Coordination chemistry of 2-(2'-hydroxyphenyl)-2-benzoxazole with gallium(III) and aluminum(III): two uncommon Group 13 metal environments stabilized by a biologically relevant binding group

1993 ◽  
Vol 32 (22) ◽  
pp. 4909-4913 ◽  
Author(s):  
H. R. Hoveyda ◽  
Steven J. Rettig ◽  
Chris Orvig
Keyword(s):  
Coordination Chemistry ◽  
Group 13 ◽  
Biologically Relevant

The coordination chemistry of o,o'-i-Pr2C6H3-bis(imino)acenaphthene to group 13 trihalides

2002 ◽  
Vol 80 (11) ◽  
pp. 1398-1403 ◽  
Author(s):  
Hilary A Jenkins ◽  
Carla L Dumaresque ◽  
Dragoslav Vidovic ◽  
Jason AC Clyburne
Keyword(s):  
Crystal Structure ◽  
Coordination Chemistry ◽  
General Formula ◽  
Group 13 ◽  
Complex Crystal Structure ◽  
Diimine Ligand ◽  
Gallium Complex ◽  
Complex Crystal

The preparation of several complexes of the diimine ligand o,o'-i-Pr2C6H3-bis(imino)acenaphthene (Ar-BIAN (1)) with group 13 trihalides (EX3, E = B, Al, Ga; X = Cl, Br) is reported. Four compounds with the general formula [(Ar-BIAN)(EX2)][EX4] (2) have been prepared and isolated. Two complexes have been crystallographically characterized: [(Ar-BIAN)(BCl2)][BCl4] (orthorhombic, P212121, a = 10.408(3) Å, b = 14.376(4) Å, c = 30.908(8) Å, Z = 4) and [(Ar-BIAN)(GaCl2)][GaCl4] (monoclinic, P21/m, a = 9.0822(7) Å, b = 15.390(1) Å, c = 15.458(1) Å, β = 92.519(2)°, Z = 2). Attempts to prepare diazametaloles via reduction of the [(Ar-BIAN)(EX2)][EX4] compounds using sodium or potassium have thus far been unsuccessful.Key words: boron, aluminium, gallium, complex, crystal structure, heterocycle.

ChemInform Abstract: Coordination Chemistry of Group 13 Monohalides

ChemInform ◽  
2011 ◽  
Vol 42 (27) ◽  
pp. no-no
Author(s):  
Dragoslav Vidovic ◽  
Simon Aldridge
Keyword(s):  
Coordination Chemistry ◽  
Group 13

Cyclopentadiene Based Low-Valent Group 13 Metal Compounds: Ligands in Coordination Chemistry and Link between Metal Rich Molecules and Intermetallic Materials

2012 ◽  
Vol 112 (6) ◽  
pp. 3136-3170 ◽  
Author(s):  
Sandra González-Gallardo ◽  
Timo Bollermann ◽  
Roland A. Fischer ◽  
Ramaswamy Murugavel
Keyword(s):  
Coordination Chemistry ◽  
Group 13 ◽  
Metal Compounds ◽  
Intermetallic Materials ◽  
Low Valent

scholarly journals Application of Density Functional Theory in Coordination Chemistry: A Case Study of Group 13 Monohalide as a Ligand

2021 ◽  
Author(s):  
Thayalaraj Christopher Jeyakumar ◽  
Francisxavier Paularokiadoss
Keyword(s):  
Density Functional Theory ◽  
Coordination Chemistry ◽  
Density Functional ◽  
Experimental Studies ◽  
Theoretical Studies ◽  
Dft Methods ◽  
Functional Theory ◽  
Group 13 ◽  
Metal Bonding

The chemistry of Group 13 Monohalide is of great interest due to its isoelectronic relationship with carbon monoxide and dinitrogen. In recent years, theoretical and experimental studies have been evolved on the group-13 atom-based diatomic molecules as a ligand. The synthetic, characterisation and reactivity of various metal complexes have been well discussed in recent reviews. The nature of the metal bonding of these ligands of various types has been explained in addition by the variety of theoretical studies (using DFT methods) such as FMO and EDA. This chapter has a comprehensive experimental and theoretical study of group 13 monohalides as a ligand in coordination chemistry.

scholarly journals Application of Complexes of Group 13 Elements in Synthetic Organic Chemistry for Activation of Carbonyl Compounds

Vestnik RFFI ◽  
2019 ◽  
pp. 113-140
Author(s):  
Roman A. Novikov ◽  
Yury V. Tomilov
Keyword(s):  
Organic Chemistry ◽  
Coordination Chemistry ◽  
Organic Synthesis ◽  
Carbonyl Compounds ◽  
Group 13 ◽  
New Era ◽  
Synthetic Organic Chemistry ◽  
Main Emphasis ◽  
New Compounds

The main aspects of modern organic chemistry of the Group 13 elements – aluminum (Al), gallium (Ga), indium (In), and thallium (Tl) – are considered. Herewith, the main emphasis is placed on their use for the various carbonyl compounds activation in organic synthesis and reactions, which are specific for these elements. The 21th century marked a new era in the development of chemistry of the Group 13 elements; it is connected with the discovery of surprising and unexpected reactions and new compounds (primarily in the area of organic and coordination chemistry), defining various fields of these elements application.

Coordination chemistry of group 13 monohalides

2011 ◽  
Vol 2 (4) ◽  
pp. 601 ◽  
Author(s):  
Dragoslav Vidovic ◽  
Simon Aldridge
Keyword(s):  
Coordination Chemistry ◽  
Group 13
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