Reactivity of the methylcyclopentadienylmanganese cyanometalate Na[Cp'Mn(CO)2CN] with titanium, zirconium, and hafnium halides. Crystal and molecular structure of the .mu.-cyano .mu.-oxo tetranuclear complex [Cp2Zr{(.mu.-NC)MnCp'(CO)2}]2(.mu.-O) (Cp = .eta.-C5H5; Cp' = .eta.-MeC5H4). [Erratum to document cited in CA119(9):95744h]

1994 ◽  
Vol 33 (9) ◽  
pp. 2068-2068
Author(s):  
Pierre Braunstein ◽  
Daniele Cauzzi ◽  
David Kelly ◽  
Maurizio Lanfranchi ◽  
Antonio Tiripicchio
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Tetranuclear Complex ◽  
Titanium Zirconium

Crystal and molecular structure of polymeric MeSHgO2CMe and MeSHgO2CMe,C5H5N and the tetranuclear complex (ButS)4Cl4Hg4(C5H5N)2

1978 ◽  
Vol 31 (3) ◽  
pp. 677 ◽  
Author(s):  
AJ Canty ◽  
CL Raston ◽  
AH White
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Polymeric Chain ◽  
Tetranuclear Complex ◽  
Pyridine Complex ◽  
Mercury Crystals

Crystals of methanethiolatomercury(II) acetate are monoclinic, P 21/c, with a 5.292(2), b 15.912(7), c 7.086(2) Ǻ, β 92.96(3)°, Z 4, and its pyridine complex MeSHgO2CMe,C5H5N is monoclinic, P21/n, with a 10.093(3), b 7.026(2), c 15.350(5) Ǻ, β 105.01(3)°, Z4. Both structures are based on a polymeric chain (-Hg-SMe-)n with coordinated acetate groups. In MeSHgO2CMe the chains are linked into sheets by bridging acetate groups, and in the pyridine complex the chains are isolated with pyridine and acetate coordination at each mercury. Crystals of (ButS)4Cl4Hg4(C5H5N)2 are triclinic, Pī, with a 14.399(6), b 9.893(6), c 9.597(5) Ǻ, α 121.82(1), β 102.52(4), γ 102.94(4)°, and Z 1. The structure is based on a tetranuclear grouping of mercury atoms bridged by chloride and thiolate species and centrosymmetric about the origin. There are two mercury environments 'Hg(μ-SBut)2ClN' and 'Hg(μ-SBut)2(μ-Cl)2' with the dichloro bridge linking two equivalent mercury atoms on opposite sides of an (-Hg-SBut-)4 ring.

Crystal and molecular structure of a platinum(II) complex with β-mercaptoethylamine hydrochloride

2018 ◽  
Vol 59 (1) ◽  
pp. 191-195
Author(s):  
A. N. Azizova ◽  
◽  
D. B. Tagiev ◽  
S. N. Osmanova ◽  
Sh. G. Kasumov ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure

The crystal and molecular structure of tris(pentamethylenedithiocarbamate) chromium(III)-chloroform (1 : 2)

1981 ◽  
Vol 46 (1) ◽  
pp. 6-19 ◽  
Author(s):  
Viktor Kettman ◽  
Ján Garaj ◽  
Jaroslav Majer
Keyword(s):  
Molecular Structure ◽  
Structural Analysis ◽  
Crystal And Molecular Structure ◽  
Analysis Method ◽  
Complex Molecules ◽  
Coordination Polyhedra ◽  
X Ray ◽  
Cell Dimensions ◽  
Crustal Density ◽  
Unit Cell Dimensions

The crystal and molecular structure of [Cr(S2CN(CH2)5)3].2 CHCl3 was found by the X-ray structural analysis method. The value R 0.090 was found for 1 131 observed independent reflections. The substance crystallizes in a space group of symmetry P212121 with the following unit cell dimensions: a = 0.8675 (6), b = 1.815(2), c = 2.155(3) nm. The experimentally observed crustal density was 1.48 Mgm-3 and the value calculated for Z = 4 was 1.51 Mgm-3. The CrS6 coordination polyhedron has the shape of a trigonally distorted octahedron, where the D3 symmetry is a approximately retained. The degree of trigonal distortion expressed as the projection of the chelate S-Cr-S angle onto the plane perpendicular to the C3 pseudo axis is Φ = 41.7° (Φ = 60° for an octahedron). The skeleton of the structure formed by the complex molecules contains channels filled with chloroform molecules. The specific type of complex-chloroform interaction consists of the formation of hydrogen bonds of the chloroform protons with the fully occupied pπ-orbitals of the sulphur atoms in the coordination polyhedra. The low stability and crystal decomposition can be explained by loss of chloroform from the channels.

The Crystal and Molecular Structure of sym-fac-(1,4,7-Triazaheptane)-(S)-aspartatocobalt(III) Diperchlorate Dihydrate

1994 ◽  
Vol 59 (5) ◽  
pp. 1052-1058 ◽  
Author(s):  
Jan Ondráček ◽  
Jana Ondráčková ◽  
Jaroslav Maixner ◽  
František Jursík
Keyword(s):  
Molecular Structure ◽  
Aspartic Acid ◽  
Crystal And Molecular Structure ◽  
Heavy Atom ◽  
Membered Ring ◽  
Boat Conformation ◽  
Hydrogen Atoms ◽  
Orthorhombic System ◽  
Anisotropic Temperature ◽  
Heavy Atom Method

The crystal and molecular structure of s-fac-[Co((S)-Asp)(dien)]ClO4 . HClO4 .2 H2O (dien = 1,4,7-triazaheptane) was solved by the heavy atom method. The position parameters of the non-hydrogen atoms and their anisotropic temperature parameters were refined based on 1 726 observed reflections with a final value of R = 0.073. The substance crystallizes in the orthorhombic system in the space group P212121, Z = 4, a = 8.506(1), b = 17.171(2), c = 13.277(1) Å. The structure involves hydrogen bonds between the O2, O4 and HN2 atoms of aspartic acid and the two molecules of water. The five-membered dien chelate rings take the asymmetric envelope conformations. The five-membered ring of (S)-aspartic acid possesses the symmetric envelope conformation whereas the six-membered ring exhibits the skew boat conformation.

Determination of the structure of bis(propyldithiocarbamate)nickel(II)

1990 ◽  
Vol 55 (4) ◽  
pp. 1010-1014 ◽  
Author(s):  
Jiří Kameníček ◽  
Richard Pastorek ◽  
František Březina ◽  
Bohumil Kratochvíl ◽  
Zdeněk Trávníček
Keyword(s):  
Molecular Structure ◽  
Title Compound ◽  
Crystal And Molecular Structure ◽  
Heavy Atom ◽  
Unit Cell ◽  
Monoclinic Space Group ◽  
Planar Configuration ◽  
Compound C ◽  
Heavy Atom Method

The crystal and molecular structure of the title compound (C8H16N2NiS4) was solved by the heavy atom method and the structure was refined anisotropically to a final R factor of R = 0.029 (wR = 0.037) for 715 observed reflections. The crystal is monoclinic, space group P21/c with a = 948.3(2), b = 776.9(2), c = 1 167.4(2) pm, β = 125.14(2)°, Z = 2. The molecule contains two four-membered NiSCS rings of approximately planar configuration with the Ni atom situated at a centre of symmetry. The molecules are arranged in chains along the c-axis of the unit cell.

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