Cyclopentadiene Based Low-Valent Group 13 Metal Compounds: Ligands in Coordination Chemistry and Link between Metal Rich Molecules and Intermetallic Materials

2012 ◽  
Vol 112 (6) ◽  
pp. 3136-3170 ◽  
Author(s):  
Sandra González-Gallardo ◽  
Timo Bollermann ◽  
Roland A. Fischer ◽  
Ramaswamy Murugavel
Keyword(s):  
Coordination Chemistry ◽  
Group 13 ◽  
Metal Compounds ◽  
Intermetallic Materials ◽  
Low Valent

The Coordination Chemistry of “[BP3]NiX” Platforms:  Targeting Low-Valent Nickel Sources as Promising Candidates to L3NiE and L3Ni⋮E Linkages

2004 ◽  
Vol 43 (15) ◽  
pp. 4645-4662 ◽  
Author(s):  
Cora E. MacBeth ◽  
J. Christopher Thomas ◽  
Theodore A. Betley ◽  
Jonas C. Peters
Keyword(s):  
Coordination Chemistry ◽  
Low Valent

The coordination chemistry of o,o'-i-Pr2C6H3-bis(imino)acenaphthene to group 13 trihalides

2002 ◽  
Vol 80 (11) ◽  
pp. 1398-1403 ◽  
Author(s):  
Hilary A Jenkins ◽  
Carla L Dumaresque ◽  
Dragoslav Vidovic ◽  
Jason AC Clyburne
Keyword(s):  
Crystal Structure ◽  
Coordination Chemistry ◽  
General Formula ◽  
Group 13 ◽  
Complex Crystal Structure ◽  
Diimine Ligand ◽  
Gallium Complex ◽  
Complex Crystal

The preparation of several complexes of the diimine ligand o,o'-i-Pr2C6H3-bis(imino)acenaphthene (Ar-BIAN (1)) with group 13 trihalides (EX3, E = B, Al, Ga; X = Cl, Br) is reported. Four compounds with the general formula [(Ar-BIAN)(EX2)][EX4] (2) have been prepared and isolated. Two complexes have been crystallographically characterized: [(Ar-BIAN)(BCl2)][BCl4] (orthorhombic, P212121, a = 10.408(3) Å, b = 14.376(4) Å, c = 30.908(8) Å, Z = 4) and [(Ar-BIAN)(GaCl2)][GaCl4] (monoclinic, P21/m, a = 9.0822(7) Å, b = 15.390(1) Å, c = 15.458(1) Å, β = 92.519(2)°, Z = 2). Attempts to prepare diazametaloles via reduction of the [(Ar-BIAN)(EX2)][EX4] compounds using sodium or potassium have thus far been unsuccessful.Key words: boron, aluminium, gallium, complex, crystal structure, heterocycle.

ChemInform Abstract: Coordination Chemistry of Group 13 Monohalides

ChemInform ◽  
2011 ◽  
Vol 42 (27) ◽  
pp. no-no
Author(s):  
Dragoslav Vidovic ◽  
Simon Aldridge
Keyword(s):  
Coordination Chemistry ◽  
Group 13
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