A Baker−Figgis Isomer of Conventional Sandwich Polyoxometalates. H2Na14[FeIII2(NaOH2)2(P2W15O56)2], a Diiron Catalyst for Catalytic H2O2-Based Epoxidation

2001 ◽  
Vol 40 (3) ◽  
pp. 418-419 ◽  
Author(s):  
Xuan Zhang ◽  
Travis M. Anderson ◽  
Qin Chen ◽  
Craig L. Hill
Keyword(s):  
Sandwich Polyoxometalates

Synergistic effect of sandwich polyoxometalates and copper–imidazole complexes for enhancing the peroxidase-like activity

RSC Advances ◽  
2015 ◽  
Vol 5 (96) ◽  
pp. 78771-78779 ◽  
Author(s):  
Dong-Feng Chai ◽  
Zhuo Ma ◽  
Hong Yan ◽  
YunFeng Qiu ◽  
Hong Liu ◽  
...  
Keyword(s):  
Synergistic Effect ◽  
Sandwich Polyoxometalates ◽  
Imidazole Complexes ◽  
Sandwich Type

Two inorganic–organic hybrids based on copper(ii)–imidazole complex modified sandwich-type tungstobismuthate or tungstoantimonite, have been synthesized, demonstrating higher peroxidase-like activity using TMB as a peroxidase substrate.

scholarly journals Protonation and water exchange kinetics in sandwich polyoxometalates

2018 ◽  
Vol 47 (38) ◽  
pp. 13602-13607 ◽  
Author(s):  
C. André Ohlin ◽  
Magda Pascual-Borràs
Keyword(s):  
Metal Oxide ◽  
Water Exchange ◽  
Oxide Surfaces ◽  
Metal Oxide Surfaces ◽  
Sandwich Polyoxometalates ◽  
Exchange Kinetics

The locus of protonation in a sandwich polyoxmetalate is determined and linked to observed reactivities; the implications for reactions on protic metal oxide surfaces are discussed.

Spectroscopic and Electrochemical Study of the Interconversion and Decomplexation of Cobalt(II) Sandwich Polyoxometalates Based on a Dawson-Type Anion

2012 ◽  
Vol 51 (15) ◽  
pp. 8202-8211 ◽  
Author(s):  
Laurent Ruhlmann ◽  
Delphine Schaming ◽  
Iftikhar Ahmed ◽  
Aimeric Courville ◽  
Jacqueline Canny ◽  
...  
Keyword(s):  
Electrochemical Study ◽  
Sandwich Polyoxometalates
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