONMe2)2MnBr2, (TPhPOOMe)2MnBr2, and (TPhPOCF3)2MnBr2 have been designed and synthesized based on functionalized Ph3PO ligand. These structures are clarified by single crystal X-ray diffraction analysis, which...

scholarly journals Bridgehead vicinal diallylation of norbornene derivatives and extension to propellane derivatives via ring-closing metathesis

2016 ◽  
Vol 12 ◽  
pp. 1877-1883 ◽  
Author(s):  
Sambasivarao Kotha ◽  
Rama Gunta
Keyword(s):  
Single Crystal ◽  
Diffraction Analysis ◽  
X Ray Diffraction ◽  
Ring Closing Metathesis ◽  
X Ray ◽  
Synthetic Strategy ◽  
Norbornene Derivatives

Here, we report a simple synthetic strategy to the bridgehead vicinal diallylation of norbornene derivatives. These substrates are useful to generate propellanes via ring-closing metathesis. Single-crystal X-ray diffraction analysis of four compounds led to the realization of configurational correction of earlier reported molecules.

X-ray diffraction analysis of Ti-diffused single-crystal LiNbO3

1993 ◽  
Vol 191 (1) ◽  
pp. 15-19
Author(s):  
Perry Skeath ◽  
S.B. Qadri ◽  
F.A. Stevie
Keyword(s):  
Single Crystal ◽  
Diffraction Analysis ◽  
X Ray Diffraction ◽  
X Ray
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