Heterodinuclear copper(II)-lead(II) and copper(II)-M(II) (M = manganese, iron, cobalt, nickel, copper, zinc) complexes of macrocycles with dissimilar 4- and 5-coordination sites: synthesis, structures, and properties

1993 ◽  
Vol 32 (13) ◽  
pp. 2949-2957 ◽  
Author(s):  
Hisashi Okawa ◽  
Jun Nishio ◽  
Masaaki Ohba ◽  
Makoto Tadokoro ◽  
Naohide Matsumoto ◽  
...  
Keyword(s):  
Zinc Complexes ◽  
Iron Cobalt ◽  
Coordination Sites ◽  
Cobalt Nickel ◽  
Nickel Copper ◽  
Structures And Properties ◽  
Copper Zinc

scholarly journals On the Dissolution of Metals in Ionic Liquids 1. Iron, Cobalt, Nickel, Copper, and Zinc

2021 ◽  
Vol 2 (1) ◽  
pp. 63-73
Author(s):  
Jéssica D. S. Vicente ◽  
Domingas C. Miguel ◽  
Afonso M. P. Gonçalves ◽  
Diogo M. Cabrita ◽  
José M. Carretas ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Redox Potential ◽  
Final State ◽  
Iron Cobalt ◽  
Influence Of Temperature ◽  
Dissolution Reaction ◽  
Cobalt Nickel ◽  
Iron Metal ◽  
Copper And Zinc ◽  
Nickel Copper

Ionic liquids are critical reagents for science and technical processes nowadays. Metals are the most used reagents in the industry. It is crucial to have a deeper understanding of how ionic liquids and metals could interact. In this article the interaction of those two families of compounds is accessed. The dissolution (reaction) of metals with ionic liquids is studied, namely the influence of temperature, redox potential, and availability of an oxidant in the process. The final state achieved by the iron metal samples was also addressed by Mössbauer spectroscopy.

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